415 research outputs found
Evaluating simplified chemical mechanisms within present-day simulations of the Community Earth System Model version 1.2 with CAM4 (CESM1.2 CAM-chem): MOZART-4 vs. Reduced Hydrocarbon vs. Super-Fast chemistry
While state-of-the-art complex chemical mechanisms expand our understanding
of atmospheric chemistry, their sheer size and computational requirements
often limit simulations to short lengths or ensembles to only a few members.
Here we present and compare three 25-year present-day offline simulations
with chemical mechanisms of different levels of complexity using the
Community Earth System Model (CESM) Version 1.2 CAM-chem (CAM4): the Model
for Ozone and Related Chemical Tracers, version 4 (MOZART-4) mechanism, the
Reduced Hydrocarbon mechanism, and the Super-Fast mechanism. We show that,
for most regions and time periods, differences in simulated ozone chemistry
between these three mechanisms are smaller than the modelâobservation
differences themselves. The MOZART-4 mechanism and the Reduced Hydrocarbon
are in close agreement in their representation of ozone throughout the
troposphere during all time periods (annual, seasonal, and diurnal). While
the Super-Fast mechanism tends to have higher simulated ozone variability and
differs from the MOZART-4 mechanism over regions of high biogenic emissions,
it is surprisingly capable of simulating ozone adequately given its
simplicity. We explore the trade-offs between chemical mechanism complexity
and computational cost by identifying regions where the simpler mechanisms
are comparable to the MOZART-4 mechanism and regions where they are not. The
Super-Fast mechanism is 3 times as fast as the MOZART-4 mechanism, which
allows for longer simulations or ensembles with more members that may not be
feasible with the MOZART-4 mechanism given limited computational resources.</p
Correction: Responses of deposition and bioaccumulation in the Great Lakes region to policy and other large-scale drivers of mercury emissions
Correction for âResponses of deposition and bioaccumulation in the Great Lakes region to policy and other large-scale drivers of mercury emissionsâ by J. A. Perlinger et al., Environ. Sci.: Processes Impacts, 2018, 20, 195â209.
In the original article, there were errors in some numerical values in Table 3 and in the text in Sections 3.1 and 4.1. The corrected Table and Sections are shown below. The changes are to the magnitudes of mercury species deposition to the Great Lakes region, the Upper Peninsula of Michigan, and the Adirondack region of the Lakes basin. The changes to the Adirondack values reduce the numerical differences in these magnitudes compared to magnitudes of total mercury deposition to the Upper Peninsula of Michigan. The changes to the mercury species deposition to the Great Lakes region and the Upper Peninsula of Michigan have no implications. The changes do not impact the conclusions of the article
Understanding mercury oxidation and airâsnow exchange on the East Antarctic Plateau: a modeling study
Distinct diurnal and seasonal variations of mercury (Hg) have been observed
in near-surface air at Concordia Station on the East Antarctic Plateau, but
the processes controlling these characteristics are not well understood.
Here, we use a box model to interpret the Hg0 (gaseous elemental
mercury) measurements in thes year 2013. The model includes atmospheric Hg0
oxidation (by OH, O3, or bromine), surface snow HgII (oxidized
mercury) reduction, and airâsnow exchange, and is driven by meteorological
fields from a regional climate model. The simulations suggest that a
photochemically driven mercury diurnal cycle occurs at the airâsnow interface
in austral summer. The fast oxidation of Hg0 in summer may be provided
by a two-step bromine-initiated scheme, which is favored by low temperature
and high nitrogen oxides at Concordia. The summertime diurnal variations of
Hg0 (peaking during daytime) may be confined within several tens of
meters above the snow surface and affected by changing mixed layer depths.
Snow re-emission of Hg0 is mainly driven by photoreduction of snow
HgII in summer. Intermittent warming events and a hypothesized reduction
of HgII occurring in snow in the dark may be important processes
controlling the mercury variations in the non-summer period, although their
relative importance is uncertain. The Br-initiated oxidation of Hg0 is
expected to be slower at Summit Station in Greenland than at Concordia (due to their
difference in temperature and levels of nitrogen oxides and ozone), which may
contribute to the observed differences in the summertime diurnal variations
of Hg0 between these two polar inland stations.</p
Chemical cycling and deposition of atmospheric mercury in Polar Regions: review of recent measurements and comparison with models
Mercury (Hg) is a worldwide contaminant that can cause adverse health effects to wildlife and humans. While atmospheric modeling traces the link from emissions to deposition of Hg onto environmental surfaces, large uncertainties arise from our incomplete understanding of atmospheric processes (oxidation pathways, deposition, and re-emission). Atmospheric Hg reactivity is exacerbated in high latitudes and there is still much to be learned from polar regions in terms of atmospheric processes. This paper provides a synthesis of the atmospheric Hg monitoring data available in recent years (2011â2015) in the Arctic and in Antarctica along with a comparison of these observations with numerical simulations using four cutting-edge global models. The cycle of atmospheric Hg in the Arctic and in Antarctica presents both similarities and differences. Coastal sites in the two regions are both influenced by springtime atmospheric Hg depletion events and by summertime snowpack re-emission and oceanic evasion of Hg. The cycle of atmospheric Hg differs between the two regions primarily because of their different geography. While Arctic sites are significantly influenced by northern hemispheric Hg emissions especially in winter, coastal Antarctic sites are significantly influenced by the reactivity observed on the East Antarctic ice sheet due to katabatic winds. Based on the comparison of multi-model simulations with observations, this paper discusses whether the processes that affect atmospheric Hg seasonality and interannual variability are appropriately represented in the models and identifies research gaps in our understanding of the atmospheric Hg cycling in high latitudes
Global Health and Economic Impacts of Future Ozone Pollution
Abstract and PDF report are also available on the MIT Joint Program on the Science and Policy of Global Change website (http://globalchange.mit.edu/).We assess the human health and economic impacts of projected 2000-2050 changes in ozone pollution using the MIT Emissions Prediction and Policy Analysis-Health Effects (EPPA-HE) model, in combination with results from the GEOS-Chem global tropospheric chemistry model that simulated climate and chemistry effects of IPCC SRES emissions. We use EPPA to assess the human health damages (including acute mortality and morbidity outcomes) caused by ozone pollution and quantify their economic impacts in sixteen world regions. We compare the costs of ozone pollution under scenarios with 2000 and 2050 ozone precursor and greenhouse gas emissions (SRES A1B scenario). We estimate that health costs due to global ozone pollution above pre-industrial levels by 2050 will be ) and that acute mortalities will exceed 2 million. We find that previous methodologies underestimate costs of air pollution by more than a third because they do not take into account the long-term, compounding effects of health costs. The economic effects of emissions changes far exceed the influence of climate alone.United States Department of Energy, Office of
Science (BER) grants DE-FG02-94ER61937 and DE-FG02-93ER61677, the United States
Environmental Protection Agency grant EPA-XA-83344601-0, and the industrial and foundation
sponsors of the MIT Joint Program on the Science and Policy of Global Change
Transient expression of ZBTB32 in anti-viral CD8+ T cells limits the magnitude of the effector response and the generation of memory
Virus infections induce CD8+ T cell responses comprised of a large population of terminal effector cells and a smaller subset of long-lived memory cells. The transcription factors regulating the relative expansion versus the long-term survival potential of anti-viral CD8+ T cells are not completely understood. We identified ZBTB32 as a transcription factor that is transiently expressed in effector CD8+ T cells. After acute virus infection, CD8+ T cells deficient in ZBTB32 showed enhanced virus-specific CD8+ T cell responses, and generated increased numbers of virus-specific memory cells; in contrast, persistent expression of ZBTB32 suppressed memory cell formation. The dysregulation of CD8+ T cell responses in the absence of ZBTB32 was catastrophic, as Zbtb32-/- mice succumbed to a systemic viral infection and showed evidence of severe lung pathology. We found that ZBTB32 and Blimp-1 were co-expressed following CD8+ T cell activation, bound to each other, and cooperatively regulated Blimp-1 target genes Eomes and Cd27. These findings demonstrate that ZBTB32 is a key transcription factor in CD8+ effector T cells that is required for the balanced regulation of effector versus memory responses to infection
Knowledge politics and new converging technologies: a social epistemological perspective
The ânew converging technologiesâ refers to the prospect of advancing the human condition by the integrated study and application of nanotechnology, biotechnology, information technology and the cognitive sciences - or âNBICâ. In recent years, it has loomed large, albeit with somewhat different emphases, in national science policy agendas throughout the world. This article considers the political and intellectual sources - both historical and contemporary - of the converging technologies agenda. Underlying it is a fluid conception of humanity that is captured by the ethically challenging notion of âenhancing evolutionâ
Oxidation of mercury by bromine in the subtropical Pacific free troposphere
Mercury is a global toxin that can be introduced to ecosystems through atmospheric deposition. Mercury oxidation is thought to occur in the free troposphere by bromine radicals, but direct observational evidence for this process is currently unavailable. During the 2013 Nitrogen, Oxidants, Mercury and Aerosol Distributions, Sources and Sinks campaign, we measured enhanced oxidized mercury and bromine monoxide in a free tropospheric air mass over Texas. We use trace gas measurements, air mass back trajectories, and a chemical box model to confirm the origin and chemical history of the sampled air mass. We find the presence of elevated oxidized mercury to be consistent with oxidation of elemental mercury by bromine atoms in this subsiding upper tropospheric air mass within the subtropical Pacific High, where dry atmospheric conditions are conducive to oxidized mercury accumulation. Our results support the role of bromine as the dominant oxidant of mercury in the upper troposphereNational Science Foundation (U.S.) (Grants 121701 and, 1215712
Subnational climate entrepreneurship: innovative climate action in California and SĂŁo Paulo
The distinct role of subnational governments such as states and provinces in addressing climate change has been increasingly acknowledged. But while most studies investigate the causes and consequences of particular governmentsâ actions and networking activities, this article argues that subnational governments can develop climate action as a collective entrepreneurial activity. Addressing many elements explored in this special issue, it focuses on the second question and identifies climate entrepreneurship in two subnational governmentsâthe states of California (USA) and SĂŁo Paulo (Brazil). Examining internal action, as well as interaction with local authorities, national governments and the international regime, entrepreneurial activities are identified in the invention, diffusion and evaluation of subnational climate policy in each case. The article draws from the recent scholarship on policy innovation, entrepreneurship and climate governance. It contributes to the literature by exploring entrepreneurial subnational government activity in addressing climate change and expanding the understanding of the effects of policy innovation at the subnational level
- âŠ