Discrete Element Modelling of Rock Cutting Processes Interaction with Evaluation of Tool Wear

The document presents a numerical model of rocks and soils using spherical Discrete Elements, also called Distinct Elements. The motion of spherical elements is described by means of equations of rigid body dynamics. Explicit integration in time yields high computational efficiency. Spherical elements interact among one another with contact forces, both in normal and tangential directions. Efficient contact search scheme based on the octree structures has been implemented. Special constitutive model of contact interface taking into account cohesion forces allows us to model fracture and decohesion of materials. Numerical simulation predicts wear of rock cutting tools. The developed numerical algorithm of wear evaluation allows us us to predict evolution of the shape of the tool caused by wear. Results of numerical simulation are validated by comparison with experimental data

Deformations of quantum field theories on de Sitter spacetime

Quantum field theories on de Sitter spacetime with global U(1) gauge symmetry are deformed using the joint action of the internal symmetry group and a one-parameter group of boosts. The resulting theory turns out to be wedge-local and non-isomorphic to the initial one for a class of theories, including the free charged Dirac field. The properties of deformed models coming from inclusions of CAR-algebras are studied in detail.Comment: 26 pages, no figure

Optimizing Carbon Nanotube Contacts for Use in Organic Photovoltaics: Preprint

This report describes research on optimizing carbon nanotube networks for use as transparent electrical contacts (TCs) in organic photovoltaics (OPV)

Short-Term Metal/Organic Interface Stability Investigations of Organic Photovoltaic Devices: Preprint

This paper addresses one source of degradation in OPV devices: the metal/organic interface. The basic approach was to study the completed device stability vs. the stability of the organic film itself as shown in subsequent devices fabricated from the films

Experimental and theoretical investigation of ligand effects on the synthesis of ZnO nanoparticles

ZnO nanoparticles with highly controllable particle sizes(less than 10 nm) were synthesized using organic capping ligands in Zn(Ac)2 ethanolic solution. The molecular structure of the ligands was found to have significant influence on the particle size. The multi-functional molecule tris(hydroxymethyl)-aminomethane (THMA) favoured smaller particle distributions compared with ligands possessing long hydrocarbon chains that are more frequently employed. The adsorption of capping ligands on ZnnOn crystal nuclei (where n = 4 or 18 molecular clusters of(0001) ZnO surfaces) was modelled by ab initio methods at the density functional theory (DFT) level. For the molecules examined, chemisorption proceeded via the formation of Zn...O, Zn...N, or Zn...S chemical bonds between the ligands and active Zn2+ sites on ZnO surfaces. The DFT results indicated that THMA binds more strongly to the ZnO surface than other ligands, suggesting that this molecule is very effective at stabilizing ZnO nanoparticle surfaces. This study, therefore, provides new insight into the correlation between the molecular structure of capping ligands and the morphology of metal oxide nanostructures formed in their presence

Enhanced Lifetime Of Excitons In Nonepitaxial Au/cds Core/shell Nanocrystals

The ability of metal nanoparticles to capture light through plasmon excitations offers an opportunity for enhancing the optical absorption of plasmon-coupled semiconductor materials via energy transfer. This process, however, requires that the semiconductor component is electrically insulated to prevent a backward charge flow into metal and interfacial states, which causes a premature dissociation of excitons. Here we demonstrate that such an energy exchange can be achieved on the nanoscale by using nonepitaxial Au/CdS core/shell nanocomposites. These materials are fabricated via a multistep cation exchange reaction, which decouples metal and semiconductor phases leading to fewer interfacial defects. Ultrafast transient absorption measurements confirm that the lifetime of excitons in the CdS shell (tau approximate to 300 ps) is much longer than lifetimes of excitons in conventional, reduction-grown Au/CdS heteronanostructures. As a result, the energy of metal nanoparticles can be efficiently utilized by the semiconductor component without undergoing significant nonradiative energy losses, an important property for catalytic or photovoltaic applications. The reduced rate of exciton dissociation in the CdS domain of Au/CdS nanocomposites was attributed to the nonepitaxial nature of Au/CdS interfaces associated with low defect density and a high potential barrier of the interstitial phase