(E)-2,4,7-Trichloro-3-hydr­oxy-8-meth­oxy-1,9-dimethyl-6-(1-methyl-1-propen­yl)-11H-dibenzo[b,e][1,4]dioxepin-11-one monohydrate (nidulin monohydrate)

In the title compound, C20H17Cl3O5·H2O, the nidulin mol­ecule consists of three rings, the folded central dioxepin-11-one ring being fused on both sides to phenyl rings. The mol­ecular structure is stabilized by intra­molecular O—H⋯Cl and C—H⋯Cl hydrogen bonds that generate S(6) ring motifs. The crystal structure is stabilized by inter­molecular O—H⋯O and O—H⋯(O,O) hydrogen bonds mediated by two inversion-related water mol­ecules, generating R 4 2(8) ring and C 2 2(4) chain motifs. Weak inter­molecular Cl⋯O halogen bonds are also present with Cl⋯O distances of 3.071 (1) and 3.182 (2) Å

11-(3-Chloro-2-hydroxy­prop­oxy)-2,3,9-trimethoxy­chromeno[3,4-b]chromen-12(6H)-one

In the title compound, C22H21ClO8, the rotenoid core is nearly planar (r.m.s. deviation 0.114 Å), with the largest deviations from the least-squares plane being 0.286 (3) and 0.274 (2) Å. An inter­molecular O—H⋯O hydrogen bond links two mol­ecules into a centrosymmetric dimer having an R 2 2(18) ring motif