Biomimetic spatial and temporal (4D) design and fabrication

We imagine the built environment of the future as a ‘bio-hybrid machine for living in’ that will sense and react to activities within the space in order to provide experiences and services that will elevate quality of life while coexisting seamlessly with humans and the natural environment. The study of Hierarchical design in biological materials has the potential to alter the way designers/ engineers/ crafts-men of the future engage with materials in order to realise such visions. We are ex-ploring this design approach using digital manufacturing technologies such as jac-quard weaving and 3D printing

Condensate fraction in liquid 4He at zero temperature

We present results of the one-body density matrix (OBDM) and the condensate fraction n_0 of liquid 4He calculated at zero temperature by means of the Path Integral Ground State Monte Carlo method. This technique allows to generate a highly accurate approximation for the ground state wave function Psi_0 in a totally model-independent way, that depends only on the Hamiltonian of the system and on the symmetry properties of Psi_0. With this unbiased estimation of the OBDM, we obtain precise results for the condensate fraction n_0 and the kinetic energy K of the system. The dependence of n_0 with the pressure shows an excellent agreement of our results with recent experimental measurements. Above the melting pressure, overpressurized liquid 4He shows a small condensate fraction that has dropped to 0.8% at the highest pressure of p = 87 bar.Comment: 12 pages. 4 figures. Accepted for publication on "Journal of Low Temperature Physics

Pair densities at contact in the quantum electron gas

The value of the pair distribution function g(r) at contact (r = 0) in a quantum electron gas is determined by the scattering events between pairs of electrons with antiparallel spins. The theoretical results for g(0) as a function of the coupling strength r_s in the paramagnetic electron gas in dimensionality D=2 and 3, that have been obtained from the solution of the two-body scattering problem with a variety of effective scattering potentials embodying many-body effects, are compared with the results of many-body calculations in the ladder approximation and with quantum Monte Carlo data.Comment: 7 pages, 2 figure

The distance to the young cluster NGC 7129 and its age

The dust cloud TGU H645 P2 and embedded in it young open cluster NGC 7129 are investigated using the results of medium-band photometry of 159 stars in the Vilnius seven-colour system down to V = 18.8 mag. The photometric data were used to classify about 50 percent of the measured stars in spectral and luminosity classes. The extinction A_V vs. distance diagram for the 20x20 arcmin area is plotted for 155 stars with two-dimensional classification from the present and the previous catalogues. The extinction values found range between 0.6 and 3.4 mag. However, some red giants, located in the direction of the dense parts of the cloud, exhibit the infrared extinction equivalent up to A_V = 13 mag. The distance to the cloud (and the cluster) is found to be 1.15 kpc (the true distance modulus 10.30 mag). For determining the age of NGC 7129, a luminosity vs. temperature diagram for six cluster members of spectral classes B3 to A1 was compared with the Pisa pre-main-sequence evolution tracks and the Palla birthlines. The cluster can be as old as about 3 Myr, but star forming continues till now as witnessed by the presence in the cloud of many younger pre-main-sequence objects identified with photometry from 2MASS, Spitzer and WISE infrared surveys.Comment: 8 pages, 6 fugures, full Table 1 online. Accepted for publication in MNRAS on 2013 November 3

Competing effects of Mn and Y doping on the low-energy excitations and phase diagram of La1−y_{1-y}Yy_{y}Fe1−x_{1-x}Mnx_xAsO0.89_{0.89}F0.11_{0.11} iron-based superconductors

Muon Spin Rotation ($\mu$SR) and $^{19}$F Nuclear Magnetic Resonance (NMR) measurements were performed to investigate the effect of Mn for Fe substitutions in La$_{1-y}$Y$_{y}$Fe$_{1-x}$Mn$_x$AsO$_{0.89}$F$_{0.11}$ superconductors. While for $y = 0$ a very low critical concentration of Mn ($x = 0.2$%) is needed to quench superconductivity, as $y$ increases the negative chemical pressure introduced by Y for La substitution stabilizes superconductivity and for $y= 20$% it is suppressed at Mn contents an order of magnitude larger. A magnetic phase arises once superconductivity is suppressed both for $y$=0 and for $y= 20$%. Low-energy spin fluctuations give rise to a peak in $^{19}$F NMR $1/T_1$ with an onset well above the superconducting transition temperature and whose magnitude increases with $x$. Also the static magnetic correlations probed by $^{19}$F NMR linewidth measurements show a marked increase with Mn content. The disruption of superconductivity and the onset of the magnetic ground-state are discussed in the light of the proximity of LaFeAsO$_{0.89}$F$_{0.11}$ to a quantum critical point.Comment: 8 pages, 9 figure

A Design Approach of Off-grid Hybrid Electric Microgrids in Isolated Villages: A Case Study in Uganda

Abstract Rural electrification in isolated areas of developing countries can be considered a pivotal factor for economic and social growth, moreover the absence of electricity grid in villages leads to an elevated usage of diesel generators that entails large costs and high CO 2 emissions. This paper presents a design methodology and economical evaluation to implement a hybrid power system composed of a photovoltaic power plant, electrical storage and a backup system of diesel generators in an isolated village in Uganda named Ntoroko. Results show that the usage of battery storage is economically crucial, particularly in areas with a low daily electrical consumption and peak loads increasing in the early morning and late evening when the solar radiation is lower and PV array has a reduced power production. Results disclose that the optimal configuration of the hybrid system (PV-storage-diesel generators), despite its high investment cost, presents an economic benefit of 25.5 and 22.2% compared to the usage of only PV array and diesel generators and only diesel generators and a reduction of fuel consumption equal to 74.7 and 77%, respectively

Mercury Clathration-Driven Phase Transition in a Luminescent Bipyrazolate Metal−Organic Framework: A Multitechnique Investigation

Mercury is one of the most toxic heavy metals. By virtue of its triple bond, the novel ligand 1,2-bis(1H-pyrazol-4- yl)ethyne (H2BPE) was expressly designed and synthesized to devise metal−organic frameworks (MOFs) exhibiting high chemical affinity for mercury. Two MOFs, Zn(BPE) and Zn(BPE)·nDMF [interpenetrated i-Zn and noninterpenetrated ni-Zn·S, respectively; DMF = dimethylformamide], were isolated as microcrystalline powders. While i-Zn is stable in water for at least 15 days, its suspension in HgCl2 aqueous solutions prompts its conversion into HgCl2@ni-Zn. A multitechnique approach allowed us to shed light onto the observed HgCl2-triggered i-Zn-to- HgCl2@ni-Zn transformation at the molecular level. Density functional theory calculations on model systems suggested that HgCl2 interacts via the mercury atom with the carbon−carbon triple bond exclusively in ni-Zn. Powder X-ray diffraction enabled us to quantify the extent of the i-Zn-to-HgCl2@ni-Zn transition in 100−5000 ppm HgCl2 (aq) solutions, while X-ray fluorescence and inductively coupled plasma-mass spectrometry allowed us to demonstrate that HgCl2 is quantitatively sequestered from the aqueous phase. Irradiating at 365 nm, an intense fluorescence is observed at 470 nm for ni-Zn·S, which is partially quenched for i-Zn. This spectral benchmark was exploited to monitor in real time the i-Zn-to-HgCl2@ni-Zn conversion kinetics at different HgCl2 (aq) concentrations. A sizeable fluorescence increase was observed, within a 1 h time lapse, even at a concentration of 5 ppb. Overall, this comprehensive investigation unraveled an intriguing molecular mechanism, featuring the disaggregation of a water-stable MOF in the presence of HgCl2 and the self-assembly of a different crystalline phase around the pollutant, which is sequestered and simultaneously quantified by means of a luminescence change. Such a case study might open the way to new-conception strategies to achieve real-time sensing of mercury-containing pollutants in wastewaters and, eventually, pursue their straightforward and costeffective purification.University of Insubria for partial fundingPrograma Juan de la Cierva Formación (FJC2020-045043-I)MCIN/AEI/10.13039/501100011033European Union NextGenerationEU/PRTR (Grants PID2020- 113608RB-I00 and TED2021-129886B-C41