579 research outputs found
SIG como ferramenta de planejamento de uso de águas subterrâneas no município de Santa Rosa do Piauí-PI.
Este trabalho teve como objetivo avaliar o aquífero subterrâneo do Município de Santa Rosa do Piauí-PI delimitando com uso de ferramentas de geoprocessamento e SIG a superfície potenciométrica, a variação de STD e a descarga de sólidos a partir de dados medidos de poços instalados no município..
Sensitivity studies on the photolysis rates calculation in Amazonian atmospheric chemistry ? Part I: The impact of the direct radiative effect of biomass burning aerosol particles
International audienceThe impact of the direct radiative effect of the aerosol particles on the calculation of the photolysis rates and consequently on the atmospheric chemistry in regional smoke clouds due to biomass burning over the Amazon basin is addressed in this work. It explores a case study for 19 September 2002 at LBA-RACCI-SMOCC (The Large-Scale Biosphere-Atmosphere experiment in Amazonia ? Radiation, Cloud, and Climate Interactions ? Smoke, Aerosols, Clouds, Rainfall and Climate) pasture site in SW Amazonia. The Tropospheric Ultraviolet Visible radiation model (TUV) version 4.2, (Madronich et al., 1987) is used for the photolysis rates calculation considering the layer aerosol optical depth from the Coupled Aerosol Tracer Transport model to the Brazilian Regional Atmospheric Modeling System (CATT-BRAMS) (Freitas et al., 2005). A dynamical aerosol model (Procópio et al., 2003) is included in the radiative transfer model to take into account the high temporal variability of the aerosol optical thickness. This methodology is tested by comparing modeled and measured clear sky solar irradiances. The results show a good agreement with measured PAR radiation values. The actinic flux attenuation, for AOT (500 nm) values around 1.94, decreases the photolysis rates by about 70% in the presence of near-ground smoke aerosol and above the smoke layer the photolysis process tends to increase by about 40%. A simulation of the ozone production is carried out using a one-dimensional photochemical box model and comparisons with observation are shown
Produção simultânea de -fructofuranosidase e fructo-oligossacarídeos por Penicillium citreonigrum URM 4459
O objetivo deste trabalho foi a produção simultânea de -Frutofuranosidase (FFase) e frutooligossacarídeos (FOS) por P. citreonigrum utilizando um planejamento fatorial completo. Para isso, o fungo foi cultivado em meio rico em sacarose (20% p/v) a 150 rpm. As condições de tempo de fermentação, temperatura, pH e concentração de extrato de levedura foram definidas utilizando um planejamento fatorial. Ao fim da fermentação, o sobrenadante obtido por filtração foi utilizado para quantificação de FFase e FOS. Todas as variáveis independentes estudadas exerceram efeito estatisticamente significativo sob a produção de FFase. Por outro lado, apenas as variáveis tempo de fermentação e temperatura exerceram efeito significativo sob a produção do FOS. As condições ideais para produção simultânea de FFase e FOS foram obtidas na região dos pontos centrais, onde obteve-se uma produção média de 93,49 g/L de FOS e uma atividade de 260,40 U/mL de FFase
Machine-assisted Cyber Threat Analysis using Conceptual Knowledge Discovery
Over the last years, computer networks have evolved into highly dynamic and interconnected environments, involving multiple heterogeneous devices and providing a myriad of services on top of them. This complex landscape has made it extremely difficult for security administrators to keep accurate and be effective in protecting their systems against cyber threats. In this paper, we describe our vision and scientific posture on how artificial intelligence techniques and a smart use of security knowledge may assist system administrators in better defending their networks. To that end, we put forward a research roadmap involving three complimentary axes, namely, (I) the use of FCA-based mechanisms for managing configuration vulnerabilities, (II) the exploitation of knowledge representation techniques for automated security reasoning, and (III) the design of a cyber threat intelligence mechanism as a CKDD process. Then, we describe a machine-assisted process for cyber threat analysis which provides a holistic perspective of how these three research axes are integrated together
Classical Infinite-Range-Interaction Heisenberg Ferromagnetic Model: Metastability and Sensitivity to Initial Conditions
A N-sized inertial classical Heisenberg ferromagnet, which consists in a
modification of the well-known standard model, where the spins are replaced by
classical rotators, is studied in the limit of infinite-range interactions. The
usual canonical-ensemble mean-field solution of the inertial classical
-vector ferromagnet (for which recovers the particular Heisenberg
model considered herein) is briefly reviewed, showing the well-known
second-order phase transition. This Heisenberg model is studied numerically
within the microcanonical ensemble, through molecular dynamics.Comment: 18 pages text, and 7 EPS figure
Stress distribution and the fragility of supercooled melts
We formulate a minimal ansatz for local stress distribution in a solid that
includes the possibility of strongly anharmonic short-length motions. We
discover a broken-symmetry metastable phase that exhibits an aperiodic,
frozen-in stress distribution. This aperiodic metastable phase is characterized
by many distinct, nearly degenerate configurations. The activated transitions
between the configurations are mapped onto the dynamics of a long range
classical Heisenberg model with 6-component spins and anisotropic couplings. We
argue the metastable phase corresponds to a deeply supercooled non-polymeric,
non-metallic liquid, and further establish an order parameter for the
glass-to-crystal transition. The spin model itself exhibits a continuous range
of behaviors between two limits corresponding to frozen-in shear and uniform
compression/dilation respectively. The two regimes are separated by a
continuous transition controlled by the anisotropy in the spin-spin
interaction, which is directly related to the Poisson ratio of the
material. The latter ratio and the ultra-violet cutoff of the theory determine
the liquid configurational entropy. Our results suggest that liquid's fragility
depends on the Poisson ratio in a non-monotonic way. The present ansatz
provides a microscopic framework for computing the configurational entropy and
relaxational spectrum of specific substances.Comment: 11 pages, 5 figures, Final version published in J Phys Chem
Black hole thermodynamical entropy
As early as 1902, Gibbs pointed out that systems whose partition function
diverges, e.g. gravitation, lie outside the validity of the Boltzmann-Gibbs
(BG) theory. Consistently, since the pioneering Bekenstein-Hawking results,
physically meaningful evidence (e.g., the holographic principle) has
accumulated that the BG entropy of a black hole is
proportional to its area ( being a characteristic linear length), and
not to its volume . Similarly it exists the \emph{area law}, so named
because, for a wide class of strongly quantum-entangled -dimensional
systems, is proportional to if , and to if
, instead of being proportional to (). These results
violate the extensivity of the thermodynamical entropy of a -dimensional
system. This thermodynamical inconsistency disappears if we realize that the
thermodynamical entropy of such nonstandard systems is \emph{not} to be
identified with the BG {\it additive} entropy but with appropriately
generalized {\it nonadditive} entropies. Indeed, the celebrated usefulness of
the BG entropy is founded on hypothesis such as relatively weak probabilistic
correlations (and their connections to ergodicity, which by no means can be
assumed as a general rule of nature). Here we introduce a generalized entropy
which, for the Schwarzschild black hole and the area law, can solve the
thermodynamic puzzle.Comment: 7 pages, 2 figures. Accepted for publication in EPJ
The Brazilian Earth System Model ocean–atmosphere (BESM-OA) version 2.5: evaluation of its CMIP5 historical simulation
The performance of the coupled ocean–atmosphere component of the Brazilian Earth System
Model version 2.5 (BESM-OA2.5) was evaluated in simulating the historical period
1850–2005. After a climate model validation procedure in which the main atmospheric and
oceanic variabilities were evaluated against observed and reanalysis datasets, the
evaluation specifically focused on the mean climate state and the most important
large-scale climate variability patterns simulated in the historical run, which was
forced by the observed greenhouse gas concentration. The most significant upgrades in the
model's components are also briefly presented here. BESM-OA2.5 could reproduce the most
important large-scale variabilities, particularly over the Atlantic Ocean (e.g., the
North Atlantic Oscillation, the Atlantic Meridional Mode, and the Atlantic Meridional
Overturning Circulation), and the extratropical modes that occur in both hemispheres. The
model's ability to simulate such large-scale variabilities supports its usefulness for
seasonal climate prediction and in climate change studies.</p
Modulating the photoluminescence of bridged silsesquioxanes incorporating Eu(3+)-complexed n,n '-diureido-2,2 '-bipyridine isomers: application for luminescent solar concentrators
Two new urea-bipyridine derived bridged organosilanes (P5 and P6) have been synthesized and their hydrolysis-condensation under nucleophilic catalysis in the presence of Eu(3+) salts led to luminescent bridged silsesquioxanes (M5-Eu and M6-Eu). An important loading of Eu(3+) (up to 11%(w)) can be obtained for the material based on the 6,6'-isomer. Indeed the photoluminescence properties of these materials, that have been investigated in depth (photoluminescence (PL), quantum yield, lifetimes), show a significantly different complexation mode of the Eu(3+) ions for M6-Eu, compared with M4-Eu (obtained from the already-reported 4,4'-isomer) and M5-Eu. Moreover, M6-Eu exhibits the highest absolute emission quantum yield value (0.18 +/- 0.02) among these three materials. The modification of the sol composition upon the addition of a malonamide derivative led to similar luminescent features but with an increased quantum yield (026 +/- 0.03). In addition, M6-Eu can be processed as thin films by spin-coating on glass substrates, leading to plates coated by a thin layer (similar to 54 nm) of Eu(3+)-containing hybrid silica exhibiting one of the highest emission quantum yields reported so far for films of Eu(3+)-containing hybrids (0.34 +/- 0.03) and an interesting potential as new luminescent solar concentrators (LSCs) with an optical conversion efficiency of similar to 4%. The ratio between the light guided to the film edges and the one emitted by the surface of the film was quantified through the mapping of the intensity of the red pixels (in the RGB color model) from a film image. This quantification enabled a more accurate estimation of the transport losses due to the scattering of the emitted light in the film (0.40), thereby correcting the initial optical conversion efficiency to a value of 1.7%.FCT - PTDC/CTM/101324/2008COMPETEFEDE
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