Composition of Initiated Cracking Products of High-sulfur Natural Bitumen

The analysis of the cracking products of bitumen Karmalskoye deposits (the content of fractions boiling up to 200 °C 6,7% wt.) has been performed. The influence of power plant coal ash microspheres on orientation of cracking bitumen components is stated. Bitumen cracking leads to significant yields of gas and coke for more than 20% wt. and destructions of all components. The initiated bitumen cracking in the presence of 10% microspheres at cracking temperature 450 °C leads to reduction of gas and coke yields and increase in fractions of ibp (initial boiling point) –360 °C at 10% wt. in comparison with products of the thermal bitumen cracking. The analysis of composition and amount of sulfur compounds in initial bitumen and the cracking products in the various conditions has shown that the thermal cracking leads to increased homologues benzothiophene contents due to partial destruction of resins, and to decrease in the content of homologues dibenzothiophene

How Unsplittable-Flow-Covering helps Scheduling with Job-Dependent Cost Functions

Generalizing many well-known and natural scheduling problems, scheduling with job-specific cost functions has gained a lot of attention recently. In this setting, each job incurs a cost depending on its completion time, given by a private cost function, and one seeks to schedule the jobs to minimize the total sum of these costs. The framework captures many important scheduling objectives such as weighted flow time or weighted tardiness. Still, the general case as well as the mentioned special cases are far from being very well understood yet, even for only one machine. Aiming for better general understanding of this problem, in this paper we focus on the case of uniform job release dates on one machine for which the state of the art is a 4-approximation algorithm. This is true even for a special case that is equivalent to the covering version of the well-studied and prominent unsplittable flow on a path problem, which is interesting in its own right. For that covering problem, we present a quasi-polynomial time $(1+\epsilon)$-approximation algorithm that yields an $(e+\epsilon)$-approximation for the above scheduling problem. Moreover, for the latter we devise the best possible resource augmentation result regarding speed: a polynomial time algorithm which computes a solution with \emph{optimal }cost at $1+\epsilon$ speedup. Finally, we present an elegant QPTAS for the special case where the cost functions of the jobs fall into at most $\log n$ many classes. This algorithm allows the jobs even to have up to $\log n$ many distinct release dates.Comment: 2 pages, 1 figur

Composition of Pre-ozonated High-Sulfur Natural Bitumen Cracking Products

The results analysis of fractional and material composition of the cracking products of Ashalchinskoye and Karmalskoye bitumen deposits was presented in this work. The effect of bitumen ozone-oxygen mixture pretreatment followed by cracking on thermolysis processes was investigated. It was shown that molecules of resins and asphaltenes containing large amounts of aliphatic fragments in its structure readily undergo thermal decomposition to form additional distillate fractions. Low content of aliphatic fragments leads to aromatization of the naphthenic cycles in the molecule of resins and asphaltenes, the thermal degradation reactions proceed in high yields of gas and coke

Research on the possibility of extending the shelf life of cheese raw material and heat-treated cheese by their freezing for further use in HoReCa

The article presents the results of a study of the regularities of changes in the functional properties and quality indicators of heat-treated cheeses made from frozen cheese raw material or frozen after thermomechanical processing for further use in HoReCa. The objects of the study were: Caliatta cheese — a semi-hard ripening cheese intended as the main raw material in the production of heat-treated cheese, as well as heat-treated «pizzacheese», subjected to freezing at temperatures of minus 14 ±2 °Cand minus 55 ±2 °Cand low-temperature storage at a temperature of minus 14 ±2 °Cfor 270 days, followed by defrosting at a temperature of 20 ±2 °C. To confirm the possibility of using the freezing technique in order to increase the shelf life of both the original cheese raw material and heat-treated cheese, their microbiological and physicochemical indicators were determined by standardized methods. Studies of structural and mechanical (rheological) properties were carried out on a Weissenberg rheogoniometer, recording changes in the elastic modulus (G’) and dynamic viscosity (h’). The length of the cheese thread, as one of the main functional properties of the «pizza-cheese», was assessed with a fork test after baking. Organoleptic characteristics were assessed by flavor, texture and appearance. Research results have shown that low-temperature storage of frozen cheese can be considered as a way to retard biological and physicochemical changes, which is a safe way to increase shelf life. Freezing cheese raw material increases the length of the cheese thread in proportion to the temperature and duration of the low-temperature storage. When obtaining heat-treated cheese from both unfrozen and frozen cheese raw material, a significant deterioration in the desired functional properties is observed. Thus, the receipt of heat-treated cheese from the original cheese raw material for further use in the production of pizza is justified only by economic feasibility. Freezing «pizza-cheese» at a temperature of minus 55 ±2 °C, made from unfrozen cheese raw material, ensures the preservation of functional properties and increases the shelf life up to 150 days

Synthesis and application of cobalt and polyoxomolybdatecontaining alumina systems

The work is devoted to the synthesis and study of the activity of cobalt and polyoxomolybdate-containing alumina catalyst. The synthesized catalytic system was characterized using the following analysis methods: scanning electron microscopy, x-ray phase analysis, x-ray diffraction analysis, IR spectroscopy. It was found that the CoMo/Al[2]O[3] system is active in the hydrodesulfurization reaction of model raw materials

Review on uranium in soil: levels, migration

The problems of radioactive contamination of biosphere with the 238U in recent years have attracted a large number of experts in various fields of knowledge. Natural radionuclides are an integral part of the biosphere. They are concentrated everywhere: in rocks, in soil, water, air and food. Various types of phosphorus fertilizers and other natural ameliorants used in agriculture are also an additional source of heavy natural radionuclides. The review describes the behaviour and migration of 238U in biosphere, which depend on various factors acting simultaneously. It is noted that the behaviour of 238U in the soil depends on the forms of its presence in it and the physical and chemical properties of the soil. The processes of sorption and desorption of 238U by different soil types are significant indicators

Processing of heavy residual feedstock on Mo/Al[2]O[3]-catalytic systems obtained using polyoxomolybdate compounds

The urgency of creating new efficient catalysts for the processes of deepening oil refining rises on the background of stricter requirements for the quality of motor fuels, as well as the deterioration of the quality of crude oil for processing, and an increase in the number of distillates of secondary processes involved in the production of commodity petroleum products. In this work, alumina-catalytic systems were synthesized using polyoxomolybdate compounds. The morphology, structure and phase composition of the synthesized catalytic systems were studied using the following analysis methods: scanning electron microscopy, microelement analysis, X-ray phase analysis, X-ray diffraction, electron spectroscopy. It has been established that the Mo/AI[2]O[3] system is active in the process of thermal catalytic conversion of heavy residual raw materials

Effect of hydrogen-donor of heavy crude oil catalytic aquathermolysis in the presence of a nickel-based catalyst

The transformations of oil components from the Zyuzeevskoye field during catalytic aquathermolysis in the presence of a nickel-containing catalyst precursor and hydrogen donors were studied. It was found that the yield of gasoline and diesel fractions increased by more than 36% in the case of catalytic aquathermolysis in the presence of tetralin. The maximum conversion of asphaltenes was achieved with a simultaneous slowing down of coke formation by four times. The calculation of the structural-group parameters of initial asphaltenes and the products of thermal cracking and catalytic aquathermolysis was made, and the hypothetical construction of their molecular structures was proposed. It was established that the phase composition, ratio, and morphology of nickel catalysts after catalytic aquathermolysis (CA) and catalytic aquathermolysis with tetralin (CA+T) depend on the amount of “free” hydrogen and are represented by Ni0.96S and Ni9S8