Groundwater quality assessment for different uses using various water quality indices in semi-arid region of central Tunisia

The Hajeb Layoun-Jelma basin, located in the central Tunisia, is the principal source of water supply for Sidi Bouzid and Sfax region. The over-abstraction from this groundwater, since 1970, and the intensive agriculture activities led to the degradation of the water quantity and quality. The quality evaluation for this groundwater is very important tool for sustainable development and decision for water management. A total of 28 groundwater samples, from shallow, springs, and deep aquifers, were collected, storage and analyzed to evaluate its quality suitability for domestic and agriculture purposes using geographic information system and geochemical methods. For the both aquifers, the abundance of cations: Na > Mg > Ca > K, and of anions in the order: Cl > HCO3 > SO4. The dominant hydrochemical facies, for the shallow aquifer and springs, are Na-Cl and Ca-Mg-Cl; for the deep aquifer, the geochemical facies are Na-Cl, Ca-Mg-Cl, and Ca-Cl. The comparison of the major parameters and the chemical data with the World Health Organization standards and the national standards indicate that this groundwater is suitable for drinking, except in some samples, with high salinity concentrations. The water quality was assessed, for drinking uses, using "water quality index," "entropy," and "improved water quality index." The results mentioned that the improved water quality index is the best method which indicated that the poor water quality coincide with the Na-Cl water type. The entropy method and the water quality index present the optimistic methods. The irrigation suitability assessment was made using various parameters (SAR, TH, % Na, PI, MH, KR, EC). The results revealed that the majority of samples in Hajeb Layoun-Jelma basin are not appropriate for irrigation uses

Impact of floodwaters on vertical water fluxes in the deep vadose zone of an alluvial aquifer in a semi-arid region

The spatial and temporal variation of moisture distribution, overall water balance and quantity of infiltrated water in the vadose zone of the Sidi Bouzid Plain (Tunisia) during successive flooding events is quantified in this study. The variation in water content in response to environmental factors such as evaporation and water root uptake is also highlighted. One-dimensional flow simulations in the deep vadose zone were conducted at three spreading perimeters located near Wadi El Fekka. The hydraulic boundary conditions of a time-dependent water blade applied to the soil surface were determined from measured flood hydrographs. For the chosen wet year, the successive flooding events contributed to a significant artificial recharge of the natural groundwater. Although the soil hydraulic parameters did not vary strongly in space, flow simulations showed significant differences in the overall water balance of approximately 9–16% for the various spreading perimeters

Rapid quantitative determination of oleuropein in olive leaves (Olea europaea) using mid-infrared spectroscopy combined with chemometric analyses

International audienceOleuropein, the major active compound in olive leaf, is well known for its benefits for human health. Oleu-ropein is classically quantified by HPLC, which is time and chemical consuming, laborious and expensive. The aim of this work was to examine the potential of mid-infrared spectroscopy, as a rapid tool, to predict oleuropein content in olive leaf from five Tunisian cultivars (Chemlali, Chetoui, Meski, Sayali and Zarrazi) and one French cultivar (Bouteillan). The reference data of oleuropein content were obtained by the HPLC method. Hundred five samples were analyzed by HPLC and mid-infrared spectroscopy. Samples were randomly divided in a calibration set (73 samples) and in a validation set (32 samples). The spectral data sets were correlated with reference data of oleuropein content by using partial least squares (PLS) regression algorithm. The results showed that the PLS model gave satisfactory model for quantitative prediction of oleuropein content in olive leaf (relative error of prediction = 8.5%). The correlation coefficient was 0.91 and 0.74 for calibration set and validation set, respectively. It can be concluded that mid-infrared spectroscopy constitutes a promising technique for rapid quantification of oleuropein in olive leaf

Canopy light heterogeneity drives leaf anatomical, eco-physiological, and photosynthetic changes in olive trees grown in a high-density plantation

15 p., 8 fig., 2 tab. Available online 26 October 2014. The definitive version is available at: http://link.springer.com/article/10.1007/s11120-014-0052-2In the field, leaves may face very different light intensities within the tree canopy. Leaves usually respond with light-induced morphological and photosynthetic changes, in a phenomenon known as phenotypic plasticity. Canopy light distribution, leaf anatomy, gas exchange, chlorophyll fluorescence, and pigment composition were investigated in an olive (Olea europaea, cvs. Arbequina and Arbosana) orchard planted with a high-density system (1,250 trees ha−1). Sampling was made from three canopy zones: a lower canopy (2 m). Light interception decreased significantly in the lower canopy when compared to the central and top ones. Leaf angle increased and photosynthetic rates and non-photochemical quenching (NPQ) decreased significantly and progressively from the upper canopy to the central and the lower canopies. The largest leaf areas were found in the lower canopy, especially in the cultivar Arbequina. The palisade and spongy parenchyma were reduced in thickness in the lower canopy when compared to the upper one, in the former due to a decrease in the number of cell layers from three to two (clearly distinguishable in the light and fluorescence microscopy images). In both cultivars, the concentration of violaxanthin-cycle pigments and β-carotene was higher in the upper than in the lower canopy. Furthermore, the de-epoxidized forms zeaxanthin and antheraxanthin increased significantly in those leaves from the upper canopy, in parallel to the NPQ increases. In conclusion, olive leaves react with morphological and photosynthetic changes to within-crown light gradients. These results strengthen the idea of olive trees as “modular organisms” that adjust the modules morphology and physiology in response to light intensity.This work was supported by the Spanish Agency of International Cooperation for Development (AECID) Project AP/040397/11 and the Aragón Government (A03 Research Group)Peer reviewe