594 research outputs found
Poisson intensity parameter estimation for stationary Gibbs point processes of finite interaction range
We introduce a semi-parametric estimator of the Poisson intensity parameter
of a spatial stationary Gibbs point process. Under very mild assumptions
satisfied by a large class of Gibbs models, we establish its strong consistency
and asymptotic normality. We also consider its finite-sample properties in a
simulation study
On the strict convexity of the Besicovitch-Orlicz space of almost periodic functions with Orlicz nor
The problem of strict convexity of the Besicovitch-Orlicz space of almost periodic functions is considered here in connection with the Orlicz norm. We give necessary and sufficient conditions in terms of the function Á generating the space
About MoO3 as buffer layer in organic optoelectronic devices, Technology Letters
MoO3 is well known as efficient anode buffer layer in optoelectronic devices. Actually, MoO3 can be easily deposited under vacuum, by sublimation for instance, and also by wet process. So it is known from a long time that the films deposited by sublimation are amorphous and slightly oxygen deficient, which induces a light blue coloration due to oxygen vacancies. These oxygen vacancies imply the presence of Mo4+ and Mo5+ in the films. The presence of oxygen vacancies increases the conductivity from 10-12 to 10-6 (Ωcm)-1, while stoichiometric films are insulating and MoO2 has a metallic like behaviour with s = 2 102 (Ωcm)-1. About the efficiency of MoO3 as buffer layer, recent studies questioned the MoO3 band structure generally admitted. Under ultra high vacuum, the measured ionisation energy, IE, and electron affinity are found to be 9.7 eV and 6.7 eV respectively, while the films are strongly n-type. Its means that the very large IE energy of the MoO3 excludes any hole transport via the valence band, while the energy alignment between the band conduction minimum, CB, of MoO3 and the Highest Occupied Molecular Orbital (HOMO) of the organic material is favourable for electron transfer between the two materials. In the case of organic photovoltaic cells, the photogenerated hole recombines with an electron at the interface between MoO3 and the organic layer. Indeed, the work function, WF, of the molybdenum oxide films depends strongly of its composition, WF decreases when the oxygen deficiency increases, and on the exposition, or not, of its surface to air contamination. This makes that WF varies from 6.9 eV for a layer studied under ultra high vacuum to 5.2 eV for a layer exposed to the air a few hours. However, since the initial value of WF is very high, MoO3 remains effective if the Highest Occupied Molecular Orbital of the organic material is lower than 6 eV. The band structure of MoO3 and the large possible variations of WF make that, for specific conditions of preparation and conditioning, MoO3 can also be used as CBL
Towards anode with low indium content as effective anode in organic solar cells
In2O3 thin films (100 nm thick) have been deposited by reactive evaporation of indium, in an oxygen partial atmosphere. Conductive (σ = 3.5×103 S/cm) and transparent films are obtained using the following experimental conditions: oxygen partial pressure = 1×10−1 Pa, substrate temperature = 300 ◦C and deposition rate = 0.02 nm/s. Layers of this In2O3 thick of 5 nm have been introduced in AZO/In2O3 and FTO/In2O3 multilayer anode structures. The performances of organic photovoltaic cells, based on the couple CuPc/C60, are studied using the anode as parameter. In addition to these bilayers, other structures have been used as anode: AZO, FTO, AZO/In2O3/MoO3, FTO/In2O3/MoO3 and FTO/MoO3. It is shown that the use of the In2O3 film in the bilayer structures improves significantly the cell performances. However the open circuit voltage is quite small while better efficiencies are achieved when MoO3 is present. These results are discussed in the light of surface roughness and surface work function of the different anodes
Optimal Fractional-Order PI Control Design for a Variable Speed PMSG-Based Wind Turbine
© 2021 IIETA. . This is an open access article distributed under the Creative Commons Attribution License, to view a copy of the license, see: https://creativecommons.org/licenses/by/4.0/This paper focusses on the design of optimal control strategies for a variable-speed wind energy system based on Permanent Magnet Synchronous Generator (PMSG). The fractional order PI controller, denoted PIλ, is an extension of the classical PI controller, which provides greater flexibility, better performance and robustness, however the tuning of the controller parameters is challenging. In this work, Particle Swarm Optimization (PSO) and Genetic Algorithm (GA) provide approximate solutions to various problems and form a good optimization. In our system, they are used to have the PI regulator parameters and tune the parameters of the proposed controllers. The proposed controllers have been applied as maximum power point (MPPT) controllers for the wind turbine and to regulate the PMGS currents under variable weather conditions and. The results show that, among all these controllers, the fractional order PI controller optimized by the PSO leads to better performance in terms of the transient response characteristics such overshoot, rise time and settling time.Peer reviewedFinal Published versio
On the Intriguing Problem of Counting (n+1,n+2)-Core Partitions into Odd Parts
Tewodros Amdeberhan and Armin Straub initiated the study of enumerating
subfamilies of the set of (s,t)-core partitions. While the enumeration of
(n+1,n+2)-core partitions into distinct parts is relatively easy (in fact it
equals the Fibonacci number F_{n+2}), the enumeration of (n+1,n+2)-core
partitions into odd parts remains elusive.
Straub computed the first eleven terms of that sequence, and asked for a
"formula," or at least a fast way, to compute many terms. While we are unable
to find a "fast" algorithm, we did manage to find a "faster" algorithm, which
enabled us to compute 23 terms of this intriguing sequence. We strongly believe
that this sequence has an algebraic generating function, since a "sister
sequence" (see the article), is OEIS sequence A047749 that does have an
algebraic generating function. One of us (DZ) is pledging a donation of 100
dollars to the OEIS, in honor of the first person to generate sufficiently many
terms to conjecture (and prove non-rigorously) an algebraic equation for the
generating function of this sequence, and another 100 dollars for a rigorous
proof of that conjecture.
Finally, we also develop algorithms that find explicit generating functions
for other, more tractable, families of (n+1,n+2)-core partitions.Comment: 12 pages, accompanied by Maple package. This version announces that
our questions were all answered by Paul Johnson, and a donation to the OEIS,
in his honor, has been mad
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