24 research outputs found
Submicron polyacrolein particles in situ embedded with upconversion nanoparticles for bioassay
We report a new surface modification approach of upconversion nanoparticles (UCNPs) structured as inorganic hosts NaYF4 codoped with Yb3+ and Er3+ based on their encapsulation in a two-stage process of precipitation polymerization of acrolein under alkaline conditions in the presence of UCNPs. The use of tetramethylammonium hydroxide both as an initiator of acrolein polymerization and as an agent for UCNP hydrophilization made it possible to increase the polyacrolein yield up to 90%. This approach enabled the facile, lossless embedment of UCNPs into the polymer particles suitable for bioassay. These particles are readily dispersible in aqueous and physiological buffers, exhibiting excellent photoluminescence properties, chemical stability, and also allow the control of particle diameters. The feasibility of the as-produced photoluminescent polymer particles mean-sized 260 nm for in vivo optical whole-animal imaging was also demonstrated using a home-built epi-luminescence imaging system
An iterative algorithm for parametrization of shortest length shift registers over finite rings
The construction of shortest feedback shift registers for a finite sequence
S_1,...,S_N is considered over the finite ring Z_{p^r}. A novel algorithm is
presented that yields a parametrization of all shortest feedback shift
registers for the sequence of numbers S_1,...,S_N, thus solving an open problem
in the literature. The algorithm iteratively processes each number, starting
with S_1, and constructs at each step a particular type of minimal Gr\"obner
basis. The construction involves a simple update rule at each step which leads
to computational efficiency. It is shown that the algorithm simultaneously
computes a similar parametrization for the reciprocal sequence S_N,...,S_1.Comment: Submitte
Emergent Phenomena Induced by Spin-Orbit Coupling at Surfaces and Interfaces
Spin-orbit coupling (SOC) describes the relativistic interaction between the
spin and momentum degrees of freedom of electrons, and is central to the rich
phenomena observed in condensed matter systems. In recent years, new phases of
matter have emerged from the interplay between SOC and low dimensionality, such
as chiral spin textures and spin-polarized surface and interface states. These
low-dimensional SOC-based realizations are typically robust and can be
exploited at room temperature. Here we discuss SOC as a means of producing such
fundamentally new physical phenomena in thin films and heterostructures. We put
into context the technological promise of these material classes for developing
spin-based device applications at room temperature