Ferroelectric properties of Pb(Zr,Ti)O<inf>3</inf> films under ion-beam induced strain

The influence of an ion-beam induced biaxial stress on the ferroelectric and dielectric properties of Pb(Zr,Ti)O3 (PZT) films is investigated using the ion beam process as a novel approach to control external stress. Tensile stress is observed to decrease the polarization, permittivity, and ferroelectric fatigue resistance of the PZT films whose structure is monoclinic. However, a compressive stress increases all of them in monoclinic PZT films. The dependence of the permittivity on stress is found not to follow the phenomenological theory relating external forces to intrinsic properties of ferroelectric materials. Changes in the ferroelectric and dielectric properties indicate that the application of a biaxial stress modulates both extrinsic and intrinsic properties of PZT films. Different degrees of dielectric non-linearity suggests the density and mobility of non-180o domain walls, and the domain switching can be controlled by an applied biaxial stress and thereby influence the ferroelectric and dielectric properties. © 2012 American Institute of Physics

Parametric performance analysis and energy model calibration workflow integration - A scalable approach for buildings

High efficiency paradigms and rigorous normative standards for new and existing buildings are fundamental components of sustainability and energy transitions strategies today. However, optimistic assumptions and simplifications are often considered in the design phase and, even when detailed simulation tools are used, the validation of simulation results remains an issue. Further, empirical evidences indicate that the gap between predicted and measured performance can be quite large owing to different types of errors made in the building life cycle phases. Consequently, the discrepancy between a priori performance assessment and a posteriori measured performance can hinder the development and diffusion of energy efficiency practices, especially considering the investment risk. The approach proposed in the research is rooted on the integration of parametric simulation techniques, adopted in the design phase, and inverse modelling techniques applied in Measurement and Verification (M&amp;V) practice, i.e., model calibration, in the operation phase. The research focuses on the analysis of these technical aspects for a Passive House case study, showing an efficient and transparent way to link design and operation performance analysis, reducing effort in modelling and monitoring. The approach can be used to detect and highlight the impact of critical assumptions in the design phase as well as to guarantee the robustness of energy performance management in the operational phase, providing parametric performance boundaries to ease monitoring process and identification of insights in a simple, robust and scalable way

Open data and models for energy and environment

An increasing number of data sources and models to handle them call for transparency and openness in assessing their goodness and practical use for people. The simplest and most robust tools to collect, process, and analyse data to offer solid data-based evidence for future projections in building and district and regional system planning are of interest. For this purpose, and following the success of the first Special Issue “Open Data and Energy Analytics”, the Special Issue “Open Data and Models for Energy and Environment” has been launched, intended for energy engineers and planners. Among a very high number of submissions, 10 articles were selected for acceptance and published

Open data and energy analytics

This pioneering Special Issue aims at providing the state-of-the-art on open energy data analytics; its availability in the different contexts, i.e., country peculiarities; and at different scales, i.e., building, district, and regional for data-aware planning and policy-making. Ten high-quality papers were published after a demanding peer review process and are commented on in this Editorial

Coexistence of two- and three-dimensional Shubnikov-de Haas oscillations in Ar^+ -irradiated KTaO_3

We report the electron doping in the surface vicinity of KTaO_3 by inducing oxygen-vacancies via Ar^+ -irradiation. The doped electrons have high mobility (> 10^4 cm^2/Vs) at low temperatures, and exhibit Shubnikov-de Haas oscillations with both two- and three-dimensional components. A disparity of the extracted in-plane effective mass, compared to the bulk values, suggests mixing of the orbital characters. Our observations demonstrate that Ar^+ -irradiation serves as a flexible tool to study low dimensional quantum transport in 5d semiconducting oxides

Molecular dynamics simulation of brittle fracture in silicon

The fracture process involves converting potential energy from a strained body into surface energy, thermal energy, and the energy needed to create lattice defects. In dynamic fracture, energy is also initially converted into kinetic energy. This paper uses molecular dynamics (MD) to simulate brittle frcture in silicon and determine how energy is converted from potential energy (strain energy) into other forms

Are the Organoid Models an Invaluable Contribution to ZIKA Virus Research?

Abstract: In order to prevent new pathogen outbreaks and avoid possible new global health threats, it is important to study the mechanisms of microbial pathogenesis, screen new antiviral agents and test new vaccines using the best methods. In the last decade, organoids have provided a groundbreaking opportunity for modeling pathogen infections in human brains, including Zika virus (ZIKV) infection. ZIKV is a member of the Flavivirus genus, and it is recognized as an emerging infectious agent and a serious threat to global health. Organoids are 3D complex cellular models that offer an inscale organ that is physiologically alike to the original one, useful for exploring the mechanisms behind pathogens infection; additionally, organoids integrate data generated in vitro with traditional tools and often support those obtained in vivo with animal model. In this mini-review the value of organoids for ZIKV research is examined and sustained by the most recent literature. Within a 3D viewpoint, tissue engineered models are proposed as future biological systems to help in deciphering pathogenic processes and evaluate preventive and therapeutic strategies against ZIKV. The next steps in this field constitute a challenge that may protect people and future generations from severe brain defect

Stress-induced platelet formation in silicon:a molecular dynamics study

The effect of stress on vacancy cluster configurations in silicon is examined using molecular dynamics. At zero pressure, the shape and stability of the vacancy clusters agrees with previous atomistic results. When stress is applied the orientation of small planar clusters changes to reduce the strain energy. The preferred orientation for the vacancy clusters under stress agrees with the experimentally observed orientations of hydrogen platelets in the high stress regions of hydrogen implanted silicon. These results suggest a theory for hydrogen platelet formation

Mechanical Response of He- Implanted Amorphous SiOC/ Crystalline Fe Nanolaminates

This study investigates the microstructural evolution and mechanical response of sputter-deposited amorphous silicon oxycarbide (SiOC)/crystalline Fe nanolaminates, a single layer SiOC film, and a single layer Fe film subjected to ion implantation at room temperature to obtain a maximum He concentration of 5 at. %. X-ray diffraction and transmission electron microscopy indicated no evidence of implantation-induced phase transformation or layer breakdown in the nanolaminates. Implantation resulted in the formation of He bubbles and an increase in the average size of the Fe grains in the individual Fe layers of the nanolaminates and the single layer Fe film, but the bubble density and grain size were found to be smaller in the former. By reducing the thicknesses of individual layers in the nanolaminates, bubble density and grain size were further decreased. No He bubbles were observed in the SiOC layers of the nanolaminates and the single layer SiOC film. Nanoindentation and scanning probe microscopy revealed an increase in the hardness of both single layer SiOC and Fe films after implantation. For the nanolaminates, changes in hardness were found to depend on the thicknesses of the individual layers, where reducing the layer thickness to 14 nm resulted in mitigation of implantation-induced hardening