Force and energy dissipation variations in non-contact atomic force spectroscopy on composite carbon nanotube systems

UHV dynamic force and energy dissipation spectroscopy in non-contact atomic force microscopy were used to probe specific interactions with composite systems formed by encapsulating inorganic compounds inside single-walled carbon nanotubes. It is found that forces due to nano-scale van der Waals interaction can be made to decrease by combining an Ag core and a carbon nanotube shell in the Ag@SWNT system. This specific behaviour was attributed to a significantly different effective dielectric function compared to the individual constituents, evaluated using a simple core-shell optical model. Energy dissipation measurements showed that by filling dissipation increases, explained here by softening of C-C bonds resulting in a more deformable nanotube cage. Thus, filled and unfilled nanotubes can be discriminated based on force and dissipation measurements. These findings have two different implications for potential applications: tuning the effective optical properties and tuning the interaction force for molecular absorption by appropriately choosing the filling with respect to the nanotube.Comment: 22 pages, 6 figure

Growth and Structure of Stochastic Sequences

We introduce a class of stochastic integer sequences. In these sequences, every element is a sum of two previous elements, at least one of which is chosen randomly. The interplay between randomness and memory underlying these sequences leads to a wide variety of behaviors ranging from stretched exponential to log-normal to algebraic growth. Interestingly, the set of all possible sequence values has an intricate structure.Comment: 4 pages, 4 figure

Improved Quantum Hard-Sphere Ground-State Equations of State

The London ground-state energy formula as a function of number density for a system of identical boson hard spheres, corrected for the reduced mass of a pair of particles in a sphere-of-influence picture, and generalized to fermion hard-sphere systems with two and four intrinsic degrees of freedom, has a double-pole at the ultimate \textit{regular} (or periodic, e.g., face-centered-cubic) close-packing density usually associated with a crystalline branch. Improved fluid branches are contructed based upon exact, field-theoretic perturbation-theory low-density expansions for many-boson and many-fermion systems, appropriately extrapolated to intermediate densities, but whose ultimate density is irregular or \textit{random} closest close-packing as suggested in studies of a classical system of hard spheres. Results show substantially improved agreement with the best available Green-function Monte Carlo and diffusion Monte Carlo simulations for bosons, as well as with ladder, variational Fermi hypernetted chain, and so-called L-expansion data for two-component fermions.Comment: 15 pages and 7 figure

Reply to Isgur's Comments on Valence QCD

We reply to Nathan Isgur's critique that is directed at some of the conclusions drawn from the lattice simulation of valence QCD, regarding the valence quark model and effective chiral theories.Comment: 12 pages, 6 figure

Moderate Resolution Spitzer Infrared Spectrograph (IRS) Observations of M, L, and T Dwarfs

We present 10 - 19 um moderate resolution spectra of ten M dwarfs, one L dwarf, and two T dwarf systems obtained with the Infrared Spectrograph (IRS) onboard the Spitzer Space Telescope. The IRS allows us to examine molecular spectroscopic features/lines at moderate spectral resolution in a heretofore untapped wavelength regime. These R~600 spectra allow for a more detailed examination of clouds, non-equilibrium chemistry, as well as the molecular features of H2O, NH3, and other trace molecular species that are the hallmarks of these objects. A cloud-free model best fits our mid-infrared spectrum of the T1 dwarf epsilon Indi Ba, and we find that the NH3 feature in epsilon Indi Bb is best explained by a non-equilibrium abundance due to vertical transport in its atmosphere. We examined a set of objects (mostly M dwarfs) in multiple systems to look for evidence of emission features, which might indicate an atmospheric temperature inversion, as well as trace molecular species; however, we found no evidence of either.Comment: 19 pages, 7 figures, accepted ApJ 1/12/0

PAH emission from Herbig AeBe stars

We present spectra of a sample of Herbig Ae and Be (HAeBe) stars obtained with the Infrared Spectrograph on the Spitzer Space Telescope. All but one of the Herbig stars show emission from polycyclic aromatic hydrocarbons (PAHs) and seven of the spectra show PAH emission, but no silicate emission at 10 microns. The central wavelengths of the 6.2, 7.7--8.2, and 11.3 micron emission features decrease with stellar temperature, indicating that the PAHs are less photo-processed in cooler radiation fields. The apparent low level of photo processing in HAeBe stars, relative to other PAH emission sources, implies that the PAHs are newly exposed to the UV-optical radiation fields from their host stars. HAeBe stars show a variety of PAH emission intensities and ionization fractions, but a narrow range of PAH spectral classifications based on positions of major PAH feature centers. This may indicate that, regardless of their locations relative to the stars, the PAH molecules are altered by the same physical processes in the proto-planetary disks of intermediate-mass stars. Analysis of the mid-IR spectral energy distributions indicates that our sample likely includes both radially flared and more flattened/settled disk systems, but we do not see the expected correlation of overall PAH emission with disk geometry. We suggest that the strength of PAH emission from HAeBe stars may depend not only on the degree of radial flaring, but also on the abundance of PAHs in illuminated regions of the disks and possibly on the vertical structure of the inner disk as well.Comment: 52 pages, 12 figure

S04-04 OA. HIV-specific responses induced by anti-CD40 targeting antibodies

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