396 research outputs found

    Assessing the reliability and validity of agility testing in team sports: a systematic review

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    The aims of this systematic review were to: 1) examine the reliability of the reactive agility tests and, 2) analyse the discriminatory validity of the agility tests. A literature search was conducted following the Preferred Reporting Items for Systematic Reviews and Meta-Analyses (PRISMA). We explored PubMed, SPORTDiscus and Cochrane Plus databases looking for articles about agility in team sports. After filtering for article relevance, only 42 studies met the inclusion criteria; 37 of which assessed the reliability of agility tests and 22 assessing their validity. Reliability showed a high ICC in almost all studies (range 0.79-0.99) with the exception of two studies. In addition, other studies also assessed the reliability of decision time (ICC=0.95), movement time (ICC=0.92) and decision accuracy (ICC=0.74-0.93), all of which exhibited acceptable reliability. Furthermore, these data show high discriminatory validity, with higher performance players being faster than lower performance level players (mean = 6.4%, range = 2.1-25.3%), with a faster decision time (mean = 23.2%, range = 10.2-48.0%) with the exception of one study, and better decision accuracy (mean = 9.3%, range = 2.5-21.0%). Thus, it can be concluded that reactive agility tests show good reliability and discriminatory validity. However, most agility tests occur in simple contexts whereby only two possible responses are possible. Therefore, future research should consider creating more specific and complex environments which challenge the cognitive process of high-level athletes

    Cambios en la arquitectura muscular y en la velocidad de ejecución de sentadillas en VersaPulley en condiciones estables e inestables en jugadores junior de baloncesto de élite durante una temporada

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    Los objetivos del presente estudio fueron: a) monitorizar y comparar la velocidadpico de ejecución de sentadillas con VersaPulley (VP) en condiciones estables (CE) y condiciones inestables (CI) en jugadores junior de baloncesto de élite durante una temporada y b) evaluar los cambios en la arquitectura muscular (AM). Siete jugadores junior de baloncesto realizaron el entrenamiento técnico-táctico y de acondicionamiento físico de la temporada (16 horas semanales) incluyendo entrenamiento de fuerza mediante sentadillas con VP en CE y CI. Durante la temporada se evaluó la velocidadpico de ejecución de las sentadillas mediante el sistema T-FORCE. Además, cada 3 meses se valoró la AM del vasto lateral mediante ultrasonidos. Los resultados no mostraron diferencias significativas en la velocidad pico al realizar sentadillas entre ambas condiciones en ningún momento de la temporada, aumentando un 17% en CE y un 23% en CI (p<0,01). El grosor muscular (p= 0,009) y el ángulo de peneación (p<0,05) aumentaron mientras que la longitud de los fascículos no experimentó cambios significativos. El entrenamiento regular de baloncesto y el entrenamiento de fuerza incluyendo sentadillas con VP en CE y CI generaron niveles similares de velocidadpico en ambas condiciones en jugadores de baloncesto júnior de élite. La velocidadpico aumentó tanto en CE como en CI durante la temporada. Además, se produjeron cambios en la AM

    Design of the traction battery for a Formula SAE racing car

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    This paper describes the design of the traction battery for the new electric Formula SAE vehicle of the University of Pisa. A model based design methodology extended to the mechanical, electrical and thermal domains was applied to find the best trade-off between the battery weight and the maximum power available at the wheel. The designed battery configuration was validated by means of electrical and thermal simulations

    MoS2 Nanosheets Uniformly Anchored on NiMoO4 Nanorods, a Highly Active Hierarchical Nanostructure Catalyst for Oxygen Evolution Reaction and Pseudo-Capacitors

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    Hierarchical nanostructures have attracted considerable research attention due to their applications in the catalysis field. Herein, we design a versatile hierarchical nanostructure composed of NiMoO4 nanorods surrounded by active MoS2 nanosheets on an interconnected nickel foam substrate. The as-prepared nanostructure exhibits excellent oxygen evolution reaction per-formance, producing a current density of 10 mA cm−2 at an overpotential of 90 mV, in comparison with 220 mV necessary to reach a similar current den-sity for NiMoO4. This behavior originates from the structural/morphological properties of the MoS2 nanosheets, which present numerous surface-active sites and allow good contact with the electrolyte. Besides, the structures can effectively store charges, due to their unique branched network providing accessible active surface area, which facilitates intermediates adsorptions. Particularly, NiMoO4/MoS2 shows a charge capacity of 358 mAhg−1 at a current of 0.5 A g−1 (230 mAhg−1 for NiMoO4), thus suggesting promising applications for charge-storing devices

    Implementation of the fast charging concept for electric local public transport: The case-study of a minibus

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    This paper shows an effective implementation of the fast charging concept in the electric local public transport context. An electric minibus powered with a lead-acid battery is considered as a case-study. Its traction battery is redesigned using 12 V standard lithium-iron-phosphate modules to benefit from the higher performance of the lithium battery technology compared to the lead-acid one. The minibus can achieve a continuous operation characterised by 20 min of traveling alternated with 10 min of standstill for fast recharging of the battery. Experiments performed on a single module of the battery show that the load profile is sustained without appreciable issues both in temperature and life degradation of the lithium cells

    Clarifying the apparent flattening of the graphene band near the van Hove singularity

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    Graphene band renormalization near the van Hove singularity (VHS) has been investigated by angle-resolved photoemission spectroscopy (ARPES) on Li-doped quasifreestanding graphene on a cobalt (0001) surface. The absence of graphene band hybridization with the substrate, the doping contribution well represented by a rigid energy shift, and the excellent electron-electron interaction screening ensured by the metallic substrate offer a privileged point of view for such an investigation. A clear ARPES signal is detected along the KMK direction of the graphene Brillouin zone, giving rise to an apparent flattened band. By simulating the graphene spectral function from the density functional theory calculated bands, we demonstrate that the photoemission signal around the M point originates from the "tail"of the spectral function of the unoccupied band above the Fermi level. Such an interpretation puts forward the absence of any additional strong correlation effects near the VHS, reconciling the mean-field description of the graphene band structure even in a highly doped scenario

    Low-temperature insulating phase of the Si(111)–7×7 surface

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    We investigated the electronic structure of the Si(111)-7 x 7 surface below 20 K by scanning tunneling and photoemission spectroscopies and by density functional theory calculations. Previous experimental studies have questioned the ground state of this surface, which is expected to be metallic in a band picture because of the odd number of electrons per unit cell. Our differential conductance spectra instead show the opening of an energy gap at the Fermi level and a significant temperature dependence of the electronic properties, especially for the adatoms at the center of the unfaulted half of the unit cell. Complementary photoemission spectra with improved correction of the surface photovoltage shift corroborate the differential conductance data and demonstrate the absence of surface bands crossing the Fermi level at 17 K. These consistent experimental observations point to an insulating ground state and contradict the prediction of a metallic surface obtained by density functional theory in the generalized gradient approximation. The calculations indicate that this surface has or is near a magnetic instability, but remains metallic in the magnetic phases even including correlation effects at mean-field level. We discuss possible origins of the observed discrepancies between experiments and calculations

    From the Hofstadter to the Fibonacci butterfly

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    We show that the electronic spectrum of a tight-binding Hamiltonian defined in a quasiperiodic chain with an on-site potential given by a Fibonacci sequence, can be obtained as a superposition of Harper potentials. The electronic spectrum of the Harper equation is a fractal set, known as Hofstadter butterfly. Here we show that is possible to construct a similar butterfly for the Fibonacci potential just by adding harmonics to the Harper potential. As a result, the equations in reciprocal space for the Fibonacci case have the form of a chain with a long range interaction between Fourier components. Then we explore the transformation between both spectra, and specifically the origin of energy gaps due to the analytical calculation of the components in reciprocal space of the potentials. We also calculate some localization properties by finding the correlator of each potential.Comment: 7 pages, 4 figure

    NiMoO4@Co3O4 Core–Shell Nanorods: In Situ Catalyst Reconstruction toward High Efficiency Oxygen Evolution Reaction

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    The sluggish kinetics of the oxygen evolution reaction (OER) is the bottleneck for the practical exploitation of water splitting. Here, the potential of a core–shell structure of hydrous NiMoO4 microrods conformally covered by Co3O4 nanoparticles via atomic layer depositions is demonstrated. In situ Raman and synchrotron-based photoemission spectroscopy analysis confirms the leaching out of Mo facilitates the catalyst reconstruction, and it is one of the centers of active sites responsible for higher catalytic activity. Post OER characterization indicates that the leaching of Mo from the crystal structure, induces the surface of the catalyst to become porous and rougher, hence facilitating the penetration of the electrolyte. The presence of Co3O4 improves the onset potential of the hydrated catalyst due to its higher conductivity, confirmed by the shift in the Fermi level of the heterostructure. In particular NiMoO4@Co3O4 shows a record low overpotential of 120 mV at a current density of 10 mA cm−2, sustaining a remarkable performance operating at a constant current density of 10, 50, and 100 mA cm−2 with negligible decay. Presented outcomes can significantly contribute to the practical use of the water-splitting process, by offering a clear and in-depth understanding of the preparation of a robust and efficient catalyst for water-splitting
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