The influence of material properties on the wear of abradable materials

In aero-engines it is possible for the blades of the compressor, turbine or fan to incur into their casings. At these interfaces a lining of composite abradable material is used to limit damage to components and thereby sustain the efficiency and longevity of the engine as a whole. These composite materials must have good abradability and erosion resistance. Previously, the wear mechanisms at the contact between the blade and the coating have been characterised using stroboscopic imaging and force measurement on a scaled test-rig platform. This work is focused on the characterisation of the wear mechanism for two different hardnesses of abradable lining. The established stroboscopic imaging technique and contact force measurements are combined with sectioning of the abradable material in order to analyse the material’s response during the tests. A measure of the thermal properties and the resulting temperature of the linings during the test have also been made to further understand the effect of coating hardness. The wear mechanism, material response, contact force and thermal properties of the coating have been used to characterise the different material behaviour with different hardness. At low incursion rates, with a soft coating, the blade tip becomes worn after an initial adhesive transfer from the coating. Post-test sectioning showed blade material and significant compaction present in the coating. The harder coating produced adhesion on the blade tip with solidification observed in the coating. Thermal diffusivity measurements and modelling indicated that thermally driven wear observed was as a consequence of the increased number of boundaries between the metal and hBN phases present interrupting heat flow, leading to a concentration of surface heat. At higher incursion rates, the wear mechanism is more similar between the coatings and a cutting mechanism dominates producing negligible adhesion and blade wear

Energy Transfer from Magnetic Iron Oxide Nanoparticles: Implications for Magnetic Hyperthermia

Magnetic iron oxide nanoparticles (IONPs) have gained momentum in the field of biomedical applications. They can be remotely heated via alternating magnetic fields, and such heat can be transferred from the IONPs to the local environment. However, the microscopic mechanism of heat transfer is still debated. By X-ray total scattering experiments and first-principles simulations, we show how such heat transfer can occur. After establishing structural and microstructural properties of the maghemite phase of the IONPs, we built a maghemite model functionalized with aminoalkoxysilane, a molecule used to anchor (bio)molecules to oxide surfaces. By a linear response theory approach, we reveal that a resonance mechanism is responsible for the heat transfer from the IONPs to the surroundings. Heat transfer occurs not only via covalent linkages with the IONP but also through the solvent hydrogen-bond network. This result may pave the way to exploit the directional control of the heat flow from the IONPs to the anchored molecules─i.e., antibiotics, therapeutics, and enzymes─for their activation or release in a broader range of medical and industrial applications

Intestinal bacterial flora of Mediterranean gilthead sea bream (Sparus aurata Linnaeus) as a novel source of natural surface active compounds

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An investigation of the relationship between wear and contact force for abradable materials

Abradable linings are frequently used on the inside of aero-engine casings. During the operation of engine, the rotating blades may strike the lining of the casing. The wear mechanisms present during these incursions have been re-produced on a scaled test rig platform. Previously, characterisation of the wear has been performed using a stroboscopic imaging technique in order to identify the different wear mechanisms at the incursion conditions investigated. In the present study, a dynamometer has been included in the test arrangement allowing the measurement of the contact force. This approach has then been combined with sectioning of the abradable test samples, in order to investigate the material response to the different incursion conditions. The wear results, the cutting force and material structure post-incursion show a high degree of correlation. At low incursion rates, significant consolidation and solidification of abradable material was observed, whilst at the same time adhesive transfer to the blade was recorded along with a low tangential to normal force ratio. At high incursion rates, little solidification and consolidation was observed, together with negligible adhesion and a higher tangential force, suggesting a cutting mechanism. Transitions in material behaviour, wear mechanism, and force ratio were observed at the same incursion condition, further highlighting the link between the different experimental measurements

Electron Localization in the Insulating State

The insulating state of matter is characterized by the excitation spectrum, but also by qualitative features of the electronic ground state. The insulating ground wavefunction in fact: (i) sustains macroscopic polarization, and (ii) is localized. We give a sharp definition of the latter concept, and we show how the two basic features stem from essentially the same formalism. Our approach to localization is exemplified by means of a two--band Hubbard model in one dimension. In the noninteracting limit the wavefunction localization is measured by the spread of the Wannier orbitals.Comment: 5 pages including 3 figures, submitted to PR

Structural, electronic, and dynamical properties of amorphous gallium arsenide: a comparison between two topological models

We present a detailed study of the effect of local chemical ordering on the structural, electronic, and dynamical properties of amorphous gallium arsenide. Using the recently-proposed ``activation-relaxation technique'' and empirical potentials, we have constructed two 216-atom tetrahedral continuous random networks with different topological properties, which were further relaxed using tight-binding molecular dynamics. The first network corresponds to the traditional, amorphous, Polk-type, network, randomly decorated with Ga and As atoms. The second is an amorphous structure with a minimum of wrong (homopolar) bonds, and therefore a minimum of odd-membered atomic rings, and thus corresponds to the Connell-Temkin model. By comparing the structural, electronic, and dynamical properties of these two models, we show that the Connell-Temkin network is energetically favored over Polk, but that most properties are little affected by the differences in topology. We conclude that most indirect experimental evidence for the presence (or absence) of wrong bonds is much weaker than previously believed and that only direct structural measurements, i.e., of such quantities as partial radial distribution functions, can provide quantitative information on these defects in a-GaAs.Comment: 10 pages, 7 ps figures with eps

New intravenous calcimimetic agents: New options, new problems. an example on how clinical, economical and ethical considerations affect choice of treatment

Background. Dialysis treatment is improving, but several long-term problems remain unsolved, including metabolic bone disease linked to chronic kidney disease (CKD-MBD). The availability of new, efficacious but expensive drugs (intravenous calcimimetic agents) poses ethical problems, especially in the setting of budget limitations. Methods. Reasons of choice, side effects, biochemical trends were discussed in a cohort of 15 patients (13% of the dialysis population) who stared treatment with intravenous calcimimetics in a single center. All patients had previously been treated with oral calcimimetic agents; dialysis efficacy was at target in 14/15; hemodiafiltration was employed in 10/15. Median Charlson Comorbidity Index was 8. The indications were discussed according to the principlist ethics (beneficience, non maleficience, justice and autonomy). Biochemical results were analyzed to support the clinical-ethical choices. Results. In the context of a strict clinical and biochemical surveillance, the lack of side effects ensured “non-maleficence”; efficacy was at least similar to oral calcimimetic agents, but tolerance was better. Autonomy was respected through a shared decision-making model; all patients appreciated the reduction of the drug burden, and most acknowledged better control of their biochemical data. The ethical conflict resides in the balance between the clinical “beneficience, non-maleficience” advantage and “justice” (economic impact of treatment, potentially in attrition with other resources, since the drug is expensive and included in the dialysis bundle). The dilemma is more relevant when a patient’s life expectancy is short (economic impact without clear clinical advantages), or when non-compliance is an issue (unclear advantage if the whole treatment is not correctly taken). Conclusions. In a context of person-centered medicine, autonomy, beneficence and non-maleficence should weight more than economic justice. While ethical discussions are not aimed at finding “the right answer” but asking “the right questions”, this example can raise awareness of the importance of including an ethical analysis in the choice of “economically relevant” drugs

Topology of amorphous tetrahedral semiconductors on intermediate lengthscales

Using the recently-proposed ``activation-relaxation technique'' for optimizing complex structures, we develop a structural model appropriate to a-GaAs which is almost free of odd-membered rings, i.e., wrong bonds, and possesses an almost perfect coordination of four. The model is found to be superior to structures obtained from much more computer-intensive tight-binding or quantum molecular-dynamics simulations. For the elemental system a-Si, where wrong bonds do not exist, the cost in elastic energy for removing odd-membered rings is such that the traditional continuous-random network is appropriate. Our study thus provides, for the first time, direct information on the nature of intermediate-range topology in amorphous tetrahedral semiconductors.Comment: 4 pages, Latex and 2 postscript figure

Metodologia de monitoramento de cobertura vegetal: estudo de caso no município de Goiânia, GO.

Este trabalho apresenta uma proposta para a análise da variação da cobertura vegetal, utilizando dados de acesso público. Os procedimentos de análise multitemporal propostos foram aplicados no município de Goiânia, GO, como estudo de caso. Aplicou-se o índice de vegetação por diferença normalizada (NDVI), obtido a partir de imagens Landsat-5, em três anos de referência: 1997, 2004, 2011. Consideraram-se três classes de cobertura: ?corpos d?água?, ?vegetação? e ?outros usos?. Foram utilizadas técnicas de processamento digital de imagens, visando à correção de erros gerados pela influência da atmosfera e à obtenção de uma melhor qualidade espectral dos alvos. Para esse fim, o modelo adotado foi o dark object subtraction (DOS). O resultado mostrou-se satisfatório, considerando-se a disponibilidade dos dados e suas limitações.bitstream/item/84894/1/0000010346-BPD-Cobert-vegetal.pd

Infraestrutura Nacional de Dados Espaciais: Aspectos Computacionais.

O objetivo deste documento é apresentar os principais conceitos relacionados aos pilares ?tecnologia? e ?padrões?, com enfoque em seus aspectos computacionais. A intenção é sumarizar os fundamentos teóricos envolvidos na especificação da INDE e reunir as principais referências de softwares open source atualmente disponíveis e amplamente adotados pela comunidade para a implantação da INDE.bitstream/item/84963/1/COMUN-TECNICO-1-GESTAO-TERRITORIAL-Infraestrut-Nac-Dados-Espac-ed01-2013.pd