Using adsorption kinetics to assemble vertically aligned nanorods at liquid interfaces for metamaterial applications

Vertically aligned monolayers of metallic nanorods have a wide range of applications as metamaterials or in surface enhanced Raman spectroscopy. However the fabrication of such structures using current top-down methods or through assembly on solid substrates is either difficult to scale up or have limited possibilities for further modification after assembly. The aim of this paper is to use the adsorption kinetics of cylindrical nanorods at a liquid interface as a novel route for assembling vertically aligned nanorod arrays that overcomes these problems. Specifically, we model the adsorption kinetics of the particle using Langevin dynamics coupled to a finite element model, accurately capturing the deformation of the liquid meniscus and particle friction coefficients during adsorption. We find that the final orientation of the cylindrical nanorod is determined by their initial attack angle when they contact the liquid interface, and that the range of attack angles leading to the end-on state is maximised when nanorods approach the liquid interface from the bulk phase that is more energetically favorable. In the absence of an external field, only a fraction of adsorbing nanorods end up in the end-on state (<=40% even for nanorods approaching from the energetically favourable phase). However, by pre-aligning the metallic nanorods with experimentally achievable electric fields, this fraction can be effectively increased to 100%. Using nanophotonic calculations, we also demonstrate that the resultant vertically aligned structures can be used as epsilon-near-zero and hyperbolic metamaterials. Our kinetic assembly method is applicable to nanorods with a range of diameters, aspect ratios and materials and therefore represents a versatile, low-cost and powerful platform for fabricating vertically aligned nanorods for metamaterial applications

Hot electrons and electromagnetic effects in the broadband Au, Ag, and Ag-Au nanocrystals: The UV, visible, and NIR plasmons

Energetic and optical properties of plasmonic nanocrystals strongly depend on their sizes, shapes, and composition. Whereas using plasmonic nanoparticles in biotesting has become routine, applications of plasmonics in energy are still early in development. Here, we investigate hot electron (HE) generation and related electromagnetic effects in both mono- and bi-metallic nanorods (NRs) and focus on one promising type of bi-metallic nanocrystals - core-shell Au-Ag nanorods. The spectra of the NRs are broadband, highly tunable with their geometry, and have few plasmon resonances. In this work, we provide a new quantum formalism describing the HE generation in bi-metallic nanostructures. Interestingly, we observe that the HE generation rate at the UV plasmon resonance of Au-Ag NRs appears to be very high. These HEs are highly energetic and suitable for carbon-fuel reactions. Simultaneously, the HE generation at the longitudinal plasmon (L-plasmon) peaks, which can be tuned from the yellow to near-IR, depends on the near-field and electromagnetic Mie effects, limiting the HE efficiencies for the long and large NRs. These properties of the L-plasmon relate to all kinds of NRs (Au, Ag, and Au-Ag). We also consider the generation of the interband d-holes in Au and Ag, since the involvement of the d-band is crucial for the energetic properties of UV plasmons. The proposed formalism is an important development for the description of bi-metallic (or tri-metallic, or more complex) nanostructures, and it paves the way to the efficient application of the plasmonic HEs and hot holes in sensing, nanotechnology, photocatalysis, and electrophotochemistry

Organic copolymer lasing from single defect microcavity fabricated using laser patterning

Reducing the lasing threshold in optically pumped organic lasers is a necessary component of the drive to develop an organic laser diode, as this may help mitigate the losses associated with electrical contacts and charge injection. In this study we show how increasing the binaphthyl (BN) spacer content in polydioctylfluorene (PFO) decreases its amplified spontaneous emission threshold (ASE) through the suppression of intermolecular interactions. Using co-polymers with low lasing thresholds, we use a laser patterning technique to fabricate physical defects (having a diameter of ∼2.5 μm) within a vertical microcavity. Such defects create additional lateral confinement, with this approach allowing us to reduce the lasing threshold from 11 μJ cm−2 to 7 μJ cm−2 and increase cavity Q-factor from 495 (planar cavity) to 2300. The enhanced performance and the stack structure of the defect microcavity show it is a promising architecture for an electrically-pumped laser device

Religious and philosophical foundation of Jurkevich’s pedagogical theory

The article contains the analyses of anthropological basis of Jurkevich’s pedagogy. This basis is Christian Anthropology and modern concept of Man. Pedagogy of Jurkevich is the unity of religious, philosophical, psychological and pedagogical ideas. That was fruitful for a development of Russian education at the last part of the XIXth CenturyВ статье дается анализ антропологических оснований педагогики П. Д. Юркевича. Показано, что его педагогическая концепция зиждется на идеях религиозно-философской антропологии, имеющей христианские корни, а также на современных ему научных представлениях о человеке. Педагогика Юркевича – сплав религиозных, философских, психологических и педагогических идей, плодотворный для развития российской педагогики второй половины XIX век

Emission enhancement of semiconductor nanocrystals by gold nanorods: a recipe

In this work, we experimentally and theoretically investigated conditions of the emission enhancement of semiconductor nanocrystals (on the example of CdSe-based quantum dots, QDs) by GNRs

Tools for modernization of information services in remote mode: the experience of Belarusian Agricultural Library

&lt;p&gt;The article discusses the stages of introducing automated technologies into the practice of the Belarusian Agricultural Library using the example of servicing remote users. The characteristics and benefits of using new technologies at each stage are described. The results of monitoring the information needs of users as a method of studying the potential market of users and promoting the library's information resources and services are presented.&lt;/p&gt

Enhanced Resonant Raman scattering of GaN functional layers using Al thin films -a versatile tool for multilayer structure analysis

International audienc