85 research outputs found

    Diamond Synthesis Employing Nanoparticle Seeds

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    Iron nanoparticles were employed to induce the synthesis of diamond on molybdenum, silicon, and quartz substrates. Diamond films were grown using conventional conditions for diamond synthesis by hot filament chemical vapor deposition, except that dispersed iron oxide nanoparticles replaced the seeding. This approach to diamond induction can be combined with dip pen nanolithography for the selective deposition of diamond and diamond patterning while avoiding surface damage associated to diamond-seeding methods

    Diamond Nucleation Using Polyethene

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    The invention presents a simple, non-destructive and non-abrasive method of diamond nucleation using polyethene. It particularly describes the nucleation of diamond on an electrically viable substrate surface using polyethene via chemical vapor deposition (CVD) technique in a gaseous environment

    Hot Filament Chemical Vapor Deposition: Enabling the Scalable Synthesis of Bilayer Graphene and Other Carbon Materials

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    The hot filament chemical vapor deposition (HFCVD) technique is limited only by the size of the reactor and lends itself to be incorporated into continuous roll-to-roll industrial fabrication processes. We discuss the HFCVD reactor design and the interplay between the reactor parameters, such as filament and substrate temperatures, filament-to-substrate distance, and total pressure. Special attention is given to the large-area synthesis of bilayer graphene on copper, which is successfully grown by HFCVD with transmittance greater than 90% in the visible region and no gaps. We also discuss the HFCVD synthesis of carbon nanotubes, microcrystalline diamond, and nanocrystalline diamond

    Low-Energy, Hydrogen-Free Method of Diamond Synthesis

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    Diamond thin films were deposited on copper substrate by the Vapor Solid (VS) deposition method using a mixture of fullerene C(sub 60) and graphite as the source material. The deposition took place only when the substrate was kept in a narrow temperature range of approximately 550-650 C. Temperatures below and above this range results in the deposition of fullerenes and other carbon compounds, respectively

    Antibacterial Activity of Silver-Graphene Quantum Dots Nanocomposites Against Gram-Positive and Gram-Negative Bacteria

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    The invention provides a composite of silver nanoparticles decorated with graphene quantum dots (Ag-GQDs) using pulsed laser synthesis. The nanocomposites were functionalized with polyethylene glycol (PEG). A concentration of 150 .mu.g/mL of Ag-GQDs, a non-toxic level for human cells, exhibits strong antibacterial activity against both Gram-Positive and Gram-Negative Bacteria

    Study on the optical and electrical properties of tetracyanoethylene doped bilayer graphene stack for transparent conducting electrodes

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    We report the optical and electrical properties of chemically-doped bilayer graphene stack by tetracyanoethylene, a strong electron acceptor. The Tetracyanoethylene doping on the bilayer graphene via charge transfer was confirmed by Raman spectroscopy and Infrared Fourier transform spectroscopy. Doped graphene shows a significant increase in the sheet carrier concentration of up to 1.520 × 1013 cm−2 with a concomitant reduction of the sheet resistance down to 414.1 Ω/sq. The high optical transmittance (ca. 84%) in the visible region in combination with the low sheet resistance of the Tetracyanoethylene-doped bilayer graphene stack opens up the possibility of making transparent conducting electrodes for practical applications

    Synthesis of Palladium with Different Nanoscale Structures by Sputtering Deposition onto Fiber Templates

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    A flexible and versatile method combining sputtering and electrospinning techniques was used to shape different palladium morphological structures with nanoscale features. The samples were prepared by dc-magnetron sputtering onto thermally degradable polymer templates. The sputtering parameters were chosen to deposit the metal under low adatom-mobility conditions. After deposition, the template was removed by heat treatment, thereby forming different palladium morphologies with shapes resembling ribbons and half tubes, amongst others. X-ray diffraction studies demonstrated that they are composed of crystalline palladium or palladium oxide, depending on the heat treatment. The cylindrical walls are composed of 30 nm or smaller crystallites, as measured from transmission electron microscopy images. A mathematical simulation demonstrate that the morphological structures obtained are a consequence of the sputtering line-of-sight deposition process. This fabrication process can be varied to modify three types of structures at the nanoscale level: the external shape, the columnar shape of the walls, and the nano-crystallinity. The external shape can be modified by controlling the deposition time and the fiber template diameter. The columnar shape of the walls and the nano-crystallinity can be modified by changes in the sputtering process parameters. The nanoscale morphologies created have potential uses in sensing and photonic applications

    Rol del oxido nitrico (NO) sobre el efecto inotropico negativo asociado con el estrés hipertónico

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    En diferentes situaciones patológicas como estados de deshidratación severa, hiperglucemia, hiperlipidemia y diabetes, los cardiomiocitos sufren encogimiento osmótico y éste se asocia con un efecto inotrópico negativo (EIN). En un trabajo previo demostramos que el hinchamiento hipotónico promueve la liberación de Óxido Nítrico (NO) y que éste aportaría soporte contráctil. El objetivo de este estudio es evaluar si el estrés hipertónico (SH) también promueve la liberación de NO y de ser así, examinar su impacto sobre la contractilidad.Facultad de Ciencias Médica

    Rol del oxido nitrico (NO) sobre el efecto inotropico negativo asociado con el estrés hipertónico

    Get PDF
    En diferentes situaciones patológicas como estados de deshidratación severa, hiperglucemia, hiperlipidemia y diabetes, los cardiomiocitos sufren encogimiento osmótico y éste se asocia con un efecto inotrópico negativo (EIN). En un trabajo previo demostramos que el hinchamiento hipotónico promueve la liberación de Óxido Nítrico (NO) y que éste aportaría soporte contráctil. El objetivo de este estudio es evaluar si el estrés hipertónico (SH) también promueve la liberación de NO y de ser así, examinar su impacto sobre la contractilidad.Facultad de Ciencias Médica
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