Δ14C balance for the Gulf of Maine, Long Island Sound and the northern Middle Atlantic Bight: Evidence for the extent of the Antarctic Intermediate Water contribution

The radiocarbon signatures of the western Sargasso Sea and the atmosphere as a function of time over the past 200 years are known. These can be combined with seawater dissolved inorganic carbon (DIC) radiocarbon data from the Gulf of Maine and the northern Middle Atlantic Bight (MAB), including Long Island Sound (LIS), for 1983 and pre-1955 shell analyses for radiocarbon, to set the amount of Antarctic Intermediate Water (AAIW) required to balance the 14C budget in the northern MAB. Approximately 40% of the water entering the Middle Atlantic Bight from the north must be AAIW, the other 60% being Sargasso Sea water. Contemporary water from LIS, a part of northern MAB, can be explained as a mixture of Sargasso Sea water and Gulf of Maine water but at times in the past more low-14C water (AAIW) was added to this mixture as recorded in shells from LIS. This implies variations in upwelling rates over time in the region of the Middle Atlantic Bight

The relationships between oral language and reading instruction: Evidence from a computational model of reading

Reading acquisition involves learning to associate visual symbols with spoken language. Multiple lines of evidence indicate that instruction on the relationship between spellings and sounds may be particularly important.However, it is unclear whether the effectiveness of this form of instruction depends on pre-existing oral language knowledge.To investigate this issue, we developed a series of computational models of reading incorporating orthographic, phonological and semantic processing to simulate bothartificialand natural orthographic learning conditions in adults and children. We exposed the models to instruction focused on spelling-sound or spelling-meaning relationships, and tested the influence of the models' oral language proficiency on the effectiveness of these training regimes. Overall, the simulations indicated thatoral language proficiency is a vital foundation for reading acquisition, and may modulate the effectiveness of reading instruction. These results provide a computational basis for the Simple View of Reading,and emphasise the importance of both oral language knowledge and spelling-sound instructionin the initial stages of learning to read

The caries experience of 5 year-old children in Scotland in 2013-2014, and in England and Wales in 2014-2015. Reports of cross-sectional dental surveys using BASCD criteria

Objective: We report the findings from and comment on the surveys of the oral health of 5-year-old children undertaken in Scotland (2013-14), Wales (2014-15) and England (2014-15). This was the fourteenth survey in Scotland since 1988. In England and Wales it is the third survey since 2007 when changes were required in consent arrangements. Method: Representative samples were drawn within Health Boards across Scotland and local authorities across England and Wales. Consent was sought via opt-out parental consent in Scotland and opt-in parental consent in England and Wales. Children examined were those aged five in England and those in Primary 1 (school year aged 5 to 6) in Scotland and Wales. Examinations were conducted in schools by trained and calibrated examiners. Caries was visually diagnosed at the dentinal threshold. Results: There is a continuing decline in d3mft in all three countries. d3mft was 1.27 (opt-out consent) for Scotland, 0.84 for England (opt-in consent) and 1.29 for Wales (opt-in consent). Tooth decay levels remain higher in more deprived areas across Great Britain, with clear inequalities gradients demonstrated across all geographies. Attempts to measure changes in dental health inequalities across the three countries show no conclusive trends. Conclusion: Inter-country comparisons provide further oral health intelligence despite differences in approach and timing. The third surveys in England and Wales using the new consent arrangements have enabled trend analysis. Dental health inequalities gradients were shown across all geographies and all of the indicators of inequalit

Feynman graph polynomials

The integrand of any multi-loop integral is characterised after Feynman parametrisation by two polynomials. In this review we summarise the properties of these polynomials. Topics covered in this article include among others: Spanning trees and spanning forests, the all-minors matrix-tree theorem, recursion relations due to contraction and deletion of edges, Dodgson's identity and matroids.Comment: 35 pages, references adde

Hydrodynamic Processes in Young Binary Systems as a Source of Cyclic Variations of Circumstellar Extinction

Hydrodynamic models of a young binary system accreting matter from the remnants of a protostellar cloud have been calculated by the SPH method. It is shown that periodic variations in column density in projection onto the primary component take place at low inclinations of the binary plane to the line of sight. They can result in periodic extinction variations. Three periodic components can exist in general case. The first component has a period equal to the orbital one and is attributable to the streams of matter penetrating into the inner regions of the binary. The second component has a period that is a factor of 5-8 longer than the orbital one and is related to the density waves generated in a circumbinary (CB) disk. The third, longest period is attributable to the precession of the inner asymmetric region of CB disk. The relationship between the amplitudes of these cycles depends on the model parameters as well as on the inclination and orientation of the binary in space. We show that at a dust-to-gas ratio of 1:100 and and a mass extinction coefficient of 250 cm$^2$ g$^{-1}$, the amplitude of the brightness variations of the primary component in the V-band can reach $1^m$ at a mass accretion rate onto the binary components of $10^{-8} M_{\odot}$ yr$^{-1}$ and a $10^{\rm o}$ inclination of the binary plane to the line of sight. We discuss possible applications of the model to pre-main-sequence stars.Comment: 13 pages, 6 figures, published in Astronomy Letters (v.33, 2007

Interactions between diurnal winds and floodplain mosaics control the insect boundary layer in a river corridor

Insect flight along river corridors is a fundamental process that facilitates sustainable succession and diversity of aquatic and terrestrial insect communities in highly dynamic fluvial environments. This study examines variations in the thickness of the insect boundary layer (i.e., the pre-surface atmosphere layer in which air velocity does not exceed the sustained speed of flying insects) caused by interactions between diurnal winds and the heterogenous habitat mosaics in the floodplain of a braided river. Based on advective–diffusive theory, we develop and test a semi-empirical model that relates vertical flux of flying insects to vertical profiles of diurnal winds. Our model suggests that, in the logarithmic layer of wind, the density of insect fluxes decreases exponentially with the altitude due to the strong physical forcing. Inside the insect boundary layer, the insect fluxes can increase with the altitude while the winds speed remains nearly constant. We suggest a hypothesis that there is a close correspondence between the height of discontinuity points in the insect profiles (e.g. points with abrupt changes of the insect flux) and the displacement heights of the wind profiles (e.g. points above which the wind profile is logarithmic). Vertical profiles were sampled during three time-intervals at three different habitat locations in the river corridor: a bare gravel bar, a gravel bar with shrubs, and an island with trees and shrubs. Insects and wind speed were sampled and measured simultaneously over each location at 1.5-m intervals up to approximately 17 m elevation. The results support our working hypothesis on close correspondence between discontinuity and displacement points. The thickness of the insect boundary layer matches the height of the discontinuity points and was about 5 m above the bare gravel bar and the gravel bar with shrubs. Above the island, the structure of the insect boundary layer was more complex and consisted of two discontinuity points, one at the mean height of the trees’ crowns (ca. 15 m), and a second, internal boundary layer at the top of the shrubs (ca. 5 m). Our findings improve the understanding of how vegetation can influence longitudinal and lateral dispersal patterns of flying insects in river corridors and floodplain systems. It also highlights the importance of preserving terrestrial habitat diversity in river floodplains as an important driver of both biotic and abiotic (i.e., morphology and airscape) heterogeneit

Interactions between diurnal winds and floodplain mosaics control the insect boundary layer in a river corridor

Insect flight along river corridors is a fundamental process that facilitates sustainable succession and diversity of aquatic and terrestrial insect communities in highly dynamic fluvial environments. This study examines variations in the thickness of the insect boundary layer (i.e., the pre-surface atmosphere layer in which air velocity does not exceed the sustained speed of flying insects) caused by interactions between diurnal winds and the heterogenous habitat mosaics in the floodplain of a braided river. Based on advective–diffusive theory, we develop and test a semi-empirical model that relates vertical flux of flying insects to vertical profiles of diurnal winds. Our model suggests that, in the logarithmic layer of wind, the density of insect fluxes decreases exponentially with the altitude due to the strong physical forcing. Inside the insect boundary layer, the insect fluxes can increase with the altitude while the winds speed remains nearly constant. We suggest a hypothesis that there is a close correspondence between the height of discontinuity points in the insect profiles (e.g. points with abrupt changes of the insect flux) and the displacement heights of the wind profiles (e.g. points above which the wind profile is logarithmic). Vertical profiles were sampled during three time-intervals at three different habitat locations in the river corridor: a bare gravel bar, a gravel bar with shrubs, and an island with trees and shrubs. Insects and wind speed were sampled and measured simultaneously over each location at 1.5-m intervals up to approximately 17 m elevation. The results support our working hypothesis on close correspondence between discontinuity and displacement points. The thickness of the insect boundary layer matches the height of the discontinuity points and was about 5 m above the bare gravel bar and the gravel bar with shrubs. Above the island, the structure of the insect boundary layer was more complex and consisted of two discontinuity points, one at the mean height of the trees’ crowns (ca. 15 m), and a second, internal boundary layer at the top of the shrubs (ca. 5 m). Our findings improve the understanding of how vegetation can influence longitudinal and lateral dispersal patterns of flying insects in river corridors and floodplain systems. It also highlights the importance of preserving terrestrial habitat diversity in river floodplains as an important driver of both biotic and abiotic (i.e., morphology and airscape) heterogeneity

Running virtual reactions: A reaction predictor app for teaching organic chemistry

Background: Students are often daunted by the process of learning the functional groups (FG’s) and functional group interconversions (FGI’s) in undergraduate organic chemistry courses.1-3 Problems arise when students attempt to rote learn, rather than understand and predict reactions.4 Owing to the portability and increasing proliferation of mobile platforms (i.e. smartphones and tablet devices), a unique opportunity exists for teaching organic chemistry, via active-learning methods, which increase the meaningfulness and retention of course material. In particular, the use of reaction prediction applications has the potential to encourage students to use problem-based, self-directed and collaborative learning methods. While reaction prediction programs have been developed for desktop computers, research in the field has stagnated, and there are no predictors available for mobile platforms.5 Aims: to develop a reaction predictor app with mobile and desktop support. The app will let students sketch any chemical structure, then add single or multiple reagents to the structure, to predict the reaction product(s). The purpose of the app is to increase student understanding and retention of FGI’s without using rote-learning techniques. We’re also interested to see if students use the app as a game, i.e. for enjoyment, particularly when challenging other students in the ‘head-to-head’ mode. Design and methods: we will code the predictor using JavaScript. Rules for FGI’s will be defined using SMIRKS notation (a derivative of SMILES used for reaction transforms). All reagents in a specified reaction will be compared against the rule database, and the likely products displayed to the user as images. Feedback analytics tools will let the app automatically sample data from all users: our focus will be on app usage duration and frequency. Touch/click and multiplayer analytics will be provided using heat maps, and real-time activity streaming. In-app feedback screens will collect student self-evaluation, and enjoyment/satisfaction trends. Traditional surveying methods will be used to collect data that the app gathered insufficiently. Finally, student results (within application problem sets, and within subject assessments) will be compared with student self-reported data, and their duration and frequency of application use. Anticipated results: the reaction predictor will be built as a hybrid web-app, working on iOS, Android and Internet-connected desktops. Users can input structures (to be used as reagents or target molecules) by sketching them, or by taking photos of structures using their device’s inbuilt camera. Problem sets will be included, wherein users are required to virtually synthesise a target molecule, from a starting material, in a specified number of steps. A multi-user mode will allow students to collaborate in building target molecules, or to compete for the same purpose (by time, or by number-of-steps). We will be using a large first year and smaller second-year cohort organic chemistry subject at UOW as the sample frame, and beta testing. All students should report improved understanding of FGI’s within each problem set, and overall in the subject, which should be reflected in the assessment of learning outcomes. Anticipated conclusion: a reaction prediction application was successfully developed for multiple platforms, and improved understanding of FGI’s, making it ready for wider testing and distribution among undergraduate students and other institutions

Femtosecond Laser-Induced Crystallization of Amorphous Silicon Thin Films under a Thin Molybdenum Layer

A new process to crystallize amorphous silicon without melting and the generation of excessive heating of nearby components is presented. We propose the addition of a molybdenum layer to improve the quality of the laser-induced crystallization over that achieved by direct irradiation of silicon alone. The advantages are that it allows the control of crystallite size by varying the applied fluence of a near-infrared femtosecond laser. It offers two fluence regimes for nanocrystallization and polycrystallization with small and large crystallite sizes, respectively. The high repetition rate of the compact femtosecond laser source enables high-quality crystallization over large areas. In this proposed method, a multilayer structure is irradiated with a single femtosecond laser pulse. The multilayer structure includes a substrate, a target amorphous Si layer coated with an additional molybdenum thin film. The Si layer is crystallized by irradiating the Mo layer at different fluence regimes. The transfer of energy from the irradiated Mo layer to the Si film causes the crystallization of amorphous Si at low temperatures (∼700 K). Numerical simulations were carried out to estimate the electron and lattice temperatures for different fluence regimes using a two-temperature model. The roles of direct phonon transport and inelastic electron scattering at the Mo-Si interface were considered in the transfer of energy from the Mo to the Si film. The simulations confirm the experimental evidence that amorphous Si was crystallized in an all-solid-state process at temperatures lower than the melting point of Si, which is consistent with the results from transmission electron microscopy (TEM) and Raman. The formation of crystallized Si with controlled crystallite size after laser treatment can lead to longer mean free paths for carriers and increased electrical conductivity