12 research outputs found

    The polymer-supported MacDonald-type porphyrin synthesis: Coupling of two dissimilar dipyrromethanes

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    Syntheses of two completely unsymmetrical porphyrins have been achieved by MacDonald-type condensations of polymer-bound 9-formyldipyrromethanes with dissimilar solution-phase dipyrromethanes. The chemoselectivity of the process depends on the nature of the substituents at the α positions of the substrates. (C) 2000 Elsevier Science Ltd
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