Applications of fluorescent sensor based on 1H-pyrazolo[3,4-b]quinoline in analytical chemistry

Fluorescent dye 2-[(2-Hydroxyethyl)-(1,3-diphenyl-1H-pyrazolo[3,4-b]quinolin-6-ylmethyl)-amino]ethanol (LL1) was examined for its efficiency in the detection of small inorganic cations (lithium, sodium, barium, calcium, magnesium, cadmium, lead and zinc). The dye was synthesized in the laboratory and investigated by means of both, steady-state and time-resolved fluorescence techniques. This compound acts as a fluorescent sensor suitable for detection of small inorganic cations (lithium, sodium, barium, calcium, magnesium, cadmium, lead and zinc) in strongly polar solvent (acetonitrile). An electron transfer from the electro-donative part (receptor) of the molecule to the acceptor part (fluorophore) is thought to be the main mechanism that underlies functionality of the compound as a sensor. This process can be retarded upon complexation of the receptor moiety by inorganic cations. Relatively high sensitivity but poor selectivity of the aminoalcohol thatcontains indicator towards the two-valued cations was observed. However, upon addition of some amounts of water the selectivity of this sensor has been enhanced (especially towards lead cation). The preliminary results in analytical application of the sensor are discussed

Smart City : Leitfaden zur Umsetzung von Smart-City-Initiativen in der Schweiz

Dieser Leitfaden zur Umsetzung von Smart-City-Initiativen in der Schweiz wurde im Rahmen des Programmes EnergieSchweiz für Gemeinden konzipiert. Das Bundesamt für Energie (BFE) fördert damit die Umsetzung der nationalen Energiepolitik in den Bereichen Energieeffizienz und erneuerbare Energie. Mit dem Programm EnergieSchweiz für Gemeinden unterstützt das BFE gezielt Projekte auf kommunaler Ebene

Recent advances in TIS research: towards a new phase in transition studies

The technological innovation systems (TIS) approach has become one of the key frameworks for the study of emerging technologies in and beyond the context of sustainability transitions. It focuses on understanding the dynamics of an innovation system associated with a specific technology. The approach is often used to assess the performance of a TIS, to identify shortcomings and to derive policy recommendations for the support of a selected technology (Bergek et al., 2008; Hekkert and Negro, 2009). Since its inception, the framework has seen several conceptual developments, including a clarification of scoping issues, TIS functions as a central tool for performance assessment, a strategic perspective on system building, international and global ties within TIS, and suggestions for the analysis of TIS contexts (Bergek et al., 2015; Binz et al., 2014; Markard et al., 2015). At the same time, however, there are also new conceptual challenges, especially when the TIS is used for sustainability transition studies. One of these challenges is how to study whole system reconfigurations, i.e. to move beyond the focus on specific technologies. Ongoing transitions such as the energy transition currently enter into a new phase of accelerated development, in which multiple emerging and mature technologies interact. Other conceptual challenges include the decline of incumbent technologies, intensified struggles among actors or transition processes transcending sectoral and national boundaries