12 New Galactic Wolf-Rayet Stars Identified via 2MASS+Spitzer/GLIMPSE

We report new results from our effort to identify obscured Wolf-Rayet stars in the Galaxy. Candidates were selected by their near-infrared (2MASS) and mid-infrared (Spitzer/GLIMPSE) color excesses, which are consistent with free-free emission from ionized stellar winds and thermal excess from hot dust. We have confirmed 12 new Wolf-Rayet stars in the Galactic disk, including 9 of the nitrogen subtype (WN), and 3 of the carbon subtype (WC); this raises the total number of Wolf-Rayet stars discovered with our approach to 27. We classify one of the new stars as a possible dust-producing WC9d+OBI colliding-wind binary, as evidenced by an infrared excess resembling that of known WC9d stars, the detection of OBI features superimposed on the WC9 spectrum, and hard X-ray emission detected by XMM-Newton. A WC8 star in our sample appears to be a member of the stellar cluster Danks 1, in contrast to the rest of the confirmed Wolf-Rayet stars that generally do not appear to reside within dense stellar clusters. Either the majority of the stars are runaways from clusters, or they formed in relative isolation. We briefly discuss prospects for the expansion and improvement of the search for Wolf-Rayet stars throughout the Milky Way Galaxy.Comment: Submitted to PASP March 12, 2009; Accepted on May 14, 200

Red Eyes on Wolf-Rayet Stars: 60 New Discoveries via Infrared Color Selection

We have spectroscopically identified 60 Galactic Wolf-Rayet (WR) stars, including 38 nitrogen types (WN) and 22 carbon types (WC). Using photometry from the Spitzer/GLIMPSE and 2MASS databases, the WRs were selected via a method we have established that exploits their unique infrared colors, which is mainly the result of excess radiation from free-free scattering within their dense ionized winds. The selection criteria has been refined since our last report, and now yields WRs at a rate of ~20% in spectroscopic follow-up of candidates that comprise a broad color space defined by the color distribution of all known WRs having B>14 mag. However, there are subregions within the broad color space which yield WRs at a rate of >50%. Cross-correlation of WR candidates with archival X-ray point-source catalogs increases the WR detection rate of the broad color space to ~40%; ten new WR X-ray sources have been found, in addition to a previously unrecognized X-ray counterpart to a known WR. The extinction values, distances, and galactocentric radii of all new WRs are calculated using the method of spectroscopic parallax. Although the majority of the new WRs have no obvious association with stellar clusters, two WC8 stars reside in a previously unknown massive-star cluster that lies near the intersection of the Scutum-Centaurus Arm and the Galaxy's bar, in which five OB supergiants were also identified. In addition, two WC and four WN stars were identified in association with the stellar clusters Danks 1 and 2. A WN9 star has also been associated with the cluster [DBS2003] 179. This work brings the total number of known Galactic WRs to 476, or ~7-8% of the total empirically estimated population. An examination of their Galactic distribution reveals a tracing of spiral arms and an enhanced WR surface density toward several massive-star formation sites (abridged).Comment: Accepted to the Astronomical Journal on May 20, 2011. Document is 39 pages, including 20 figures and 8 table

Discovery of Twin Wolf-Rayet Stars Powering Double Ring Nebulae

We have spectroscopically discovered a pair of twin, nitrogen-type, hydrogen-rich, Wolf-Rayet stars (WN8-9h) that are both surrounded by circular, mid-infrared-bright nebulae detected with the Spitzer Space Telescope and MIPS instrument. The emission is probably dominated by a thermal continuum from cool dust, but also may contain contributions from atomic line emission. There is no counterpart at shorter Spitzer/IRAC wavelengths, indicating a lack of emission from warm dust. The two nebulae are probably wind-swept stellar ejecta released by the central stars during a prior evolutionary phase. The nebulae partially overlap on the sky and we speculate on the possibility that they are in the early stage of a collision. Two other evolved massive stars have also been identified within the area subtended by the nebulae, including a carbon-type Wolf-Rayet star (WC8) and an O7-8 III-I star, the latter of which appears to be embedded in one of the larger WN8-9h nebulae. The derived distances to these stars imply that they are coeval members of an association lying 4.9 (1.2) kpc from Earth, near the intersection of the Galaxy's Long Bar and the Scutum-Centaurus spiral arm. This new association represents an unprecedented display of complex interactions between multiple stellar winds, outflows, and the radiation fields of evolved massive stars.Comment: Accepted to ApJ Letters on Friday, September 3, 2010; 15 pages, 4 figure

Three Concurrent Phases of Massive-Star Evolution in a Pulsar-Wind Nebula

The nebular material associated the the SNR G54.1+0.3 (hereafter G54) contains the the first reported instance of triggered star formation in the immediate vicinity of a Pulsar and its Wind Nebula (PWN). With 2MASS and Spitzer colors and followup near-IR spectroscopy, we have discovered the presence of a hot, massive and most likely evolved Be-type star among the cluster of stars hosted by the pulsar. This star has probably triggered cloud collapse and formation of at least 11 YSOs, which ring the nebula. In this unique cluster are now identified three concurrent stages of stellar evolution, from massive star birth, post-Main-Sequence transition, and stellar death

Applications of Machine-Learning Algorithms for Infrared Colour Selection of Galactic Wolf-Rayet Stars

We have investigated and applied machine-learning algorithms for Infrared Colour Selection of Galactic Wolf-Rayet (WR) candidates. Objects taken from the GLIMPSE catalogue of the infrared objects in the Galactic plane can be classified into different stellar populations based on the colours inferred from their broadband photometric magnitudes ($J$, $H$ and $K_s$ from 2MASS, and the four \textit{Spitzer}/IRAC bands). The algorithms tested in this pilot study are variants of the $k$-Nearest Neighbours ($k$-NN) approach, which is ideal for exploratory studies of classification problems where interrelations between variables and classes are complicated. The aims of this study are (1) to provide an automated tool to select reliable WR candidates and potentially other classes of objects, (2) to measure the efficiency of infrared colour selection at performing these tasks and, (3) to lay the groundwork for statistically inferring the total number of WR stars in our Galaxy. We report the performance results obtained over a set of known objects and selected candidates for which we have carried out follow-up spectroscopic observations, and confirm the discovery of 4 new WR stars.Comment: Authors' version of published paper, now at MNRAS, 473, 256

Synthesis of Chiral Nonracemic Tertiary α-Thio and α-Sulfonyl Acetic Esters via SN2 Reactions of Tertiary Mesylates

Syntheses of enantioenriched sulfides and sulfones via substitution of tertiary mesylate with thiolate nucleophile were achieved with modest to excellent success

NASA Ares I Launch Vehicle Upper Stage Reaction Control System (ReCS) Cold Flow Development Test Overview

NASA s Ares I launch vehicle, consisting of a five segment solid rocket booster first stage and a liquid bi-propellant J2-X engine Upper Stage, is the vehicle that s been chosen to launch the Orion Crew Module, which will return humans to the Moon, Mars, and beyond. After First Stage booster separation, the Reaction Control System (ReCS), a monopropellant hydrazine system, will provide the Upper Stage element with three degrees of freedom control as needed. This paper provides an overview of the system level development testing that has taken place on the Ares I launch vehicle Upper Stage ReCS. The ReCS System Development Test Article (SDTA) was built as a flight representative water flow test article whose primary test objective was to obtain fluid system performance data to evaluate the integrate system performance characteristics and verify analytical models. Water is the industry standard for cold flow testing of hydrazine systems, because the densities are very close and the speeds of sound are well characterized. The completion of this development level test program was considered necessary to support the ReCS Critical Design Review. This paper will address the design approach taken in building the test article, the objectives of the test program, types of testing completed, general results, the ability of the program to meet the test objectives, and lessons learne

A Hidden Population of Massive Stars with Circumstellar Shells Discovered with the Spitzer Space Telescope

We have discovered a large number of circular and elliptical shells at 24 microns around luminous central sources with the MIPS instrument on-board the Spitzer Space Telescope. Our archival follow-up effort has revealed 90% of these circumstellar shells to be previously unknown. The majority of the shells is only visible at 24 microns, but many of the central stars are detected at multiple wavelengths from the mid- to the near-IR regime. The general lack of optical counterparts, however, indicates that these sources represent a population of highly obscured objects. We obtained optical and near-IR spectroscopic observations of the central stars and find most of these objects to be massive stars. In particular, we identify a large population of sources that we argue represents a narrow evolutionary phase, closely related or identical to the LBV stage of massive stellar evolution.Comment: 23 pages, 9 figures, accepted for publication in A

First trimester ultrasound measurements and maternal serum biomarkers as prognostic factors in monochorionic twins: a cohort study

Background: Monochorionic twin pregnancies are high-risk of adverse outcomes, but it is not possible to predict which pregnancies will develop complications. The aim of the study was to evaluate, in monochorionic twin pregnancies, whether first trimester ultrasound (nuchal translucency [NT], crown-rump length [CRL]) and maternal serum biomarkers (alpha-fetoprotein (AFP), soluble fms-like tyrosine kinase-1 (sFlt-1), placental growth factor (PlGF)) are prognostic factors for fetal adverse outcome composite, twin-twin transfusion syndrome (TTTS), growth restriction, and intrauterine fetal death (IUFD). Methods: Cohort study of 177 monochorionic diamniotic twin pregnancies. Independent prognostic ability of each factor was assessed by multivariable logistic regression, adjusting for standard prognostic factors. Factors were analysed as continuous data, thus the reported ORs relate either 1% change in NT or CRL inter-twin percentage discordance, or one unit of measure in each serum biomarker. Results: The odds of the fetal adverse outcome composite was significantly associated with increased NT inter-twin percentage discordance (adjusted OR 1.03 [95%CI 1.01,1.06]), and CRL inter-twin percentage discordance (adjusted OR 1.17 [95%CI 1.07,1.29]). TTTS was significantly associated with increased NT discordance (adjusted OR 1.06 [95%CI 1.03,1.10]), and decreased PlGF (adjusted OR 0.42 [95%CI 0.19,0.93]). Antenatal growth restriction was significantly associated with increased CRL discordance (adjusted OR 1.20 [95%CI 1.08,1.34]). Single and double IUFD were associated with decreased PlGF (adjusted OR 0.34 [95%CI 0.12,0.98]) and (adjusted OR 0.18 [95%CI 0.05,0.58]) respectively. Conclusion(s): This study has identified potential individual prognostic factors in the first trimester (fetal biometric and maternal serum biomarkers) that show promise but require further robust evaluation in a larger, prospective series of MC twin pregnancies, so that their usefulness both individually and in combination can be defined. Trial registration: ISRCTN 13114861 (retrospectively registered

Stereospecific decarboylative allylation of sulfones

This document is the Accepted Manuscript version of a Published Work that appeared in final form in the Journal of the American Chemical Society, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see http://doi.org/10.1021/ja104196x.Allyl sulfonyl acetic esters undergo highly stereospecific, palladium-catalyzed decarboxylative allylation. The reaction allows the stereospecific formation of tertiary homoallylic sulfones in high yield. In contrast to related reactions that proceed at -100 °C and require highly basic preformed organometallics, the decarboxylative coupling described herein occurs under mild non-basic conditions and requires no stoichiometric additives. Allylation of the intermediate α-sulfonyl anion is more rapid than racemization, leading to a highly enantiospecific process. DFT calculations indicate that the barrier for racemization is 9.9 kcal/mol and thus the barrier of allylation must be <9.9 kcal/mol