6,082 research outputs found

    Electronic Tuning of Mixed Quinoidal‐Aromatic Conjugated Polyelectrolytes: Direct Ionic Substitution on Polymer Main‐Chains

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    The synthesis of conjugated polymers with ionic substituents directly bound to their main chain repeat units is a strategy for generating strongly electron-accepting conjugated polyelectrolytes, as demonstrated through the synthesis of a series of ionic azaquinodimethane (iAQM) compounds. The introduction of cationic substituents onto the quinoidal para-azaquinodimethane (AQM) core gives rise to a strongly electron-accepting building block, which can be employed in the synthesis of ionic small molecules and conjugated polyelectrolytes (CPEs). Electrochemical measurements alongside theoretical calculations indicate notably low-lying LUMO values for the iAQMs. The optical band gaps measured for these compounds are highly tunable based on structure, ranging from 2.30 eV in small molecules down to 1.22 eV in polymers. The iAQM small molecules and CPEs showcase the band gap reduction effects of combining the donor-acceptor strategy with the bond-length alternation reduction strategy. As a demonstration of their utility, the iAQM CPEs so generated were used as active agents in photothermal therapy

    Uncovering many-body correlations in nanoscale nuclear spin baths by central spin decoherence

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    Many-body correlations can yield key insights into the nature of interacting systems; however, detecting them is often very challenging in many-particle physics, especially in nanoscale systems. Here, taking a phosphorus donor electron spin in a natural-abundance 29Si nuclear spin bath as our model system, we discover both theoretically and experimentally that many-body correlations in nanoscale nuclear spin baths produce identifiable signatures in the decoherence of the central spin under multiple-pulse dynamical decoupling control. We find that when the number of decoupling -pulses is odd, central spin decoherence is primarily driven by second-order nuclear spin correlations (pairwise flip-flop processes). In contrast, when the number of -pulses is even, fourth-order nuclear spin correlations (diagonal interaction renormalized pairwise flip-flop processes) are principally responsible for the central spin decoherence. Many-body correlations of different orders can thus be selectively detected by central spin decoherence under different dynamical decoupling controls, providing a useful approach to probing many-body processes in nanoscale nuclear spin baths

    Development of Competency Indexes to Assess Nursing Postgraduate's Tutor

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    The aim of this study was to develop competency indexes assessing nursingpostgraduate's tutor in China. Based on Iceberg competency theory, a Delphisurvey was carried out. 30 nursing experts in 16 provinces of China wereinvited to rate the importance of indexes and give some comments on thecontent. There were 22 experts taking part in two rounds Delphi study. AKendall's W test also demonstrated experts were well coordinated. Duringthe first round, overall mean scores were high, except for 1 tertiary index.We also added and moved some indexes building on the experts'suggestions. After two rounds, we developed competency indexesappropriate to assess tutots' competencies, consisting of 5 preliminaryindexes, 13 secondary indexes and 68 tertiary indexes. The competencyindexes were validated and scientific, it can be used to assess tutors in China

    Next-to-leading-order corrections to exclusive processes in kTk_T factorization

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    We calculate next-to-leading-order (NLO) corrections to exclusive processes in kTk_T factorization theorem, taking πγγ\pi\gamma^*\to\gamma as an example. Partons off-shell by kT2k_T^2 are considered in both the quark diagrams from full QCD and the effective diagrams for the pion wave function. The gauge dependences in the above two sets of diagrams cancel, when deriving the kTk_T-dependent hard kernel as their difference. The gauge invariance of the hard kernel is then proven to all orders by induction. The light-cone singularities in the kTk_T-dependent pion wave function are regularized by rotating the Wilson lines away from the light cone. This regularization introduces a factorization-scheme dependence into the hard kernel, which can be minimized in the standard way. Both the large double logarithms ln2kT\ln^2k_T and ln2x\ln^2 x, xx being a parton momentum fraction, arise from the loop correction to the virtual photon vertex, the former being absorbed into the pion wave function and organized by the kTk_T resummation, and the latter absorbed into a jet function and organized by the threshold resummation. The NLO corrections are found to be only few-percent for πγγ\pi\gamma^*\to\gamma, if setting the factorization scale to the momentum transfer from the virtual photon.Comment: 13 pages; version to appear in Physical Review

    Scaling in directed dynamical small-world networks with random responses

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    A dynamical model of small-world network, with directed links which describe various correlations in social and natural phenomena, is presented. Random responses of every site to the imput message are introduced to simulate real systems. The interplay of these ingredients results in collective dynamical evolution of a spin-like variable S(t) of the whole network. In the present model, global average spreading length \langel L >_s and average spreading time _s are found to scale as p^-\alpha ln N with different exponents. Meanwhile, S behaves in a duple scaling form for N>>N^*: S ~ f(p^-\beta q^\gamma t'_sc), where p and q are rewiring and external parameters, \alpha, \beta, \gamma and f(t'_sc) are scaling exponents and universal functions, respectively. Possible applications of the model are discussed.Comment: 4 pages, 6 Figure

    Negotiating Agency and Control: Theorizing Human-Machine Communication from a Structurational Perspective

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    Intelligent technologies have the potential to transform organizations and organizing processes. In particular, they are unique from prior organizational technologies in that they reposition technology as agent rather than a tool or object of use. Scholars studying human-machine communication (HMC) have begun to theorize the dual role played by human and machine agency, but they have focused primarily on the individual level. Drawing on Structuration Theory (Giddens, 1984), we propose a theoretical framework to explain agency in HMC as a process involving the negotiation of control between human and machine agents. This article contributes to HMC scholarship by offering a framework and research agenda to guide future theory-building and research on the use of intelligent technologies in organizational contexts

    Exoskeletons and the Future of Work: Envisioning Power and Control in a Workforce Without Limits

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    Exoskeletons are an emerging form of technology that combines the skills of both machines and humans to give wearers the ability to complete physically demanding tasks that would be too strenuous for most humans. Exoskeleton adoption has the potential to both enhance and disrupt many aspects of work, including power dynamics in the workplace and the human-machine interactions that take place. Dyadic Power Theory (DPT) is a useful theory for exploring the impacts of exoskeleton adoption. In this conceptual paper, we extend DPT to relationships between humans and machines in organizations, as well as human-human communication where use of an exoskeleton has resulted in shifts of power

    Controlled tuning of whispering gallery modes of GaN/InGaN microdisk cavities

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    Controlled tuning of the whispering gallery modes of GaN/InGaN {\mu}-disk cavities is demonstrated. The whispering gallery mode (WGM) tuning is achieved at room temperature by immersing the {\mu}-disks in water and irradiating with ultraviolet (UV) laser. The tuning rate can be controlled by varying the laser excitation power, with a nanometer precision accessible at low excitation power (~ several {\mu}W). The selective oxidation mechanism is proposed to explain the results and supported by theoretical analysis. The tuning of WGMs in GaN/InGaN {\mu}-disk cavities may have important implication in cavity quantum electrodynamics and the development of efficient light emitting devices

    A full free spectral range tuning of p-i-n doped Gallium Nitride microdisk cavity

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    Effective, permanent tuning of the whispering gallery modes (WGMs) of p-i-n doped GaN microdisk cavity with embedded InGaN quantum dots over one free spectral range is successfully demonstrated by irradiating the microdisks with a ultraviolet laser (380nm) in DI water. For incident laser powers between 150 and 960 nW, the tuning rate varies linearly. Etching of the top surface of the cavity is proposed as the driving force for the observed shift in WGMs, and is supported by experiments. The tuning for GaN/InGaN microdisk cavities is an important step for deterministically realizing novel nanophotonic devices for studying cavity quantum electrodynamics
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