96 research outputs found
A Scheme for Solving the Plane–Plane Challenge in Force Measurements at the Nanoscale
Non-contact interaction between two parallel flat surfaces is a central paradigm in sciences. This situation is the starting point for a wealth of different models: the capacitor description in electrostatics, hydrodynamic flow, thermal exchange, the Casimir force, direct contact study, third body confinement such as liquids or films of soft condensed matter. The control of parallelism is so demanding that no versatile single force machine in this geometry has been proposed so far. Using a combination of nanopositioning based on inertial motors, of microcrystal shaping with a focused-ion beam (FIB) and of accurate in situ and real-time control of surface parallelism with X-ray diffraction, we propose here a “gedanken” surface-force machine that should enable one to measure interactions between movable surfaces separated by gaps in the micrometer and nanometer ranges
Correlated Electrical and Chemical Nanoscale Properties in Potassium-Passivated, Triple-Cation Perovskite Solar Cells
Perovskite semiconductors are an exciting class of materials due to their
promising performance outputs in optoelectronic devices. To boost their
efficiency further, researchers introduce additives during sample synthesis, such as KI. However, it is not well understood how KI changes the material
and, often, leaves precipitants. To fully resolve the role of KI, a multiple
microscopy techniques is applied and the electrical and chemical behavior of a Reference (untreated) and a KI-treated perovskite are compared. Upon correlation between electrical and chemical nanoimaging techniques, it is discovered that these local properties are linked to the macroscopic voltage enhancement of the KI-treated perovskite. The heterogeneity revealed in both the local electrical and chemical responses indicates that the additive partially migrates to the surface, yet surprisingly; does not deteriorate the performance locally, rather, the voltage response homogeneously increases. The research presented within provides a diagnostic methodology, which connects the nanoscale electrical and chemical properties of materials, relevant to other perovskites, including multication and Pb-free alternatives.University of Maryland All-S.T.A.R. Fellowship
Hulka Energy Research Fellowship
National Science Foundation
US Department of Energy
The Royal Society
Office of Naval Researc
Correlated Electrical and Chemical Nanoscale Properties in Potassium-Passivated, Triple-Cation Perovskite Solar Cells
Perovskite semiconductors are an exciting class of materials due to their promising performance outputs in photovoltaic devices. To boost their efficiency further, researchers introduce additives during sample synthesis, such as KI. However, it is not well understood how KI changes the material and, often, leaves precipitants. To fully resolve the role of KI, multiple microscopy techniques are applied and the electrical and chemical behavior of a Reference (untreated) and a KI‐treated perovskite are compared. Upon correlation between electrical and chemical nanoimaging techniques, it is discovered that these local properties are linked to the macroscopic voltage enhancement of the KI‐treated perovskite. The heterogeneity revealed in both the local electrical and chemical responses indicates that the additive partially migrates to the surface, yet surprisingly does not deteriorate the performance locally, rather, the voltage response homogeneously increases. The research presented within provides a diagnostic methodology, which connects the nanoscale electrical and chemical properties of materials, relevant to other perovskites, including multication and Pb‐free alternatives
Casimir forces on a silicon micromechanical chip
Quantum fluctuations give rise to van der Waals and Casimir forces that
dominate the interaction between electrically neutral objects at sub-micron
separations. Under the trend of miniaturization, such quantum electrodynamical
effects are expected to play an important role in micro- and nano-mechanical
devices. Nevertheless, utilization of Casimir forces on the chip level remains
a major challenge because all experiments so far require an external object to
be manually positioned close to the mechanical element. Here, by integrating a
force-sensing micromechanical beam and an electrostatic actuator on a single
chip, we demonstrate the Casimir effect between two micromachined silicon
components on the same substrate. A high degree of parallelism between the two
near-planar interacting surfaces can be achieved because they are defined in a
single lithographic step. Apart from providing a compact platform for Casimir
force measurements, this scheme also opens the possibility of tailoring the
Casimir force using lithographically defined components of non-conventional
shapes
Strong Casimir force reduction through metallic surface nanostructuring
The Casimir force between bodies in vacuum can be understood as arising from
their interaction with an infinite number of fluctuating electromagnetic
quantum vacuum modes, resulting in a complex dependence on the shape and
material of the interacting objects. Becoming dominant at small separations,
the force plays a significant role in nanomechanics and object manipulation at
the nanoscale, leading to a considerable interest in identifying structures
where the Casimir interaction behaves significantly different from the
well-known attractive force between parallel plates. Here we experimentally
demonstrate that by nanostructuring one of the interacting metal surfaces at
scales below the plasma wavelength, an unexpected regime in the Casimir force
can be observed. Replacing a flat surface with a deep metallic lamellar grating
with sub-100 nm features strongly suppresses the Casimir force and for large
inter-surfaces separations reduces it beyond what would be expected by any
existing theoretical prediction.Comment: 11 pages, 8 figure
Observation of the thermal Casimir force
Quantum theory predicts the existence of the Casimir force between
macroscopic bodies, due to the zero-point energy of electromagnetic field modes
around them. This quantum fluctuation-induced force has been experimentally
observed for metallic and semiconducting bodies, although the measurements to
date have been unable to clearly settle the question of the correct
low-frequency form of the dielectric constant dispersion (the Drude model or
the plasma model) to be used for calculating the Casimir forces. At finite
temperature a thermal Casimir force, due to thermal, rather than quantum,
fluctuations of the electromagnetic field, has been theoretically predicted
long ago. Here we report the experimental observation of the thermal Casimir
force between two gold plates. We measured the attractive force between a flat
and a spherical plate for separations between 0.7 m and 7 m. An
electrostatic force caused by potential patches on the plates' surfaces is
included in the analysis. The experimental results are in excellent agreement
(reduced of 1.04) with the Casimir force calculated using the Drude
model, including the T=300 K thermal force, which dominates over the quantum
fluctuation-induced force at separations greater than 3 m. The plasma
model result is excluded in the measured separation range.Comment: 6 page
Ocean Acidification Affects Prey Detection by a Predatory Reef Fish
Changes in olfactory-mediated behaviour caused by elevated CO2 levels in the ocean could affect recruitment to reef fish populations because larval fish become more vulnerable to predation. However, it is currently unclear how elevated CO2 will impact the other key part of the predator-prey interaction – the predators. We investigated the effects of elevated CO2 and reduced pH on olfactory preferences, activity levels and feeding behaviour of a common coral reef meso-predator, the brown dottyback (Pseudochromis fuscus). Predators were exposed to either current-day CO2 levels or one of two elevated CO2 levels (∼600 µatm or ∼950 µatm) that may occur by 2100 according to climate change predictions. Exposure to elevated CO2 and reduced pH caused a shift from preference to avoidance of the smell of injured prey, with CO2 treated predators spending approximately 20% less time in a water stream containing prey odour compared with controls. Furthermore, activity levels of fish was higher in the high CO2 treatment and feeding activity was lower for fish in the mid CO2 treatment; indicating that future conditions may potentially reduce the ability of the fish to respond rapidly to fluctuations in food availability. Elevated activity levels of predators in the high CO2 treatment, however, may compensate for reduced olfactory ability, as greater movement facilitated visual detection of food. Our findings show that, at least for the species tested to date, both parties in the predator-prey relationship may be affected by ocean acidification. Although impairment of olfactory-mediated behaviour of predators might reduce the risk of predation for larval fishes, the magnitude of the observed effects of elevated CO2 acidification appear to be more dramatic for prey compared to predators. Thus, it is unlikely that the altered behaviour of predators is sufficient to fully compensate for the effects of ocean acidification on prey mortality
Roles of cysteines Cys115 and Cys201 in the assembly and thermostability of grouper betanodavirus particles
The virus-like particle (VLP) assembled from capsid subunits of the dragon grouper nervous necrosis virus (DGNNV) is very similar to its native T = 3 virion. In order to investigate the effects of four cysteine residues in the capsid polypeptide on the assembly/dissociation pathways of DGNNV virions, we recombinantly cloned mutant VLPs by mutating each cysteine to destroy the specific disulfide linkage as compared with thiol reduction to destroy all S–S bonds. The mutant VLPs of C187A and C331A mutations were similar to wild-type VLPs (WT-VLPs); hence, the effects of Cys187 and Cys331 on the particle formation and thermostability were presumably negligible. Electron microscopy showed that either C115A or C201A mutation disrupted de novo VLP formation significantly. As shown in micrographs and thermal decay curves, β-mercaptoethanol-treated WT-VLPs remained intact, merely resulting in lower tolerance to thermal disruption than native WT-VLPs. This thiol reduction broke disulfide linkages inside the pre-fabricated VLPs, but it did not disrupt the appearance of icosahedrons. Small dissociated capsomers from EGTA-treated VLPs were able to reassemble back to icosahedrons in the presence of calcium ions, but additional treatment with β-mercaptoethanol during EGTA dissociation resulted in inability of the capsomers to reassemble into the icosahedral form. These results indicated that Cys115 and Cys201 were essential for capsid formation of DGNNV icosahedron structure in de novo assembly and reassembly pathways, as well as for the thermal stability of pre-fabricated particles
Tunable bipolar optical interactions between guided lightwaves
The optical binding forces between guided lightwaves in dielectric waveguides
can be either repulsive or attractive. So far only attractive force has been
observed. Here we experimentally demonstrate a bipolar optical force between
coupled nanomechanical waveguides. Both attractive and repulsive optical forces
are obtained. The sign of the force can be switched reversibly by tuning the
relative phase of the interacting lightwaves. This tunable, bipolar interaction
forms the foundation for the operation of a new class of light force devices
and circuits.Comment: 4 figure
Towards Visible Light Hydrogen Generation: Quantum Dot-Sensitization via Efficient Light Harvesting of Hybrid-TiO2
We report pronounced enhancement of photoelectrochemical hydrogen generation of a quantum dot-sensitized hybrid-TiO2 (QD/H-TiO2) electrode that is composed of a mesoporous TiO2 layer sandwiched by a double sided energy harvesting layer consisting of a surface-textured TiO2 inverse opals layer on the bottom and a patterned mesoporous TiO2 layer on the top. CdSe/H-TiO2 exhibits a maximum photocurrent density of similar to 16.2 mA/cm(2), which is 35% higher than that of the optimized control sample (CdSe/P25), achieved by matching of the bandgap of quantum dot-sensitization with the wavelength where light harvesting of H-TiO2 is observed. Furthermore, CdSe/H-TiO2 under filtered exposure conditions recorded current density of similar to 14.2 mA/cm(2), the greatest value in the visible range. The excellent performance of the quantum dot-sensitized H-TiO2 suggests that alteration of the photoelectrodes to suitable nanostructures with excellent light absorption may offer optimal strategies for attaining maximum efficiency in a variety of photoconversion systems.open3
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