Umklapp scattering of pairs in BCS superconductivity theory

The BCS theory of superconductivity is extended to recognize pairing of electrons by both normal and umklapp scattering. Application of the variational approach shows that coexistence of normal and umklapp scattering frustrates superconductivity.Comment: 9 pages, 5 figures. to be published in Journal of Physics: Condensed Matte

Fractional and unquantized dc voltage generation in THz-driven semiconductor superlattices

We consider the spontaneous creation of a dc voltage across a strongly coupled semiconductor superlattice subjected to THz radiation. We show that the dc voltage may be approximately proportional either to an integer or to a half- integer multiple of the frequency of the applied ac field, depending on the ratio of the characteristic scattering rates of conducting electrons. For the case of an ac field frequency less than the characteristic scattering rates, we demonstrate the generation of an unquantized dc voltage.Comment: 6 pages, 3 figures, RevTEX, EPSF. Revised version v3: corrected typo

New Use for a Corn By-product

Iowa farmers can expect satisfactory results when Iowa-produced hydrol is fed to dairy cows

Symmetry-breaking and chaos in electron transport in semiconductor superlattices

We study the motion of electrons in a single miniband of a semiconductor superlattice driven by THz electric field polarized along the growth direction. We work in the semiclassical balance-equation model, including different elastic and inelastic scattering rates, and incorporating the self-consistent electric field generated by electron motion. We explore regions of complex dynamics, which can include chaotic behaviour and symmetry-breaking. We estimate the magnitudes of dc current and dc voltage that spontaneously appear in regions of broken-symmetry for parameters characteristic of modern semiconductor superlattices. This work complements PRL 80(1998)2669 [ cond-mat/9709026 ].Comment: 4 pages, 3 figures, RevTEX, EPS

Z-Selective Cross-Metathesis and Homodimerization of 3E-1,3-Dienes: Reaction Optimization, Computational Analysis, and Synthetic Applications

Olefin metathesis reactions with 3E-1,3-dienes using Z-selective cyclometalated ruthenium benzylidene catalysts are described. In particular, a procedure for employing 3E-1,3-dienes in Z-selective homodimerization and cross-metathesis with terminal alkenes is detailed. The reaction takes advantage of the pronounced chemoselectivity of a recently reported ruthenium-based catalyst containing a cyclometalated NHC ligand for terminal alkenes in the presence of internal E-alkenes. A wide array of commonly encountered functional groups can be tolerated, and only a small excess (1.5 equiv) of the diene coupling partner is required to achieve high yields of the desired internal E,Z-diene cross-metathesis product. Computational studies have been performed to elucidate the reaction mechanism. The computations are consistent with a diene-first pathway. The reaction can be used to quickly assemble structurally complex targets. The power of this cross-metathesis reaction is demonstrated by the concise syntheses of two insect pheromones

The NIRSPEC Brown Dwarf Spectroscopic Survey. I. Low-Resolution Near-Infrared Spectra

We present the first results of a near-infrared (0.96-2.31 micron) spectroscopic survey of M, L, and T dwarfs obtained with NIRSPEC on the Keck II telescope. Our new survey has a resolving power of R = 2000 and is comprised of two major data sets: 53 J-band (1.14-1.36 micron) spectra covering all spectral types from M6 to T8 with at least two members in each spectral subclass (wherever possible), and 25 flux-calibrated spectra from 1.14 to 2.31 microns for most spectral classes between M6 and T8. Sixteen of these 25 objects have additional spectral coverage from 0.96-1.14 microns to provide overlap with optical spectra. Spectral flux ratio indexes for prominent molecular bands are derived and equivalent widths (EWs) for several atomic lines are measured. We find that a combination of four H2O and two CH4 band strengths can be used for spectral classification. Weak (EW~1-2 angstrom) atomic lines of Al I and Ca I disappear at the boundary between M and L types.Comment: 60 pages, 25 figures. To appear in the Astrophysical Journal Vol 596. Received 2003 March 31; accepted 2003 June 20. Web site at http://www.astro.ucla.edu/~mclean/BDSSarchiv

A Unified Near Infrared Spectral Classification Scheme for T Dwarfs

A revised near infrared classification scheme for T dwarfs is presented, based on and superseding prior schemes developed by Burgasser et al. and Geballe et al., and defined following the precepts of the MK Process. Drawing from two large spectroscopic libraries of T dwarfs identified largely in the Sloan Digital Sky Survey and the Two Micron All Sky Survey, nine primary spectral standards and five alternate standards spanning spectral types T0 to T8 are identified that match criteria of spectral character, brightness, absence of a resolved companion and accessibility from both northern and southern hemispheres. The classification of T dwarfs is formally made by the direct comparison of near infrared spectral data of equivalent resolution to the spectra of these standards. Alternately, we have redefined five key spectral indices measuring the strengths of the major H$_2$O and CH$_4$ bands in the 1-2.5 micron region that may be used as a proxy to direct spectral comparison. Two methods of determining T spectral type using these indices are outlined and yield equivalent results. These classifications are also equivalent to those from prior schemes, implying that no revision of existing spectral type trends is required. The one-dimensional scheme presented here provides a first step toward the observational characterization of the lowest luminosity brown dwarfs currently known. Future extensions to incorporate spectral variations arising from differences in photospheric dust content, gravity and metallicity are briefly discussed. A compendium of all currently known T dwarfs with updated classifications is presented.Comment: 52 pages, 11 figures; accepted for publication to Ap

Photonic superdiffusive motion in resonance line radiation trapping - partial frequency redistribution effects

The relation between the jump length probability distribution function and the spectral line profile in resonance atomic radiation trapping is considered for Partial Frequency Redistribution (PFR) between absorbed and reemitted radiation. The single line Opacity Distribution Function [M.N. Berberan-Santos et.al. J.Chem.Phys. 125, 174308 (2006)] is generalized for PFR and used to discuss several possible redistribution mechanisms (pure Doppler broadening, combined natural and Doppler broadening and combined Doppler, natural and collisional broadening). It is shown that there are two coexisting scales with a different behavior: the small scale is controlled by the intricate PFR details while the large scale is essentially given by the atom rest frame redistribution asymptotic. The pure Doppler and combined natural, Doppler and collisional broadening are characterized by both small and large scale superdiffusive Levy flight behaviors while the combined natural and Doppler case has an anomalous small scale behavior but a diffusive large scale asymptotic. The common practice of assuming complete redistribution in core radiation and frequency coherence in the wings of the spectral distribution is incompatible with the breakdown of superdiffusion in combined natural and Doppler broadening conditions

Magnetic Fluctuations in a Charge Ordered State of the One-Dimensional Extended Hubbard Model with a Half-Filled Band

Magnetic properties in a charge ordered state are examined for the extended Hubbard model at half-filling. Magnetic excitations, magnetic susceptibilities and a nuclear spin relaxation rate are calculated with taking account of fluctuations around the mean-field solution. The relevance of the present results to the observation in the 1:1 organic conductors, (TTM-TTP)I$_3$, is discussed.Comment: 4 pages, 3 figures, to be published in J. Phys. Soc. Jpn. Vol.71 (2002) No.

Blue Straggler Stars: Early Observations that Failed to Solve the Problem

In this chapter, I describe early ideas on blue stragglers, and various observations (some published, some not) that promised but failed to resolve the question of their origin. I review the data and ideas that were circulating from Allan Sandage's original discovery in 1953 of "anomalous blue stars" in the globular cluster M3, up until about 1992, when what seems to have been the only previous meeting devoted to Blue Straggler Stars (BSSs) was held at the Space Telescope Science Institute.Comment: Chapter 2, in Ecology of Blue Straggler Stars, H.M.J. Boffin, G. Carraro & G. Beccari (Eds), Astrophysics and Space Science Library, Springe