14,800 research outputs found
On the chain length dependence of local correlations in polymer melts and a perturbation theory of symmetric polymer blends
The self-consistent field (SCF) theory of dense polymer liquids assumes that
short-range correlations are almost independent of how monomers are connected
into polymers. Some limits of this idea are explored in the context of a
perturbation theory for mixtures of structurally identical polymer species, A
and B, in which the AB pair interaction differs slightly from the AA and BB
interaction, and the difference is controlled by a parameter alpha Expanding
the free energy to O(\alpha) yields an excess free energy of the form alpha
, in both lattice and continuum models, where z(N) is a
measure of the number of inter-molecular near neighbors of each monomer in a
one-component liquid. This quantity decreases slightly with increasing N
because the self-concentration of monomers from the same chain is slightly
higher for longer chains, creating a deeper correlation hole for longer chains.
We analyze the resulting -dependence, and predict that , where is an invariant degree of
polymerization, and . This and other predictions are
confirmed by comparison to simulations. We also propose a way to estimate the
effective interaction parameter appropriate for comparisons of simulation data
to SCF theory and to coarse-grained theories of corrections to SCF theory,
which is based on an extrapolation of coefficients in this perturbation theory
to the limit . We show that a renormalized one-loop theory
contains a quantitatively correct description of the -dependence of local
structure studied here.Comment: submitted to J. Chem. Phy
Quantized Non-Abelian Monopoles on S^3
A possible electric-magnetic duality suggests that the confinement of
non-Abelian electric charges manifests itself as a perturbative quantum effect
for the dual magnetic charges. Motivated by this possibility, we study vacuum
fluctuations around a non-Abelian monopole-antimonopole pair treated as point
objects with charges g=\pm n/2 (n=1,2,...), and placed on the antipodes of a
three sphere of radius R. We explicitly find all the fluctuation modes by
linearizing and solving the Yang-Mills equations about this background field on
a three sphere. We recover, generalize and extend earlier results, including
those on the stability analysis of non-Abelian magnetic monopoles. We find that
for g \ge 1 monopoles there is an unstable mode that tends to squeeze magnetic
flux in the angular directions. We sum the vacuum energy contributions of the
fluctuation modes for the g=1/2 case and find oscillatory dependence on the
cutoff scale. Subject to certain assumptions, we find that the contribution of
the fluctuation modes to the quantum zero point energy behaves as -R^{-2/3} and
hence decays more slowly than the classical -R^{-1} Coulomb potential for large
R. However, this correction to the zero point energy does not agree with the
linear growth expected if the monopoles are confined.Comment: 18 pages, 5 figures. Minor changes, reference list update
Resonance modes in a 1D medium with two purely resistive boundaries: calculation methods, orthogonality and completeness
Studying the problem of wave propagation in media with resistive boundaries
can be made by searching for "resonance modes" or free oscillations regimes. In
the present article, a simple case is investigated, which allows one to
enlighten the respective interest of different, classical methods, some of them
being rather delicate. This case is the 1D propagation in a homogeneous medium
having two purely resistive terminations, the calculation of the Green function
being done without any approximation using three methods. The first one is the
straightforward use of the closed-form solution in the frequency domain and the
residue calculus. Then the method of separation of variables (space and time)
leads to a solution depending on the initial conditions. The question of the
orthogonality and completeness of the complex-valued resonance modes is
investigated, leading to the expression of a particular scalar product. The
last method is the expansion in biorthogonal modes in the frequency domain, the
modes having eigenfrequencies depending on the frequency. Results of the three
methods generalize or/and correct some results already existing in the
literature, and exhibit the particular difficulty of the treatment of the
constant mode
Finite Temperature Spectral Densities of Momentum and R-Charge Correlators in Yang Mills Theory
We compute spectral densities of momentum and R-charge correlators in thermal
Yang Mills at strong coupling using the AdS/CFT correspondence. For
and smaller, the spectral density differs markedly from
perturbation theory; there is no kinetic theory peak. For large , the
spectral density oscillates around the zero-temperature result with an
exponentially decreasing amplitude. Contrast this with QCD where the spectral
density of the current-current correlator approaches the zero temperature
result like . Despite these marked differences with perturbation
theory, in Euclidean space-time the correlators differ by only from
the free result. The implications for Lattice QCD measurements of transport are
discussed.Comment: 18 pages, 3 figure
Elastic response of a nematic liquid crystal to an immersed nanowire
We study the immersion of a ferromagnetic nanowire within a nematic liquid
crystal using a lattice Boltzmann algorithm to solve the full three-dimensional
equations of hydrodynamics. We present an algorithm for including a moving
boundary, to simulate a nanowire, in a lattice Boltzmann simulation. The
nematic imposes a torque on a wire that increases linearly with the angle
between the wire and the equilibrium direction of the director field. By
rotation of these nanowires, one can determine the elastic constants of the
nematic.Comment: 10 pages, 8 figure
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