Antiferro-quadrupole state of orbital-degenerate Kondo lattice model with f^2 configuration

To clarify a key role of $f$ orbitals in the emergence of antiferro-quadrupole structure in PrPb$_{3}$, we investigate the ground-state property of an orbital-degenerate Kondo lattice model by numerical diagonalization techniques. In PrPb$_{3}$, Pr$^{3+}$ has a $4f^{2}$ configuration and the crystalline-electric-field ground state is a non-Kramers doublet $\Gamma_{3}$. In a $j$-$j$ coupling scheme, the $\Gamma_{3}$ state is described by two local singlets, each of which consists of two $f$ electrons with one in $\Gamma_{7}$ and another in $\Gamma_{8}$ orbitals. Since in a cubic structure, $\Gamma_{7}$ has localized nature, while $\Gamma_{8}$ orbitals are rather itinerant, we propose the orbital-degenerate Kondo lattice model for an effective Hamiltonian of PrPb$_{3}$. We show that an antiferro-orbital state is favored by the so-called double-exchange mechanism which is characteristic of multi-orbital systems.Comment: 3 pages, 3 figures, Proceedings of Skutterudite2007 (September 26-30, 2007, Kobe

Porcine and Human intestinal cells for profiling the capacity of colonization and infection of the foodborne pathogen Yersinia enterocolitica

Y. enterocolitica is the third bacterial cause of human enteritis in Europe. The species is divided into six biotypes (BT), BT1A regarded as nonpathogenic and pathogenic biotypes 1B, 2, 3, 4 and 5. Pigs, the principal reservoir for human pathogenic strains, do not develop clinical signs. The BT4 is the most frequently biotype isolated from pig and encountered in human yersiniosis. This study investigated the use of in vitro cultured cells to assess the ability of Y. enterocolitica to adhere and invade pig and human cells. We tested in vitro the adhesion and invasion abilities of a collection of 23 Y. enterocolitica on intestinal pork cells IPEC-J2 and on human intestinal cells Caco-2. The overall profile of adhesion / invasion was different in the both tests. Nevertheless, in the two tests, the BT1A and the BT5 strains, which are rarely isolated from pigs, show a low capacity to adhere and to invade. These strains were clustered in the class 1. The class 2, forming by strains having a greater efficiency of adhesion and/or a greater efficiency of invasion, contained predominantly strains of BT4. The results obtained in this study reflect the ability of BT4 to colonize pigs and the low capacity to BT1A and BT5 to colonize pigs and humans

Thermodynamic metrics and optimal paths

A fundamental problem in modern thermodynamics is how a molecular-scale machine performs useful work, while operating away from thermal equilibrium without excessive dissipation. To this end, we derive a friction tensor that induces a Riemannian manifold on the space of thermodynamic states. Within the linear-response regime, this metric structure controls the dissipation of finite-time transformations, and bestows optimal protocols with many useful properties. We discuss the connection to the existing thermodynamic length formalism, and demonstrate the utility of this metric by solving for optimal control parameter protocols in a simple nonequilibrium model.Comment: 5 page

Monitoring alkylphenols in water using the polar organic chemical integrative sampler (POCIS): determining sampling rates via the extraction of PES membranes and Oasis beads

Polar organic chemical integrative samplers (POCIS) have previously been used to monitor alkylphenol (AP) contamination in water and produced water. However, only the sorbent receiving phase of the POCIS (Oasis beads) is traditionally analyzed, thus limiting the use of POCIS for monitoring a range of APs with varying hydrophobicity. Here a “pharmaceutical” POCIS was calibrated in the laboratory using a static renewal setup for APs (from 2-ethylphenol to 4-n-nonylphenol) with varying hydrophobicity (log Kow between 2.47 and 5.76). The POCIS sampler was calibrated over its 28 day integrative regime and sampling rates (Rs) were determined. Uptake was shown to be a function of AP hydrophobicity where compounds with log Kow < 4 were preferentially accumulated in Oasis beads, and compounds with log Kow > 5 were preferentially accumulated in the PES membranes. A lag phase (over a 24 h period) before uptake in to the PES membranes occurred was evident. This work demonstrates that the analysis of both POCIS phases is vital in order to correctly determine environmentally relevant concentrations owing to the fact that for APs with log Kow ≤ 4 uptake, to the PES membranes and the Oasis beads, involves different processes compared to APs with log Kow ≥ 4. The extraction of both the POCIS matrices is thus recommended in order to assess the concentration of hydrophobic APs (log Kow ≥ 4), as well as hydrophilic APs, most effectively. © 2017 Elsevier Lt

Snow spectral albedo at Summit, Greenland: measurements and numerical simulations based on physical and chemical properties of the snowpack

The broadband albedo of surface snow is determined both by the near-surface profile of the physical and chemical properties of the snowpack and by the spectral and angular characteristics of the incident solar radiation. Simultaneous measurements of the physical and chemical properties of snow were carried out at Summit Camp, Greenland (72°36´ N, 38°25´ W, 3210 m a.s.l.) in May and June 2011, along with spectral albedo measurements. One of the main objectives of the field campaign was to test our ability to predict snow spectral albedo by comparing the measured albedo to the albedo calculated with a radiative transfer model, using measured snow physical and chemical properties. To achieve this goal, we made daily measurements of the snow spectral albedo in the range 350–2200 nm and recorded snow stratigraphic information down to roughly 80 cm. The snow specific surface area (SSA) was measured using the DUFISSS instrument (DUal Frequency Integrating Sphere for Snow SSA measurement, Gallet et al., 2009). Samples were also collected for chemical analyses including black carbon (BC) and dust, to evaluate the impact of light absorbing particulate matter in snow. This is one of the most comprehensive albedo-related data sets combining chemical analysis, snow physical properties and spectral albedo measurements obtained in a polar environment. The surface albedo was calculated from density, SSA, BC and dust profiles using the DISORT model (DIScrete Ordinate Radiative Transfer, Stamnes et al., 1988) and compared to the measured values. Results indicate that the energy absorbed by the snowpack through the whole spectrum considered can be inferred within 1.10%. This accuracy is only slightly better than that which can be obtained considering pure snow, meaning that the impact of impurities on the snow albedo is small at Summit. In the near infrared, minor deviations in albedo up to 0.014 can be due to the accuracy of radiation and SSA measurements and to the surface roughness, whereas deviations up to 0.05 can be explained by the spatial heterogeneity of the snowpack at small scales, the assumption of spherical snow grains made for DISORT simulations and the vertical resolution of measurements of surface layer physical properties. At 1430 and around 1800 nm the discrepancies are larger and independent of the snow properties; we propose that they are due to errors in the ice refractive index at these wavelengths. This work contributes to the development of physically based albedo schemes in detailed snowpack models, and to the improvement of retrieval algorithms for estimating snow properties from remote sensing data

System, Apparatus and Method for Pedal Control

An apparatus, method, and system for controlling motion in six degrees of freedom is described. The apparatus includes a support structure, a first pedal and a second pedal. A first set of three independent articulating mechanisms is operatively connected to the support structure and the first pedal. The first set of three independent articulating mechanisms, in combination, enable motion of the first pedal in three control axes corresponding to three discrete degrees of freedom. A second set of three independent articulating mechanisms, operatively connected to the second pedal, enable motion, in combination, in three control axes corresponding to a discrete second set of three degrees of freedom. The apparatus may also include first and second sensors configured to detect the motion of the first and second pedals

Nonperturbative Matching for Field Theories with Heavy Fermions

We examine a paradox, suggested by Banks and Dabholkar, concerning nonperturbative effects in an effective field theory which is obtained by integrating out a generation of heavy fermions, where the heavy fermion masses arise from Yukawa couplings. They argue that light fermions in the effective theory appear to decay via instanton processes, whereas their decay is forbidden in the full theory. We resolve this paradox by showing that such processes in fact do not occur in the effective theory, due to matching corrections which cause the relevant light field configurations to have infinite action.Comment: 10 pages, no figures, uses harvmac, Harvard University Preprint HUTP-93/A03

Random replicators with high-order interactions

We use tools of the equilibrium statistical mechanics of disordered systems to study analytically the statistical properties of an ecosystem composed of N species interacting via random, Gaussian interactions of order p >= 2, and deterministic self-interactions u <= 0. We show that for nonzero u the effect of increasing the order of the interactions is to make the system more cooperative, in the sense that the fraction of extinct species is greatly reduced. Furthermore, we find that for p > 2 there is a threshold value which gives a lower bound to the concentration of the surviving species, preventing then the existence of rare species and, consequently, increasing the robustness of the ecosystem to external perturbations.Comment: 7 pages, 4 Postscript figure