1,194 research outputs found
Studies on the Removal of Sulfides from Wastewater
In the present work a thorough and systematic study has been made on the removal of sulfides by oxidation and precipitation methods. Both synthetically prepared sulfide solution and industrial waste water sample containing sulfide were treated by this method in the present investigations.
Iodometric and spectrophotometeric methods were used for the analysis of sulfide and sulfur bearing other radicals. The treatment was carried out by aeration in the presence of UV light, oxidation by hydrogen peroxide in the presence of ferric oxide catalyst, precipitation using iron salts followed by aeration and aeration in the presence of ultrasonic vibration. Aeration in the presence of UV light was found to be
very effective for the removal of sulfide. The effects of sulfide concentration and partial pressure of oxygen on the kinetics of oxidation of sulfide under specific UV light intensity was investigated. Sulfide oxidation was found to be faster at higher UV light intensity. The catalyst synthesized for the oxidation of sulfide was analyzed by XRD, FT-IR, SEM and EDX. The precipitate formed in the treatment process was also analyzed following the above mentioned techniques. SEM analysis of ferric oxide synthesized by sol-gel technique revealed that the average particle size of the sample was less than 200nm. The XRD picture of the catalyst reveals that the presence of non-stiochiometric ferric oxide appears as a major crystalline phase. In the FT-IR spectra of the catalyst sample stretching vibration of FE-O was observed in different regions. Oxidation of sulfide by hydrogen peroxide in the presence of synthesized ferric oxide catalyst was also found to be very effective.
The effects of sulfide concentration, catalyst loading, hydrogen peroxide dosing and temperature were investigated on the kinetics of sulfide oxidation. Sulfide oxidation by hydrogen peroxide in the presence of catalyst was found to be faster with the increase in temperature. Before oxidation initially the sulfide solution was highly alkaline (pH =11-12) and during oxidation the solution became almost neutral (pH=7-8). It was observed that by precipitation more than 70% of sulfide was removed from the wastewater. Complete removal of sulfide was achieved by aeration in the presence of precipitate formed. From the SEM picture of the precipitate formed no distinct or definite size of the particle was observed. Average particle size of the precipitate was found to be 500nm. From the EDX analysis of the precipitate, it was confirmed that Fe and S were the major elements present in the sample. Some amount of Na and Cl were also observed in the sample.
Aeration in the presence of ultrasonic vibration has also been carried out for the removal of sulfide. The effects of air flow rate and sulfide concentration were investigated on the kinetics of sulfide oxidation.
Oxidation was carried out at different ultrasonic vibration frequencies. Rate of sulfide oxidation was found faster at higher air flow rate and sulfide concentration.
The results of this study are expected to be useful for the assessment of different alternatives for the removal of sulfide as well as for actual remediation of sulfidic wastewater in chemical and allied industries
The Effects of Associative Interference, Stimulus Type, and Item Familiarity on Associative Recognition Memory
This study investigated whether recognition memory requires two retrieval processes (i.e., familiarity and recognition) as stated by the Dual process theory or requires one retrieval process (i.e., familiarity) as stated by the Single process theory. The first experiment investigated the effects of A-B, A-C, A-D-, A-E interference on both word and picture pair recognition. As expected, it was found that a picture superiority effect was present in the baseline condition, but was reduced in the interference condition. Moreover, in the baseline condition, a non-mirror pattern (i.e., hits higher for picture pairs, but false alarm rates were the same) was present indicating picture pairs were encoding better than word pairs, however recall to reject strategy was the same. Furthermore, for both types of stimuli, false alarm rates and estimates of familiarity-based hit rates increased in the interference condition. The second experiment investigated the effects of interference on false alarm rates occurred not due to the fan effect, but due to the familiarity of items in the overlapping pairs. Familiarity increased hit rates but did not affect false alarm rates for word pairs. Interestingly, familiarity had an effect on false alarm rates for picture pairs. In Experiment 3, a more extreme manipulation of item familiarity was used in Experiment 3 provided more conclusive findings than Experiment 2 supporting the theory that the effects of interference on hit rates and false alarm rates were in accordance with Kelley and Wixted’s (2001) “some-or-none” model. Experiment 4 was similar in design and procedure as Experiment 1, however the two conditions were general and specific sentence conditions. The general sentence condtiion contained a general noun and specific location (i.e. the furniture is in the jungle). And the specific sentence condition contained a specific subject noun which was an instantiation of teh general subject noun (i.e., the desk is in the jungle). Supporting the Dual process theory and similar to Experiment 1, there was a non-mirror pattern present in baseline condition. There were significantly higher hit rates present in the specific sentence condition than the general sentence condition. However, false alarm rates were the same for both sentence conditions. In addition, similar to Experiment 1, estimates of familiarity significantly increased in the interference condition for both types of stimuli. Overall, the results provide strong support for the theory that item familiarity eliminated the advantage in recognition performance for distinctive stimuli in associative recognition
AN INVESTIGATION OF THE INCREASED RELIANCE ON FAMILIARITY IN ASSOCIATIVE RECOGNITION OF UNITIZED COMPOUND WORD PAIRS
Unitization refers to when two components are integrated or combined into a single unit. So the whole is more familiar than the parts (Graf & Schacter, 1989). Previous researchers have shown unitization of unrelated word pairs can occur by the use of compound definition. As support, they have found unitization to increase reliance on familiarity in associative recognition. The purpose of this PhD dissertation was to examine the effects of unitization of preexperimental associations on associative recognition. The effects of associative recognition of unitized compound word (CW) pairs can serve as a useful benchmark to compare to that of other methods of unitization. In Chapter 2, I present findings from Manuscript 1 consisting of five experiments in which I investigated the effects of unitization of CW pairs on associative recognition. In Experiment 1, I found a CW effect as in higher hit rates and false alarm rates for CW compared to noncompound word (NCW) pairs. In addition, there was no discrimination difference between CW and NCW pairs. In Experiments 2a and 2b, I show from both a non-speeded and speeded forced-choice test that when response bias is minimized, participants show a discrimination advantage for CW pairs. In Experiments 3a and 3b, I show that item recognition is reduced for CW compared to NCW pairs, but when components of the CW and NCW pairs are emphasized at encoding, similar item recognition is shown for both pair types. Lastly, in Experiment 5, I show from receiver operating characteristic (ROC) curves that there is a discrimination advantage for repeated NCW pairs compared to CW and NCW pairs. In Chapter 3, I present findings from Manuscript 2 consisting of three experiments in which I investigated the effects of unitization of CW pairs on associative recognition in older adults. In Experiment 1, older adults showed a discrimination advantage for CW pairs. Moreover, when presentation time was reduced young adults still did not show a discrimination advantage for CW pairs. Finally, in Experiment 3, I found both young and older adults showed a discrimination advantage for CW pairs in the forced-choice test. Thus, unitization of CW pairs benefited older adults because of ease of encoding and allowing increased use of familiarity during recognition. In addition, test format influences younger adults’ use of familiarity. Lastly, in Chapter 4, I present findings from Manuscript 3 consisting of three experiments examining whether processing fluency of unitized CW pairs was associated with the greater use of familiarity. In Experiment 1, minimizing perceptual fluency did not influence the CW effect. In Experiment 2B, I found there was no difference in CW effect between the more conceptual fluent transparent CW than opaque CW pairs. In conclusion, I show there are many effects of unitization of preexperimental associations on associative recognition and there are a number of factors that can determine if there is a benefit of unitization to associative memory. The results provide a set of benchmarks that can be used in the evaluation of different procedures designed to unitize random word pairs
Identity Crisis in Hanif Kureshi’s My Son the Fanatic
Postcolonial subjects find it difficult to self-define their identities in territories of colonizers. Study implies the postcolonial ideology of Kaletha that “search of identity has become a pressing fact in the global world” (02) upon Hanif Kureshi’s short story My Son The Fanatic. Asians migrated to the Britain colonies tend to mimic the white residents in order to discover their identities by assimilating with the dominant culture. The colonial subject reconstructs themselves in all social domains of tradition, customs, behavioral pattern, and language in order to assimilate in Britain society. Assimilation can only occurs when any black resident of society tries to abandon his personal ethnic identity in favor to adopt ideals of Britain society
Cash Conversion Cycle Management in Auto Mobile Industry: Relationship with Firm Performance, Leverage, Liquidity and Capital Employed
The business entities seek for different tools to maximize the shareholder wealth. The management of cash conversion cycle is one of the tools that play an essential role to generate maximum earnings to business firm. The recent paper is an effort to find out the different determinants that persuade cash cycle in automobile division in Pakistan. This industry provides employment opportunities to more than 192000 people directly and 1200000 indirectly. The data of eleven companies from this sector is analyzed to establish a relationship between profitability, leverage, capital employed, liquidity and cash conversion cycle. The data selected for this purpose ranges between 2008 and 2013. Multiple linear regression model is adopted for results. The outputs confirm that a negative considerable relation exists between return on assets, liquidity and cash cycle, whilst leverage and capital employed present a positive significant association with cash conversion cycle. Keywords: Cash Conversion Cycle (CCC), Profitability, Liquidity, Leverage (debt) and Capital Employe
Deficiency Analysis of Writing Skills with reference to Civil Judges in Pakistan
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This paper is an attempt to analyze the deficiency in writing skills with reference to Civil Judges in Pakistan. The purpose is to provide a solution in the light of the findings of the research: recommendation of a specific course. In the introduction, the paper describes the structure of judiciary in Pakistan, states the problem, provides the objective of research, and introduces the research carried out. Next, review of literature has been presented. This is followed by sections on research methodology, data analysis, and overall findings. Subsequently, the paper ends with recommendations.</p
Impact of Corporate Governance on Islamic Banking: Evidence from Pakistan
Purpose- The intention of this experiential research is to investigate corporate governance effects on capital structure of all KSE listed firm in Pakistan. Design/methodology/approach: Through expending wide-ranging sample of listed companies of Karachi stock exchange and through applying regression model in which fixed effect techniques has been used in order to get results and analyses the relationship between corporate governance and capital structure. Findings: Finding shows that Board meetings are negatively correlated with short-term debt. ROA and CEO Duality are negatively correlated with long-term debt. Rest all variables are positively correlated with capital structure. Practical Implications: The outcomes of this study are very helpful for all managers on all levels to better understand the corporate governance rules and their importance as well as also helpful for work effectively and efficiently in Pakistan environment. Study is also supportive for further more studies on this topic. Originality/value: The study involves short-term debt ratio as corporate structure measure of listed companies in Karachi stock exchange in Pakistan. Keywords: Corporate Governance, Capital structure, Islamic Banks
Identity Crisis in Hanif Kureshi’s My Son the Fanatic
Postcolonial subjects find it difficult to self-define their identities in territories of colonizers. Study implies the postcolonial ideology of Kaletha that “search of identity has become a pressing fact in the global world” (02) upon Hanif Kureshi’s short story My Son The Fanatic. Asians migrated to the Britain colonies tend to mimic the white residents in order to discover their identities by assimilating with the dominant culture. The colonial subject reconstructs themselves in all social domains of tradition, customs, behavioral pattern, and language in order to assimilate in Britain society. Assimilation can only occurs when any black resident of society tries to abandon his personal ethnic identity in favor to adopt ideals of Britain society
The Functions of Code Switching in ESL Classroom Discourse
This study objective to investigate the discourse functions of code-switching used by the teachers in ESL classrooms in a Pakistani university. Another aim of this study was to find out the forms of code-switching used by the teachers and functions of these code-switching usages at diploma level. In the light of these aims, four diploma classes were observed and audio recorded. The data obtained from these recordings were transcribed using the content analysis method and the following results have been obtained: 1) teachers use code-switching in the classes for educational and social reasons; 2) the most frequent form of code-switching was observed to be used discourse markers. Keywords: Function of Code-switching, Classroom discourse
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