Formulation and characterization of a multiple emulsion containing 1% L-ascorbic acid

The purpose of the study was to prepare a stable multiple emulsion containing a skin anti-aging agent and using paraffin oil. Vitamin C, was incorporated into the inner aqueous phase of water-in-oil-in-water (w/o/w) multiple emulsion at a concentration of 1%. Multiple emulsion was prepared by two step method. Stability studies were performed at different accelerated conditions, i.e. 8 oC (in refrigerator), 25 oC (in oven), 40 oC (in oven), and 40 oC at 75% RH (in stability cabin) for 28 days to predict the stability of formulations. Different parameters, namely pH, globule size, electrical conductivity and effect of centrifugation (simulating gravity) were determined during stability studies. Data obtained was evaluated statistically using ANOVA two way analyses and LSD tests. Multiple emulsion formulated was found to be stable at lower temperatures (i.e. 8 and 25 oC) for 28 days. No phase separation was observed in the samples during stability testing. It was found that there was no significant change (p > 0.05) in globule sizes in most of the samples kept at various conditions. Insignificant changes (p > 0.05) in both pH and conductivity values were determined for the samples kept at 8, 40, and 40 oC at 75% RH, throughout the study period. Further studies are needed to formulate more stable emulsions with other emulsifying agents. KEY WORDS: Multiple emulsion, Vitamin C, StabilityBull. Chem. Soc. Ethiop. 2010, 24(1), 1-10.

Flame Retardancy and Excellent Electrical Insulation Performance of RTV Silicone Rubber

Room temperature vulcanized (RTV) silicone rubber filled with aluminum trihydrate (ATH) is substantially engaged in electrical outdoor insulation applications. The pristine silicone rubber is highly combustible. ATH filled silicone rubber offers excellent electrical insulation but lacks in providing adequate flame retardancy. This short communication reports the novel results on improved flame retardancy of pristine and ATH filled silicone rubber whilst retaining the electrical insulation properties to a great extent. Results suggest that the presence of only one percent of graphene nanoplatelets with ATH sharply reduces the heat release rate and rate of smoke release. A minor reduction in dielectric breakdown strength and volume resistivity is noticed. Furthermore, permittivity and dielectric loss at power frequency suggest that a marginal 1% concentration of nanoplatelet with ATH is an excellent approach to fabricate flame retardant silicone rubber with an acceptable electrical insulation level

SYNTHESIS OF NANO - HYDROXYAPATITE AND NANO - FLUOROAPATITE PARTICLES BY SOL-GEL METHOD

Background: Hydroxyapatite is a material which resembles the composition and crystal structure of hard tissues in human body. It is being used in dentistry as a bioactive material in dental implants and is a major constituent in the bone regenerative materials. Fluoroapatite is also a bioactive material and is more stable than Hydroxyapatite. The fluoride content is anti - bacterial and is working very efficiently as a component of dental restorative materials. Objective: The objective is to synthesize the nano Hydroxyapatite and nanoFluoroapatite powder via sol-gel method, and compare the FTIR and Raman Spectrums of synthesized material with the FTIR and Raman of nano Hydroxyapatite and Fluoroapatite. Methods: The materials were synthesized by sol - gel method and then evaluated by the FTIR and Raman spectroscopy to confirm the chemical structure of both the materials. Results: FTIR and Raman Spectroscopy of the synthesized Hydroxyapatite and Fluoroapatite are then evaluated and compared with market grade materials, which confirm the presence of hydroxyl, phosphate and carbonate group in the obtained samples. Conclusion: Sol - gel is proved to be a reliable and simple method for the synthesis of nano Hydroxyapatite and Fluoroapatite particles. The obtained samples then compared with the available materials to confirm that the material synthesized is pure and chemically identical

Botanical biopesticides have an influence on tomato quality through pest control and are cost-effective for farmers in developing countries

This research article was published by plos one,2023Synthetic insecticides heavily applied to manage agricultural pests are highly hazardous to the environment and non-target organisms. Their overuse through repeated treatments in smallholder farming communities is frequent. Botanical biopesticides are ideal for sustainable pest management in agricultural environments by keeping synthetic insecticide use at a minimum. Here we evaluated a locally prepared neem seed extract (NSE) alongside emamectin benzoate against both lepidopteran pests Helicoverpa armigera (Hübner) and Spodoptera exigua (Hübner) on tomato Lycopersicon esculentum Mill under natural field conditions in Pakistan. We compared pest severity, fruit injury, quality, marketability, and cost:benefit ratio (CBR) between treatments. The concentration of azadirachtin A in the NSE was 26.5 ppm. NSE at 2% (20 mL/L) and the emamectin benzoate at the recommended field rate in Pakistan were sprayed weekly throughout the fruiting stage. The pest larvae were significantly more abundant on fruits than on flowers and leaves. Fruit injury and losses were significantly more important in untreated control compared to NSE and emamectin benzoate treatments. NSE efficacy varied with respect to the cultivars used and the seasons. Cultivar Eden harboured more pests than Adventa, and emamectin benzoate suppressed more pest individuals than NSE. Both the insecticidal treatments were comparable in terms of marketable yield productions as well as unmarketable, uninjured, and recovered fruit yields. NSE generated a higher CBR (1: 9.26) than emamectin benzoate (1: 3.23). NSE suppressed pests by acting as an antifeedant, similar to its synthetic counterpart. Smallholder growers can thus use NSE as a cost-effective solution in tomato pest management in Pakistan

A multiband circular polarization selective metasurface for microwave applications

In this research article, a multiband circular polarization selective (CPS) metasurface is presented. A reciprocal bi-layered metasurface is designed by introducing the chirality in the structure. The top layer of the proposed metasurface is composed of circular split-ring resonator with a cross shape structure inside it. The same structure is printed on the bottom side of the proposed metasurface by rotating it at an angle of 90° to achieve chirality in the structure. The proposed metasurface is able to add CPS surface capability between 5.18 and 5.23 GHz for y-polarized incident wave. For the frequency band of 5.18–5.23 GHz, the transmission goes up to − 4 dB, while the polarization extinction ratio (PER) reaches up to − 27.4 dB at 5.2 GHz. Similarly, for x-polarized incident wave, three strategic CPS operating bands are achieved within the frequency ranges of 10.64–10.82 GHz, 12.25–12.47 GHz, and 14.42–14.67 GHz. The maximum PER of 47.16 dB has been achieved for the 14.42–14.67 GHz frequency band at 14.53 GHz. Furthermore, the response of the metasurface does not vary against oblique incidences up to 45°. The simple structure, angular stability, multiband and miniaturized size make this metasurface an outstanding applicant for polarization conversion and biomedical applications

Zoonotic and Reverse Zoonotic Events of SARS-CoV-2 and their Impact on Global Health

Coronaviruses (CoVs) are enveloped, positive sense, single-stranded RNA viruses. The viruses have adapted to infect a large number of animal species, ranging from bats to camels. At present, seven CoVs infect humans, of which Severe Acute Respiratory Syndrome Coronavirus-2 (SARS-CoV-2) is responsible for causing the Coronavirus Disease 2019 (COVID-19) in humans. Since its emergence in late 2019, SARS-CoV-2 has spread rapidly across the globe. Healthcare systems around the globe have been stretched beyond their limits posing new challenges to emergency healthcare services and critical care. The outbreak continues to jeopardize human health, social life and economy. All known human CoVs have zoonotic origins. Recent detection of SARS-CoV-2 in pet, zoo and certain farm animals has highlighted its potential for reverse zoonosis. This scenario is particularly alarming, since these animals could be potential reservoirs for secondary zoonotic infections. In this article, we highlight interspecies SARS-CoV-2 infections and focus on the reverse zoonotic potential of this virus. We also emphasize the importance of potential secondary zoonotic events and the One-Health and One-World approach to tackle such future pandemics

A multifunctional ultrathin flexible bianisotropic metasurface with miniaturized cell size

In this paper, a flexible bianisotropic metasurface possessing omega-type coupling is presented. The designed metasurface behaves differently when excited from either forward (port 1) or back (port 2) sides. It provides an absorption of 99.46% at 15.1 Gigahertz (GHz), when illuminated from port 1, whereas, on simultaneous illumination from port 2, it behaves like a partially reflective surface (PRS). Furthermore, the presented metasurface not only acts as an in-band absorptive surface (port 1) and partially reflective surface (port 2), but it also provides 97% out-of-band transmission at 7.8 GHz. The response of the presented metasurface remains the same for both transverse Electric (TE) and transverse magnetic (TM) polarized wave or any arbitrary linearly polarized wave. Additionally, the response of the metasurface is angularly stable for any oblique incidence up to 45º. The proposed ultrathin flexible metasurface with absorption, partial reflection and out-of-band transmission properties can be used in the Fabry Perrot cavity antenna for gain enhancement with radar cross-section (RCS) reduction both for passband and stop-band filtering, and conformal antenna applications