Characteristics of hydrogen separation and methane steam reforming in a Pd-based membrane reactor of shell and tube design

This work investigates numerically the characteristics of the two process, hydrogen separation and steam methane reforming (SMR), in a palladium-based (Inconel-supported Pd–Ag film) membrane reactor (MR) of porous reformer (30% Ni/Al2O3) shell and multi-tube design. Still parameters like reactor design and temperature, feed gas concentration and pressure, and flow configuration need more investigation to figure out their impact on hydrogen production rate at lower energy cost and minimum possible volume. This work targets optimization of reactor performance for higher hydrogen yield and coming up with a scalable optimized reactor design for industrial applications. First, an optimization study is performed under non-reforming (separation-only) conditions to optimize the MR design and operating parameters for higher hydrogen production. Then, the study is extended to consider hydrogen separation under SMR conditions to come up with a MR design for hydrogen production at the industrial scale. Hydrogen permeation is limited to small zone near the membrane surface with no effect of feed pressure, inlet gas temperature, and feed hydrogen concentration on widening such zone that necessitates reducing the pitch distance between membrane tubes below 22 mm. The results showed reduced hydrogen permeation rate under SMR conditions compared to the separation-only cases

Lab-scale validation and parametric numerical investigation on hydrogen production in a porous media as a byproduct of in-situ combustion

A numerical 1D model was developed and validated using the measured data on a porous tube lab experiment for hydrogen generation as an in-situ combustion (ISC) byproduct, and a detailed parametric numerical study was performed. This work explores the impacts of various water injection parameters on the generation of hydrogen, the oil recovery factor (ORF), and carbon monoxide using a thorough parametric analysis. The methodology included simulating the injection of mutually enriched air and water into the combustion tube, focusing on parameters such as water temperature, quality, and flow rates. Key findings reveal that the oxygen ratio in the oxidizer substantially influences hydrogen production and ORF, with hydrogen generation increasing from 1.65 × 103 cm3 to 3.0 × 103 cm3, which is around 82 % when the oxygen percentage is raised from 50 % to 95 %. The results showed that employing wet combustion instead of dry combustion increased the hydrogen production rate by roughly four times. Variable water temperature has insignificant impacts on the hydrogen production rate and ORF. Increasing the steam quality has an opposed effect on the hydrogen generation rate. Additionally, escalating the injected water flow rate from 3000 cm³/day to 15000 cm³/day boosts hydrogen production from 10000 cm³ to 53400 cm³, respectively

Investigation of a turbulent premixed combustion flame in a backward-facing step combustor; effect of equivalence ratio

In the present study, LES (large-eddy simulation) is utilized to analyze lean-premixed propane-air flame stability in a backward-step combustor over a range of equivalence ratio. The artificially thickened flame approach coupled with a reduced reaction mechanism is incorporated for modeling the turbulence–combustion interactions at small scales. Simulation results are compared to high-speed PIV (particle image velocimetry) measurements for validation. The results show that the numerical framework captures different topological flow features effectively and with reasonable accuracy, for stable flame configurations, but some quantitative differences exist. The RZ (recirculation zone) is formed of a primary eddy and a secondary eddy and its overall size is significantly impacted by the equivalence ratio. The temperature distribution inside the recirculation zone is highly non-uniform, with much lower values observed close to the backward step and the bottom wall. The mixture distribution inside the RZ is also non-uniform because of mixing with reactants and heat loss to the walls. The flame is stabilized closer to the backward step as the equivalence ratio increases. At lower fuel fractions, the flame lifts off the step starting at equivalence ratio of 0.63 and the lift off distance is increased while the equivalence ratio is lowered. Keywords Flame stability Large eddy simulation (LES) Particle image velocimetry (PIV) Premixed flame Recirculation zone (RZ) Step combusto

Technoeconomic Feasibility of Hydrogen Production from Waste Tires with the Control of CO2Emissions

The worldwide demand for energy is increasing significantly, and the landfill disposal of waste tires and their stockpiles contributes to huge environmental impacts. Thermochemical recycling of waste tires to produce energy and fuels is an attractive option for reducing waste with the added benefit of meeting energy needs. Hydrogen is a clean fuel that could be produced via the gasification of waste tires followed by syngas processing. In this study, two process models were developed to evaluate the hydrogen production potential from waste tires. Case 1 involves three main processes: The steam gasification of waste tires, water gas shift, and acid gas removal to produce hydrogen. On the other hand, case 2 represents the integration of the waste tire gasification system with the natural gas reforming unit, where the energy from the gasifier-derived syngas can provide sufficient heat to the steam methane reforming (SMR) unit. Both models were also analyzed in terms of syngas compositions, H2production rate, H2purity, overall process efficiency, CO2emissions, and H2production cost. The results revealed that case 2 produced syngas with a 55% higher heating value, 28% higher H2production, 7% higher H2purity, and 26% lower CO2emissions as compared to case 1. The results showed that case 2 offers 10.4% higher process efficiency and 28.5% lower H2production costs as compared to case 1. Additionally, the second case has 26% lower CO2-specific emissions than the first, which significantly enhances the process performance in terms of environmental aspects. Overall, the case 2 design has been found to be more efficient and cost-effective compared to the base case design

Technoeconomic Feasibility of Hydrogen Production from Waste Tires with the Control of CO2Emissions

The worldwide demand for energy is increasing significantly, and the landfill disposal of waste tires and their stockpiles contributes to huge environmental impacts. Thermochemical recycling of waste tires to produce energy and fuels is an attractive option for reducing waste with the added benefit of meeting energy needs. Hydrogen is a clean fuel that could be produced via the gasification of waste tires followed by syngas processing. In this study, two process models were developed to evaluate the hydrogen production potential from waste tires. Case 1 involves three main processes: The steam gasification of waste tires, water gas shift, and acid gas removal to produce hydrogen. On the other hand, case 2 represents the integration of the waste tire gasification system with the natural gas reforming unit, where the energy from the gasifier-derived syngas can provide sufficient heat to the steam methane reforming (SMR) unit. Both models were also analyzed in terms of syngas compositions, H2production rate, H2purity, overall process efficiency, CO2emissions, and H2production cost. The results revealed that case 2 produced syngas with a 55% higher heating value, 28% higher H2production, 7% higher H2purity, and 26% lower CO2emissions as compared to case 1. The results showed that case 2 offers 10.4% higher process efficiency and 28.5% lower H2production costs as compared to case 1. Additionally, the second case has 26% lower CO2-specific emissions than the first, which significantly enhances the process performance in terms of environmental aspects. Overall, the case 2 design has been found to be more efficient and cost-effective compared to the base case design