Coherent radiation by molecular magnets

The possibility of coherent radiation by molecular magnets is investigated. It is shown that to realize the coherent radiation, it is necessary to couple the considered sample to a resonant electric circuit. A theory for describing this phenomenon is developed, based on a realistic microscopic Hamiltonian, including the Zeeman terms, single-site anisotropy, and dipole interactions. The role of hyperfine interactions between molecular and nuclear spins is studied. Numerical solutions of the spin evolution equations are presented.Comment: Latex file, 11 pages, 3 figure

The Competition between Staggered Field and Antiferromagnetic Interactions in Cugeo3:Fe

The EPR spectra along different crystallographic axes for single crystals of CuGeO3 containing 1% of Fe impurity have been studied in the frequency range 60-360 GHz at temperatures 0.5-30 K. The analysis based on the Oshikawa-Affleck (OA) theory suggests that the temperature dependences of the line width and g-factor are formed as a result of the competition between interchain antiferromagnetic interactions and staggered Zeeman energy. It is found that staggered magnetic moments in CuGeO3:Fe are located predominantly along b axis.Comment: 9 pages, 4 figures; submitted to QSS04 symposiu

Highly Strengthened Superconducting Magnet for a 40 T Compact Hybrid Magnet(Magnet Technology)

A 16 T outer superconducting magnet for a 40 T compact hybrid magnet is investigated. A highly strengthened superconducting magnet with a 360 mm room temperature bore can be made using newly developed (Nb, Ti)_3Sn wires with Cu-Al_2O_3 reinforcing stabilizer. The coil weight is outstandingly reduced by as much as 70 %

Water-Cooled Magnet for a 40T Compact Hybrid Magnet(Magnet Technology)

A water-cooled poly Bitter magnet for a new compact hybrid magnet was designed under the fully utilization of the electric power source of 8 MW and the cooling systems installed in the High Field Laboratory for Superconducting Materials, Tohoku University. Supposing copper-silver plates with high yield strength are used, a poly Bitter magnet can be designed. The magnet consists of four axial water-cooled Bitter coils which are electrically connected in series and all of cooling water flows from the bottom tc upper side of coils. The designed poly Bitter magnet will produce 24 T in the room temperature bore of 14 mm and can provide 40 T as a hybrid magnet with backup field of 16 T by the combined superconducting magne

Fluctuation-induced phase in CsCuCl3 in transverse magnetic field: Theory

CsCuCl3 is a quantum triangular antiferromagnet, ferromagnetically stacked, with an incommensurate (IC) structure due to a Dzyaloshinskii-Moriya interaction. Because of the classical degeneracy caused by the frustration, fluctuations in CsCuCl3 have extraordinarily large effects, such as the phase transition in longitudinal magnetic field (normal to the planes, parallel to the IC wavenumber q) and the plateau in q in transverse field (perpendicular to q). We argue that fluctuations are responsible also for the new IC phase discovered in transverse field near the Neel temperature T_N, by T. Werner et al. [Solid State Commun. 102, p.609 (1997)]. We develop and analyse the corresponding minimal Landau theory; the effects of fluctuations on the frustration are included phenomenologically, by means of a biquadratic term. The Landau theory gives two IC phases, one familiar from previous studies; properties of the new IC phase, which occupies a pocket of the temperature-field phase diagram near T_N, agree qualitatively with those of the new phase found experimentally.Comment: 12 pages, revtex, 4 postscript figures, submitted to J. Phys: Condens. Matte

Anomalous Spin Dynamics observed by High Frequency ESR in Honeycomb Lattice Antiferromagnet InCu2/3V1/3O3

High-frequency ESR results on the S=1/2 Heisenberg hexagonal antiferromagnet InCu2/3V1/3O3 are reported. This compound appears to be a rare model substance for the honeycomb lattice antiferromagnet with very weak interlayer couplings. The high-temperature magnetic susceptibility can be interpreted by the S=1/2 honeycomb lattice antiferromagnet, and it shows a magnetic-order-like anomaly at TN=38 K. Although, the resonance field of our high-frequency ESR shows the typical behavior of the antiferromagnetic resonance, the linewidth of our high-frequency ESR continues to increase below TN, while it tends to decrease as the temperature in a conventional three-dimensional antiferromagnet decreases. In general, a honeycomb lattice antiferromagnet is expected to show a simple antiferromagnetic order similar to that of a square lattice antiferromagnet theoretically because both antiferromagnets are bipartite lattices. However, we suggest that the observed anomalous spin dynamics below TN is the peculiar feature of the honeycomb lattice antiferromagnet that is not observed in the square lattice antiferromagnet.Comment: 5 pages, 5 figure

Mechanical properties of the compass depressors of the sea-urchin Paracentrotus lividus (Echinodermata, Echinoidea) and the effects of enzymes, neurotransmitters and synthetic tensilin-like protein

The compass depressors (CDs) of the sea-urchin lantern are ligaments consisting mainly of discontinuous collagen fibrils associated with a small population of myocytes. They are mutable collagenous structures, which can change their mechanical properties rapidly and reversibly under nervous control. The aims of this investigation were to characterise the baseline (i.e. unmanipulated) static mechanical properties of the CDs of Paracentrotus lividus by means of creep tests and incremental force-extension tests, and to determine the effects on their mechanical behaviour of a range of agents. Under constant load the CDs exhibited a three-phase creep curve, the mean coefficient of viscosity being 561±365 MPa.s. The stress-strain curve showed toe, linear and yield regions; the mean strain at the toe-linear inflection was 0.86±0.61; the mean Young's modulus was 18.62±10.30 MPa; and the mean tensile strength was 8.14±5.73 MPa. Hyaluronidase from Streptomyces hyalurolyticus had no effect on creep behaviour, whilst chondroitinase ABC prolonged primary creep but had no effect on secondary creep or on any force-extension parameters; it thus appears that neither hyaluronic acid nor sulphated glycosaminoglycans have an interfibrillar load transfer function in the CD. Acetylcholine, the muscarinic agonists arecoline and methacholine, and the nicotinic agonists nicotine and 1-[1-(3,4-dimethyl-phenyl)-ethyl]-piperazine produced an abrupt increase in CD viscosity; the CDs were not differentially sensitive to muscarinic or nicotinic agonists. CDs showed either no, or no consistent, response to adrenaline, L-glutamic acid, 5-hydroxytryptamine and γ-aminobutyric acid. Synthetic echinoid tensilin-like protein had a weak and inconsistent stiffening effect, indicating that, in contrast to holothurian tensilins, the echinoid molecule may not be involved in the regulation of collagenous tissue tensility. We compare in detail the mechanical behaviour of the CD with that of mammalian tendon and highlight its potential as a model system for investigating poorly understood aspects of the ontogeny and phylogeny of vertebrate collagenous tissues.(undefined)info:eu-repo/semantics/publishedVersio

Diverse and productive source of biopolymer inspiration: marine collagens

Marine biodiversity is expressed through the huge variety of vertebrate and invertebrate species inhabiting intertidal to deep-sea environments. The extraordinary variety of â forms and functionsâ  exhibited by marine animals suggests they are a promising source of bioactive molecules and provides potential inspiration for different biomimetic approaches. This diversity is familiar to biologists and has led to intensive investigation of metabolites, polysaccharides, and other compounds. However, marine collagens are less well-known. This review will provide detailed insight into the diversity of collagens present in marine species in terms of their genetics, structure, properties, and physiology. In the last part of the review the focus will be on the most common marine collagen sources and on the latest advances in the development of innovative materials exploiting, or inspired by, marine collagens.The authors are grateful for the financial support from European Union, under the scope of European Regional Development Fund((ERDF) through the POCTEP project 0687_NOVOMAR_1_P and Structured Project NORTE-01- 0145-FEDER-000021 and from the Portuguese Foundation for Science and Technology (FCT), under the scope of the BiogenInk project (M-ERA-NET2/0022/2016) and from the European Cooperation in Science & Technology program (EU COST). Grant title: “Stem cells of marine/aquatic inverte brates: from basic research to innovative applications” (MARISTEM). MSR acknowledges FCT for the Ph.D. scholarship (PD/BD/143091/2018)