Activation volume of selected liquid crystals in the density scaling regime

In this paper, we demonstrate and thoroughly analyze the activation volumetric properties of selected liquid crystals in the nematic and crystalline E phases in comparison with those reported for glass-forming liquids. In the analysis, we have employed and evaluated two entropic models (based on either total or configurational entropies) to describe the longitudinal relaxation times of the liquid crystals in the density scaling regime. In this study, we have also exploited two equations of state: volumetric and activation volumetric ones. As a result, we have established that the activation volumetric properties of the selected liquid crystals are quite opposite to such typical properties of glass-forming materials, i.e., the activation volume decreases and the isothermal bulk modulus increases when a liquid crystal is isothermally compressed. Using the model based on the configurational entropy, we suggest that the increasing pressure dependences of the activation volume in isothermal conditions and the negative curvature of the pressure dependences of isothermal longitudinal relaxation times can be related to the formation of antiparallel doublets in the examined liquid crystals. A similar pressure effect on relaxation dynamics may be also observed for other material groups in case of systems, the molecules of which form some supramolecular structures

X-ray observations of the hot phase in Sgr~A*

We analyze 134 ks Chandra ACIS-I observations of the Galactic Centre (GC) performed in July 2011. The X-ray image with the field of view $17' \times 17'$ contains the hot plasma surrounding the Sgr~A*. The obtained surface brightness map allow us to fit Bondi hot accretion flow to the innermost hot plasma around the GC. We have fitted spectra from region up to $5"$ from Sgr~A* using a thermal bremsstrahlung model and four Gaussian profiles responsible for K$_{\alpha}$ emission lines of Fe, S, Ar, and Ca. The X-ray surface brightness profile up to $3"$ from Sgr~A* found in our data image, was successfully fitted with the dynamical model of Bondi spherical accretion. By modelling the surface brightness profile, we derived the temperature and number density profiles in the vicinity of the black hole. The best fitted model of spherical Bondi accretion shows that this type of flow works only up to $3"$ and implies outer plasma density and temperature to be: $n_{\rm e}^{\rm out}=18.3 \pm {0.1}$ cm$^{-3}$ and $T_{\rm e}^{\rm out}= 3.5 \pm {0.3}$ keV respectively. We show that the Bondi flow can reproduce observed surface brightness profile up to $3"$ from Sgr~A* in the Galactic Center. This result strongly suggests the position of stagnation radius in the complicated dynamics around GC. The Faraday rotation computed from our model towards the pulsar PSR J1745-2900 near the GC agrees with the observed one, recently reported.Comment: 10 pages, 7 figures, accepted for publication in A&

Učinak parametara asimetričnog valjanja platine na promjene ukupnog pritiska valjka

This work shows the results of theoretical analysis of asymmetric rolling process of plates in the finishing mill of plate rolling. Its aim was to determine the influence of asymmetry velocity of working rolls on decrease of unit pressure of metal on the rolls. The lower value of the unit pressure will reduce the elastic deflection of the finishing stand and improve the cross-section shape of plate. Three-dimensional simulation of asymmetric hot rolling of S355J2G3 steel plates was done with the aid of FORGE 2008® software. The tensor polynomial interpolation was used for comparing the values of the unit pressure obtaining from symmetric and asymmetric rolling.Rad daje rezultate teorijske analize asimetričnog valjanja platine u završnom stanu. Cilj je odrediti utjecaj asimetrične brzine radnih valjaka na umanjenje jediničnog pritiska metala na valjke. Niža vrijednost jediničnog pritiska smanjiti će elastičnu deformaciju završnog stana. i poboljšati oblik presjeka platine. Trodimenzionalna simulacija asimetričnog vrućeg valjanja S355J2G3 čeličnih platina izvedena je pomoću FORGE 2008® softvera. Polinomni tenzor interpolacije rabljen je za usporedbu vrijednosti jediničnog pritiska dobijenog sa simetričnim I nesimetričnim valjanjem

Experimental and Theoretical Investigation of Overall Energy Deposition in Surface-Induced Unfolding of Protein Ions

Recent advances in native mass spectrometry have enabled its use to probe the structure of and interactions within biomolecular complexes. Surface-induced dissociation, in which inter- and intramolecular interactions are disrupted following an energetic ion-surface collision, is a method that can directly interrogate the topology of protein complexes. However, a quantitative relationship between the ion kinetic energy at the moment of surface collision and the internal energy deposited into the ion has not yet been established for proteins. The factors affecting energy deposition in surface-induced unfolding (SIU) of protein monomers were investigated and a calibration relating laboratory-frame kinetic energy to internal energy developed. Protein monomers were unfolded by SIU and by collision-induced unfolding (CIU). CIU and SIU cause proteins to undergo the same unfolding transitions at different values of laboratory-frame kinetic energy. There is a strong correlation between the SIU and CIU energies, demonstrating that SIU, like CIU, can largely be understood as a thermal process. The change in internal energy in CIU was modeled using a Monte Carlo approach and theory. Computed values of the overall efficiency were found to be approximately 25% and used to rescale the CIU energy axis and relate nominal SIU energies to internal energy. The energy deposition efficiency in SIU increases with mass and kinetic energy from a low of -20% to a high of -68%, indicating that the effective mass of the surface increases along with the mass of the ion. The effect of ion structure on energy deposition was probed using multiple stages of ion activation. Energy deposition in SIU strongly depends on structure, decreasing as the protein is elongated, due to decreased effective protein-surface collisional cross section and increased transfer to rotational modes

The Ursinus Weekly, December 9, 1977

Ursinus news in brief: Ursinus alumnus plays peace role; Union director attends conference; Dusko resigns Snack Shop position; Med student tricked south of border; Student publication fails • Dusko closes Union: March, Williams not warned • Student wages to rise • TFSL meets • Ursinus seeks advising fund • Comment: Ursinus - fact or fiction? • Letters to the editorhttps://digitalcommons.ursinus.edu/weekly/1079/thumbnail.jp