27,043 research outputs found
Do Hydrogen-Deficient Carbon Stars Have Winds?
We present high resolution spectra of the five known hydrogen-deficient carbon (HdC) stars in the vicinity of the 10830 angstrom line of neutral helium. In R Coronae Borealis (RCB) stars the He I line is known to be strong and broad, often with a P Cygni profile, and must be formed in the powerful winds of those stars. RCB stars have similar chemical abundances as HdC stars and also share greatly enhanced O-18 abundances with them, indicating a common origin for these two classes of stars, which has been suggested to be white dwarf mergers. A narrow He I absorption line may be present in the hotter HdC stars, but no line is seen in the cooler stars, and no evidence for a wind is found in any of them. The presence of wind lines in the RCB stars is strongly correlated with dust formation episodes so the absence of wind lines in the HdC stars, which do not make dust, is as expected.NSFScience and Technology FacilitiesCouncilthe National Research CouncilCONICYTAustralian Research CouncilMinistï¾´erio da Ciï¾´encia e TecnologiaSECYTMcDonald Observator
Magnetic and electron transport properties of the rare-earth cobaltates, La0.7-xLnxCa0.3CoO3 (Ln = Pr, Nd, Gd and Dy) : A case of phase separation
Magnetic and electrical properties of four series of rare earth cobaltates of
the formula La0.7-xLnxCa0.3CoO3 with Ln = Pr, Nd, Gd and Dy have been
investigated. Compositions close to x = 0.0 contain large ferromagnetic
clusters or domains, and show Brillouin-like behaviour of the field-cooled DC
magnetization data with fairly high ferromagnetic Tc values, besides low
electrical resistivities with near-zero temperature coefficients. The
zero-field-cooled data generally show a non-monotonic behaviour with a peak at
a temperatures slightly lower than Tc. The near x = 0.0 compositions show a
prominent peak corresponding to the Tc in the AC-susceptibility data. The
ferromagnetic Tc varies linearly with x or the average radius of the A-site
cations, (rA). With increase in x or decrease in (rA), the magnetization value
at any given temperature decreases markedly and the AC-susceptibility
measurements show a prominent transition arising from small magnetic clusters
with some characteristics of a spin-glass. Electrical resistivity increases
with increase in x, showed a significant increase around a critical value of x
or (rA), at which composition the small clusters also begin to dominate. These
properties can be understood in terms of a phase separation scenario wherein
large magnetic clusters give way to smaller ones with increase in x, with both
types of clusters being present in certain compositions. The changes in
magnetic and electrical properties occur parallely since the large
ferromagnetic clusters are hole-rich and the small clusters are hole-poor.
Variable-range hopping seems to occur at low temperatures in these cobaltates.Comment: 23 pages including figure
Catalytic activity of nickel ferrite nanoparticles in synthesis of 4-aryl benzelidene-2- ((5-fluoro-1H-indol-1-yl)methyl)oxazol-5(4H)-one and its evalute the biological activity
ABSTRACT. Seven 4-arylbenzelidene-2-((5-fluoro-1H-indol-1-yl)methyl)oxazol-5(4H)-one derivatives were synthesized by the condensation of 2-(2-(5-fluoro-1H-indol-1-yl) acetoamide) acetic acid, substituted aromatic aldehydes with acetic anhydride and sodium acetate in the presence of MgO/Al2O3 under reflux using nickel ferrite nanoparticles. Seven of the compounds are new derivatives. 2-(2-(5-fluoro-1H-indol-1-yl)acetoamide) acetic acid was obtained from 2-(5-fluoro-1H-indol-1-yl)acetyl chloride with lysine in the presence of NaOH and HCl in the ice cold solution. 2-(5-fluoro-1H-indol-1-yl)acetyl chloride can be prepared from 5-fluoro indole with chloroacetyl chloride in triethylamine and dichloromethane. The structures of the compounds were evaluated based on 1H-NMR, 13C-NMR and LC-MS and by elemental analysis. These compounds were screened by anti-oxidant as well as anti-microbial activity.               KEY WORDS: 2-(5-Fluoro-1H-indol-1-yl)acetyl chloride, 2-(2-(5-Fluoro-1H-indol-1-yl)acetoamide) acetic acid, 4-Aryl Benzelidene-2-((5-fluoro-1H-indol-1-yl)methyl)oxazol-5(4H)-one, Anti-oxidant, Anti-microbial activity, Nickel ferrite Bull. Chem. Soc. Ethiop. 2019, 33(3), 517-526.  DOI: https://dx.doi.org/10.4314/bcse.v33i3.1
Hot Core, Outflows and Magnetic Fields in W43-MM1 (G30.79 FIR 10)
We present submillimeter spectral line and dust continuum polarization
observations of a remarkable hot core and multiple outflows in the high-mass
star-forming region W43-MM1 (G30.79 FIR 10), obtained using the Submillimeter
Array (SMA). A temperature of 400 K is estimated for the hot-core using
CHCN (J=19-18) lines, with detections of 11 K-ladder components. The high
temperature and the mass estimates for the outflows indicate high-mass
star-formation. The continuum polarization pattern shows an ordered
distribution, and its orientation over the main outflow appears aligned to the
outflow. The derived magnetic field indicates slightly super-critical
conditions. While the magnetic and outflow energies are comparable, the B-field
orientation appears to have changed from parsec scales to 0.1 pc scales
during the core/star-formation process.Comment: accepted, ApJ Letter
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