Can One-Run-Fixed-Arrhenius Kerogen Analysis Provide Comparable Organofacies Results to Detailed Palynological Analysis? A Case Study from a Prospective Mississippian Source Rock Reservoir (Bowland Shale, UK)

Organofacies analysis, a fundamental component within source rock appraisal based on the study of kerogen within a source rock, is typically produced from microscopy (palynological) and geochemical (kerogen kinetic) data, both of which are costly to acquire. One-Run-Fixed-Arrhenius (ORFA) kerogen kinetic analysis based on Rock–Eval pyrolysis offers a substantially cheaper kinetic dataset. Here, ORFA and palynological analyses are compared in organofacies characterization of a prospective Mississippian source rock reservoir (Bowland Shale, UK). Two-end-member organofacies were determined based on the abundance of the 56 kcal/mol activation energy peak derived from ORFA data: absence ( 15%) indicating ‘organofacies B’ containing the highest proportion of sporomorphs (Type II kerogen). A mud-dominated slope setting for the rock reservoir was also used to test the accuracy of organofacies analysis in determining depositional environment. Organofacies A found within lithofacies deposited from dilute waning density flows and hemipelagic suspension settling occurred between shelf edge, slope and basin. Organofacies B found within lithofacies deposited from dilute waning density flows, and low-strength cohesive debrites occurred only within the lower slope. This study demonstrates that ORFA kerogen kinetic analysis provides comparable net results to palynological analysis, enabling cheaper and faster organic characterization during initial source rock appraisal. However, caution must be exercised in drawing interpretations as to biological source(s), organic matter mixing and preservation state(s) without additional investigation using data from detailed palynological analysis

Comparative Assessment of Insulation Materials for Improving Indoor Air Quality in Building Retrofit

This paper evaluates the impacts of different insulation materials on Indoor Air Quality (IAQ) and occupant health with a focus on the Volatile Organic Compound (VOC) emissions. The main aim is to identify options that minimize exposure rates while improving IAQ and energy in retrofitted buildings. A comprehensive literature review was conducted synthesizing scholarly articles, guidelines from international organizations, and information on pollutants, IAQ standards, and retrofit strategies. The findings show high emission rates for some insulation materials that could negatively affect health. Hemp insulation in contrast was identified as a promising solution exhibiting low VOC emissions compared to other insulation materials. As sustainable construction practices advance, hemp insulation emerges as a viable retrofit strategy for social housing by synergistically addressing performance gaps related to energy conservation, air quality, and thermal comfort. The synthesis of evidence from this paper suggests that, from environmental and public health perspectives, certain insulation materials are preferable for improving IAQ and reducing the risk of exposure to indoor air pollutants in retrofitted buildings

Influence of waste glass in the foaming process of open cell porous ceramic as filtration media for industrial wastewater

This paper reports the development and testing results of a prototype ceramic filter with excellent sorption properties (<99% elimination in 5 min) leading to good efficacy in the removal of industrial contaminants (Reactive Bezaktiv Turquoise Blue V-G (BTB) dye). The novelty in the investigation lies in developing the filter material obtained from the recycling of waste glass combined with highly porous open-cell clay material. This newly developed material showed a significant reduction in the energy requirements (sintering temperature required for the production of industrial filters) thus addressing the grand challenge of sustainable and cleaner manufacturing. The methodology entails sintering of the clay foam (CF) at temperatures ranging from 800 to 1050 °C and blending it with 5%, 7% and 10 wt% milled glass cullet. One of the aims of this investigation was to evaluate and analyse the effect of the pH of the solution, contact time and equilibrium isotherm on the sorption process and the mechanical compressive strength, porosity, water uptake. From the kinetic studies, it was discovered that the experimental results were well aligned with the pseudo-second-order model and chemisorption was discovered to be a mechanism driving the adsorption process. These findings are crucial in designing cost-effective industrial filtration system since the filter material being proposed in this work is reusable, recyclable and readily available in abundance. Overall, the pathway for the reuse of waste glass shown by this work help address the sustainability targets set by the UN Charter via SDG 6 and SDG 12

Evaluating Thermal Comfort and Overheating Risks in A Social Housing Prototype: As-Built Versus Retrofit Scenarios

Climate change has highlighted the importance of thermal comfort and its health-related outcomes, particularly for the most vulnerable members of society living in social housing. Due to their vulnerable living conditions, low-income people are more exposed to negative outcomes of overheating and cold indoor temperatures in buildings. Previous studies suggest that there is a significant risk of overheating in retrofitted buildings both for the current and future weather scenarios. The UK government has introduced new building regulations to assess and limit the risk of overheating in new buildings; however, there is still a need to assess and improve conditions for existing and retrofitted properties. This study aims to evaluate the effect of retrofit strategies on thermal comfort and the risk of overheating in social housing under current and future climatic conditions. A typical case study building was simulated in DesignBuilder to assess thermal comfort conditions for upgraded building fabric to Part L of the UK building regulations and Passive House standards. The summer results were analyzed according to CIBSE TM59 while the Predicted Mean Vote index (PMV) was used for winter analysis. Findings revealed that the south-facing bedrooms are most exposed to overheating. Risk of overheating significantly increased for the future weather scenarios by up to 10 times while winter thermal comfort improved for the retrofitted scenarios

Charles Wesley in Ireland (1747-1748): A reconstruction from primary sources

This article uses previously unresearched primary materials relating to Charles Wesley's two visits to Ireland in 1747 and 1748. It contains a reconstruction of his time during these visits and provides some analysis of the progress of the very earliest Methodist societies, mainly in Dublin and Cork. It contains annotated transcriptions of six of the seven documents concerned, which helps the reader to gain an overall picture of Charles Wesley's time in Ireland and the progress of the nascent Methodist movement

Empirical modeling of low-frequency dispersive effects due to traps and thermal phenomena in III-V FET's

The modeling of low-frequency dispersive effects due to surface state densities, deep level traps and thermal phenomena plays an important role in the large-signal performance prediction of III-V FET's. This paper describes an empirical modeling approach to accurately predict deviations between static and dynamic drain current characteristics caused by dispersive effects in III-V devices operating at microwave frequencies. It is based on reasonable assumptions and can easily be embedded in nonlinear FET models to be used in Harmonic-Balance tools for circuit analysis and design. Experimental and simulated results, for HEMT's and GaAs MESFET's of different manufacturers, that confirm the validity of the new approach, are presented and discussed together with the characterization procedures require

Patient-Centered Endodontic Outcomes: A Narrative Review

Introduction: Root canal treatment (RCT) success criteria inform us of the path to bony healing and of prognostic factors, but tell little about how the patient perceives, feels, or values RCT. Patients choose, undergo, and pay for RCT, they live with the result, and inform their community. The purpose of this narrative review was to appraise patient-centered outcomes of initial non-surgical RCT and nonsurgical retreatment, in adults. Materials and Methods: Patient-centered RCT outcome themes were identified in the extant literature: quality of life, satisfaction, anxiety, fear, pain, tooth survival and cost. Narrative review was applied because the disparate themes and data were unsuited to systematic review or meta-analysis. Results: Application of the Oral Health Impact Profile (OHIP) demonstrated that disease of pulpal origin affects quality of life with moderate severity, primarily through physical pain and psychological discomfort, and that RCT results in broad improvement of quality of life. Satisfaction with RCT is extremely high, but cost is the primary reason for dissatisfaction. Anxiety and fear affect RCT patients, profoundly influencing their behaviors, including treatment avoidance, and their pain experience. Fear of pain is “fair” to “very much” prior to RCT. Pain is widely feared, disliked, and remembered; however, disease of pulpal origin generally produces moderate, but not severe pain. RCT causes a dramatic decrease in pain prevalence and severity over the week following treatment. Survival rates of teeth after RCT are very high; complication rates are low. Cost is a barrier to RCT, but initial costs, lifetime costs, cost effectiveness, cost utility, and cost benefit all compare extremely well to the alternatives involving replacement using implants or fixed prostheses. Conclusion: Dentists must strive to reduce anxiety, fear, experienced and remembered pain, and to accurately inform and educate their patients with respect to technical, practical and psychosocial aspects of RCT

Sedimentology and microfacies of a mud-rich slope succession: in the Carboniferous Bowland Basin, NW England (UK)

A paucity of studies on mud-rich basin slope successions has resulted in a significant gap in our sedimentological understanding in these settings. Here, macro- and micro-scale analysis of mudstone composition, texture and organic matter was undertaken on a continuous core through a mud-dominated slope succession from the Marl Hill area in the Carboniferous Bowland Basin. Six lithofacies, all dominated by turbidites and debrites, combine into three basin slope facies associations: sediment-starved slope, slope dominated by low-density turbidites and slope dominated by debrites. Variation in slope sedimentation was a function of relative sea-level change, with the sediment-starved slope occurring during maximum flooding of the contemporaneous shelf, and the transition towards a slope dominated by turbidites and then debrites occurring during normal or forced shoreline progradation towards the shelf margin. The sediment-starved slope succession is dominated by Type II kerogen, whereas the slope dominated by low-density turbidites is dominated by Type III kerogen. This study suggests that mud-dominated lower slope settings are largely active depositional sites, with consistent evidence for sediment traction. Additionally, the composition and texture of basin slope mudstones, as well as organic content, vary predictably as a function of shelf processes linked to relative sea-level change