The reaction NH2 + PH3 yields NH3 + PH2: Absolute rate constant measurement and implication for NH3 and PH3 photochemistry in the atmosphere of Jupiter

The rate constant is measured over the temperature interval 218-456 K using the technique of flash photolysis-laser-induced fluorescence. NH2 radicals are produced by the flash photolysis of ammonia highly diluted in argon, and the decay of fluorescent NH2 photons is measured by multiscaling techniques. For each of the five temperatures employed in the study, the results are shown to be independent of variations in PH3 concentration, total pressure (argon), and flash intensity. It is found that the rate constant results are best represented for T between 218 and 456 K by the expression k = (1.52 + or - 0.16) x 10 to the -12th exp(-928 + or - 56/T) cu cm per molecule per sec; the error quoted is 1 standard deviation. This is the first determination of the rate constant for the reaction NH2 + PH3. The data are compared with an estimate made in order to explain results of the radiolysis of NH3-PH3 mixtures. The Arrhenius parameters determined here for NH2 + PH3 are then constrasted with those for the corresponding reactions of H and OH with PH3

Afterglows from precursors in Gamma Ray Bursts. Application to the optical afterglow of GRB 091024

About 15% of Gamma Ray Bursts have precursors, i.e. emission episodes preceding the main event, whose spectral and temporal properties are similar to the main emission. We propose that precursors have their own fireball, producing afterglow emission due to the dissipation of the kinetic energy via external shock. In the time lapse between the precursor and the main event, we assume that the central engine is not completely turned off, but it continues to eject relativistic material at a smaller rate, whose emission is below the background level. The precursor fireball generates a first afterglow by the interaction with the external circumburst medium. Matter injected by the central engine during the "quasi-quiescent" phase replenishes the external medium with material in relativistic motion. The fireball corresponding to the main prompt emission episode crashes with this moving material, producing a second afterglow, and finally catches up and merges with the first precursor fireball. We apply this new model to GRB 091024, an event with a precursor in the prompt light curve and two well defined bumps in the optical afterglow, obtaining an excellent agreement with the existing data.Comment: 11 pages, 6 figures, 3 tables. Accepted for publication in MNRAS, Main Journa

Ocorrência da mosca dos favos Pseudohpocera kerteszi (Diptera: Phoridae) em colméias de abelhas melíferas africanizadas no Rio Grande do Sul.

bitstream/item/31359/1/comunicado-178.pdfMeta: 2008

Primeiro relato de Drosophila suzukii (Diptera: Drosophilidae) em frutos de araçá e pitanga em municípios da região sul do Rio Grande do Sul, Brasil.

O objetivo do estudo foi relatar a ocorrência de D. suzukii em frutíferas mirtáceas em municípios da região sul do Rio Grande do Sul, Brasil

Ocorrência de tefritídeos em Passiflora caerulea em Pelotas e Capão do Leão, RS, Brasil.

O objetivo do estudo foi determinar a(s) espécie(s) de tefritídeo(s) coletado(s) em P. caerulea

Cosmological constraints with GRBs: homogeneous medium vs wind density profile

We present the constraints on the cosmological parameters obtained with the $E_{\rm peak}$--$E_{\gamma}$ correlation found with the most recent sample of 19 GRBs with spectroscopically measured redshift and well determined prompt emission spectral and afterglow parameters. We compare our results obtained in the two possible uniform jet scenarios, i.e. assuming a homogeneous density profile (HM) or a wind density profile (WM) for the circumburst medium. Better constraints on $\Omega_{M}$ and $\Omega_{\Lambda}$ are obtained with the (tighter) $E_{\rm peak}$--$E_{\gamma}$ correlation derived in the wind density scenario. We explore the improvements to the constraints of the cosmological parameters that could be reached with a large sample, $\sim$ 150 GRBs, in the future. We study the possibility to calibrate the slope of these correlations. Our optimization analysis suggests that $\sim 12$ GRBs with redshift $z\in(0.9,1.1)$ can be used to calibrate the $E_{\rm peak}$--$E_{\gamma}$ with a precision better than 1%. The same precision is expected for the same number of bursts with $z\in(0.45,0.75)$. This result suggests that we do not necessarily need a large sample of low z GRBs for calibrating the slope of these correlations.Comment: 7 pages, 7 figures, submitted to A&

Rate constant for the reaction of hydroxyl radical with formaldehyde over the temperature range 228-362 K

Absolute rate constants for the reaction OH ? H2CO measured over the temperature range 228-362 K using the flash photolysis-resonance fluorescence technique are given. The results are independent of variations in H2CO concentration, total pressure Ar concentration, and flash intensity (i.e., initial OH concentration). The rate constant is found to be invariant with temperature in this range, the best representation being k sub 1 = (1.05 ? or - 0.11) x 10 to the 11th power cu cm molecule(-1) s(-1) where the error is two standard deviations. This result is compared with previous absolute and relative determinations of k sub 1. The reaction is also discussed from a theoretical point of view

Rate constant for the reaction NH2 + NO from 216 to 480 K

The absolute rate constant was measured by the technique of flash photolysis-laser induced fluorescence (FP-LIF). NH2 radicals were produced by the flash photolysis of ammonia and the fluorescent NH2 photons were measured by multiscaling techniques. At each temperature, the results were independent of variations in total pressure, and flash intensity. The results are compared with previous determinations using the techniques of mass spectrometry, absorption spectroscopy, laser absorption spectroscopy, and laser induced fluorescence. The implications of the results are discussed with regard to combustion, post combustion, and atmospheric chemistry. The results are also discussed theoretically

Upper atmosphere research: Reaction rate and optical measurements

The objective is to provide photochemical, kinetic, and spectroscopic information necessary for photochemical models of the Earth's upper atmosphere and to examine reactions or reactants not presently in the models to either confirm the correctness of their exclusion or provide evidence to justify future inclusion in the models. New initiatives are being taken in technique development (many of them laser based) and in the application of established techniques to address gaps in the photochemical/kinetic data base, as well as to provide increasingly reliable information

The reaction Cl + H2CO yields HCl + HCO: Decreased sensitivity of stratospheric ozone to chlorine perturbations

The absolute rate constant for the reaction Cl + H2CO yields HCl + HCO was determined by the flash-photolysis resonance fluorescence method to be 7.5 plus or minus 0.9 (2 sigma) times 10 to the minus 11th power cu cm/molecule sec at 298 K and to have a negligible temperature dependence. This rate which is more than 2000 times faster than the rate of Cl + CH4 indicates that formaldehyde (H2CO) will compete significantly with methane (CH4) for the conversion of active chlorine in the stratosphere to the inactive reservoir HCl. Chlorine will thus be a less efficient destroyer of stratosphere ozone than previously believed. Ambient stratospheric ozone will depend less on the ambient chlorine amount and the predicted response to chlorine perturbations will be lessened. One-dimensional eddy-diffusion photochemical model calculations indicate a factor of 1.1 less sensitivity to chlorine than recently reported. For a steady-state CFM release at 1975 rates (750,000 tons/year) the eventual ozone depletion is now calculated to be 14%