evidence of bipolar resistive switching memory in perovskite solar cell

In hybrid inorganic-organic perovskite solar cells a very stable bipolar resistive switching behavior in the dark current-voltage characteristics at low-voltages has been observed. The possible use of the solar cell as an electrical memory with a moderate on-off contrast but very good stability over a prolonged time has been suggested. The reversible behavior and the long dynamics during the write/erase processes indicate that the physical mechanism behind the switching is related to polarization effects. A detailed analysis of the charge carrier trapping/detrapping, transport, and recombination mechanisms has been performed by taking the ion migration and the consequent charge carrier accumulation within the device into account. The charge transport during the write operation can be described by space-charge-limited conduction process. The formation and subsequent interruption of conducting pathways due to ion migration have been identified as the main cause of the resistive switching within the perovskite material. The strong interaction between the ion movement and the electron transport enables the operation of the perovskite solar cell also as a non-volatile memory

Proton‐Radiation Tolerant All‐Perovskite Multijunction Solar Cells

Funder: European Research Council; Id: http://dx.doi.org/10.13039/501100000781Funder: Engineering and Physical Sciences Research Council; Id: http://dx.doi.org/10.13039/501100000266Funder: European Union's Horizon 2020Abstract: Radiation‐resistant but cost‐efficient, flexible, and ultralight solar sheets with high specific power (W g−1) are the “holy grail” of the new space revolution, powering private space exploration, low‐cost missions, and future habitats on Moon and Mars. Herein, this study investigates an all‐perovskite tandem photovoltaic (PV) technology that uses an ultrathin active layer (1.56 µm) but offers high power conversion efficiency, and discusses its potential for high‐specific‐power applications. This study demonstrates that all‐perovskite tandems possess a high tolerance to the harsh radiation environment in space. The tests under 68 MeV proton irradiation show negligible degradation (22%. Using high spatial resolution photoluminescence (PL) microscopy, it is revealed that defect clusters in GaAs are responsible for the degradation of current space‐PV. By contrast, negligible reduction in PL of the individual perovskite subcells even after the highest dose studied is observed. Studying the intensity‐dependent PL of bare low‐gap and high‐gap perovskite absorbers, it is shown that the VOC, fill factor, and efficiency potentials remain identically high after irradiation. Radiation damage of all‐perovskite tandems thus has a fundamentally different origin to traditional space PV

Assessment of Melt Compounding with Zeolites as an Effective Deodorization Strategy for Mixed Plastic Wastes and Comparison with Degassing

The emission of off-odors from mechanically recycled plastics severely limits their re-introduction into the market for the production of new objects, for the same use or even for less demanding applications, thus hindering the implementation of an effective circular economy for plastics. The addition of adsorbing agents during the extrusion of polymers represents one of the most promising strategy to reduce the odorous emissions of plastics, due to its characteristics of cost-effectiveness, flexibility and low energy consumption. The novelty of this work lies in the assessment of zeolites as VOC adsorbents during the extrusion of recycled plastics. They appear more suitable than other types of adsorbents, due to their ability to capture and "hold" the adsorbed substances at the high temperatures of the extrusion process. Moreover, the effectiveness of this deodorization strategy was compared with the traditional degassing technique. Two types of mixed polyolefin wastes, coming from completely different collection and recycling processes, were tested: Fil-S (Film-Small), deriving from post-consumer flexible films of small size, and PW (pulper waste), which is the residual plastic waste obtained from the paper recycling process. The melt compounding of the recycled materials with two micrometric zeolites (zeolite 13X and Z310) resulted as more effective in the off-odors removal with respect to degassing. In particular, the highest reduction (-45%) of the Average Odor Intensity (AOI) was measured for both PW/Z310 and Fil-S/13X systems at 4 wt% of the zeolites' amount, compared with the corresponding untreated recyclates. Finally, by combining degassing and melt compounding with zeolites, the best result was obtained for the composite Fil-S/13X, whose Average Odor Intensity resulted as quite close (+22%) to the one of the virgin LDPE

Preparation and characterization of conductive foams based on PBS, carbon nanofibers and expanded graphite nanocomposites

Recently, conductive polymeric foams have aroused considerable research interest owing to their attractive properties associated with conventional polymers and unique electronic properties of metals or semiconductors. Large surface area, lower density and higher specific properties make them promising candidates for broad applications in energy conversion and storage, sensors, actuators, and biomedical devices. This work reports on the preparation and characterization of novel conductive polymeric foams based on a biodegradable polymer (Polybutylene succinate, PBS) and carbon nanoparticles (carbon nanofibres and expanded graphite). Foaming has been performed on PBS/CNF and PBS/CNF/EG nanocomposites using a batch process by using supercritical CO2as blowing agent. The control of foaming parameters allowed to prepare foams with tailored morphologies, and cellular structures with macro to micro sized cells were obtained. An in deep discussion about the general design rules, advantages, and also the actual limitations of such novel conductive polymeric foams are provided. Results demonstrate their potential applications as active electrode materials for next-generation biodegradable energy storage

Methylammonium-free co-evaporated perovskite absorbers with high radiation and UV tolerance: an option for in-space manufacturing of space-PV? †

With a remarkable tolerance to high-energetic radiation and potential high power-to-weight ratios, halide perovskite-based solar cells are interesting for future space PV applications. In this work, we fabricate and test methylammonium-free, co-evaporated FA0.7Cs0.3Pb(I0.9Br0.1)3 perovskite solar cells that could potentially be fabricated in space or on the Moon by physical vapor deposition, making use of the available vacuum present. The absence of methylammonium hereby increased the UV-light stability significantly, an important factor considering the increased UV proportion in the extra-terrestrial solar spectrum. We then tested their radiation tolerance under high energetic proton irradiation and found that the PCE degraded to 0.79 of its initial value due to coloring of the glass substrate, a typical problem that often complicates analysis. To disentangle damage mechanisms and to assess whether the perovskite degraded, we employ injection-current-dependent electroluminescence (EL) and intensity-dependent VOC measurements to derive pseudo-JV curves that are independent of parasitic effects. This way we identify a high radiation tolerance with 0.96 of the initial PCE remaining after 1 × 1013 p+ cm−2 which is beyond today's space material systems (<0.8) and on par with those of previously tested solution-processed perovskite solar cells. Together our results render co-evaporated perovskites as highly interesting candidates for future space manufacturing, while the pseudo-JV methodology presents an important tool to disentangle parasitic effects

Methylammonium-free co-evaporated perovskite absorbers with high radiation and UV tolerance: an option for in-space manufacturing of space-PV?

With a remarkable tolerance to high-energetic radiation and potential high power-to-weight ratios, halide perovskite-based solar cells are interesting for future space PV applications. In this work, we fabricate and test methylammonium-free, co-evaporated FA0.7Cs0.3Pb(I0.9Br0.1)3 perovskite solar cells that could potentially be fabricated in space or on the Moon by physical vapor deposition, making use of the available vacuum present. The absence of methylammonium hereby increased the UV-light stability significantly, an important factor considering the increased UV proportion in the extra-terrestrial solar spectrum. We then tested their radiation tolerance under high energetic proton irradiation and found that the PCE degraded to 0.79 of its initial value due to coloring of the glass substrate, a typical problem that often complicates analysis. To disentangle damage mechanisms and to assess whether the perovskite degraded, we employ injection-current-dependent electroluminescence (EL) and intensity-dependent VOC measurements to derive pseudo-JV curves that are independent of parasitic effects. This way we identify a high radiation tolerance with 0.96 of the initial PCE remaining after 1 × 1013 p+ cm−2 which is beyond today's space material systems (&lt;0.8) and on par with those of previously tested solution-processed perovskite solar cells. Together our results render co-evaporated perovskites as highly interesting candidates for future space manufacturing, while the pseudo-JV methodology presents an important tool to disentangle parasitic effects

Radiation Tolerant All-Perovskite Multijunction Solar Cells for Moon, Mars and Deep Space Applications

In this presentation, we discuss all-perovskite tandem solar cells that offer low-weight, high-efficiency, and high power-weight attributes, about five times larger than commercially available, industry-standard III-V semiconductor on Ge triple-junction space solar cells. We show that all-perovskite tandem PV possesses a remarkable radiation tolerance. Our tests under 68 MeV proton irradiation revealed negligible degradation (&lt; 6 %) at a dose of 1013p+cm2. Their resilience thus exceeds not only previously tested perovskite/CIGS tandem PV1 but also commercially available radiation-hardened space PV (&gt; 22%) that we tested under identical conditions. Using sub-cell selective high-spatial-resolution PL microscopy &amp; intensity dependant absolute PL measurements, we then bring to light the fundamentally different origin of radiation damage in traditional III-V semiconductor-based PV systems compared to halide perovskite-based tandem PV. Pseudo-JV measurements constructed from optically measured quasi-Fermi level (QFLS) splitting of high-and low-gap perovskite absorbers prior to and after proton irradiation reveal no degradation, suggesting that further improvements of their radiation resilience are possible with optimized contact layers