Synthesis of New Pyrazoline - Phenoxathiin Derivatives

Phenoxathiin was prepared by the reaction of diphenyl ether with sulfur in the presence of anhydrous aluminum chloride. This work comprised the synthesis of new phenoxathiin derivatives containing heterocyclic moieties. These heterocyclic compounds were synthesized in three groups. The first group was made up of 2-(oxoalken-1-yl) phenoxathiin derivatives (3a-3j) obtained from the reaction of 2-acetylphenoxathiin with different aromatic aldehyde in the presence of sodium hydroxide. The other two groups involved compounds produced from the reaction of (3a-3j) with hydrazine hydrate in acetic acid to get 2-(1-acetyl pyrazolin-3-yl) phenoxathiin derivatives (4a-4j), and phenyl hydrazine in the presence of piperidine to afford 2-(1-phenyl pyrazolin-3-yl) phenoxathiin derivatives (5a-5j). All these compounds of two groups above were substituted in position (5) in pyrazoline ring with different aryl groups according to aromatic aldehyde used in the preparation of the first group series compounds

On the performance of non-orthogonal multiple access (NOMA) using FPGA

In this paper,  non-orthogonal multiple access (NOMA) is designed and implemented for the fifth generation (5G) of multi-user wireless communication.  Field-programmable gate array (FPGA) is considered for the implementation of this technique for two users. NOMA is applied in downlink phase of the base-station (BS) by applying power allocation mechanism for far and near users, in which one signal contains the superposition of two scaled signals depending on the distance of each user from the BS.  We assume an additive white Gaussian noise (AWGN) channel for each user in the presence of the interference due to the non-orthogonality between the two users’ signals. Therefore, successive-interference cancellation (SIC) is exploited to remove the undesired signal of the other user. The outage probability and the bit-error rate performance are presented over different signal-to-interference-plus-noise ratio (SINR). Furthermore, Monte-Carlo simulations via Matlab are utilized to verify the results obtained by FPGA, which show exact-close match

A Comparative Study on Developing the Hybrid-Electric Vehicle ‎Systems and its Future Expectation over the Conventional Engines Cars

The use of hybrid electric vehicles (HEVs) as an alternative to traditional petroleum-powered cars has risen due to climate change, air pollution, and fuel depletion. The transportation sector is the second largest energy-consuming sector that accounts for 30% of the world’s total delivered energy and about 60% of world oil demand. In 2008, the transportation sector accounted for about 22% of total world CO2 emissions. Within this sector, road vehicles dominate oil consumption and represent 81% of total transportation energy demand. This review discusses opportunities to reduce energy consumed and greenhouse gases in this sector and briefly discusses the Hybrid electric vehicles as a solution to improve fuel economy and reduce emissions. Also, the Classification of Hybrid Electric Vehicles, and the General architectures of hybrid electric vehicles and their subtypes have been discussed. Hybrid electric vehicle system components, system analysis, and fuel economy benefits are also explained. As the comparison results proved that the benefits of improved engine thermal efficiency outweigh the losses caused by longer energy transmission paths and showed that hybridization can improve fuel economy by about 24% in typical urban cycles. This study offers a thorough analysis of hybrid electric vehicles, including information on the designs, and energy management systems, created by different researchers. According to the thorough analysis, the current systems can execute HEVs rather effectively, but their dependability and autonomous systems remain not satisfactory. Several variables, difficulties, and issues related to the future generation of hybrid cars have been highlighted in this research

Effect of Battery Charging Rates for Electric Hybrid Vehicle on Fuel consumption and emissions behaviors in different road conditions: a comparative Study with Conventional Car

The transportation sector is a major source of worldwide carbon emissions and represents a significant contributor to air quality issues, particularly in metropolitan areas. To address the enormous carburization issues, the transportation sector must embrace low-emission vehicle technology. The team is presently developing a passenger electric hybrid car with the goal of reducing the environmental pollution. Hybrid electric vehicles (HEVs), which have a record of success in lowering hydrocarbon usage, stand as an intermediary technique between fully electric cars and internal combustion engines. In the present work, the conventional gasoline car has been tested on road at different trips condition. The gasoline fuel consumption as well as the SI engine emissions have been tested. A complete Hybrid electric system has been impeded instead of conventional driving gasoline engines and tested at a different charging rate of the battery. A comparison between the tested systems shows increased fuel efficiency as a key advantage of using HEVs technology. However, there are still unresolved issues about the system\u27s energy reliability. HEVs emit up to 21.0, 5.8, 9.0-, and 23.3-times lower NOx, UHC, CO, and particle number emissions than comparable gasoline vehicles. The development of after-treatment systems, enhanced engine management methods and the use of renewable fuels are emerging as research strategic prioritie

About fuzzy fixed point theorem in the generalized fuzzy fractal space.

The Banach fixed point theorem has applications in several branches of science. Many authors prove this theorem in different types of fuzzy metric spaces and fuzzy fractal spaces. The aim of this paper is to prove the Banach fixed point theorem in a new generalized space called multi fuzzy fractal space

Efficiency analysis for public key systems based on fractal functions.

In the last decade, dynamical systems were utilized to develop cryptosystems, which ushered the era of continuous value cryptography that transformed the practical region from finite field to real numbers. Approach: Taking the security threats and privacy issues into consideration, fractals functions were incorporated into public-key cryptosystem due to their complicated mathematical structure and deterministic nature that meet the cryptographic requirements. In this study we propose a new public key cryptosystem based on Iterated Function Systems (IFS). Results: In the proposed protocol, the attractor of the IFS is used to obtain public key from private one, which is then used with the attractor again to encrypt and decrypt the messages. By exchanging the generated public keys using one of the well known key exchange protocols, both parties can calculate a unique shared key. This is used as a number of iteration to generate the fractal attractor and mask the Hutchinson operator, so that, the known attacks will not work anymore. The algorithm is implemented and compared to the classical one, to verify its efficiency and security. We conclude that public key systems based on IFS transformation perform more efficiently than RSA cryptosystems in terms of key size and key space

IFS on the multi-fuzzy fractal space.

The IFS is a scheme for describing and manipulating complex fractal attractors using simple mathematical models. More precisely, the most popular “fractal –based” algorithms for both representation and compression of computer images have involved some implementation of the method of Iterated Function Systems (IFS) on complete metric spaces. In this paper a new generalized space called Multi-Fuzzy Fractal Space was constructed. On these spases a distance function is defined, and its completeness is proved. The completeness property of this space ensures the existence of a fixed-point theorem for the family of continuous mappings. This theorem is the fundamental result on which the IFS methods are based and the fractals are built. The defined mappings are proved to satisfy some generalizations of the contraction condition

Antecedents of psychological capital: The role of work design

Aim/purpose – Though psychological capital has become a hot topic in the recent years, scholars have given little attention to its antecedents. This study used the job characteristics model (Hackman & Oldham, 1975) as a framework to examine the relationship between the five job characteristics and the four components of psychological capital. Moreover, task performance is examined as an outcome of psychological capital. Design/methodology/approach – Using structural equation modelling, data were ob-tained from Egyptian professionals (N = 251). The survey included measures of psychological capital and job characteristics as well as task performance, which was rated by employees’ supervisors. Findings – Results indicate that the five job characteristics of skill variety, task significance, job feedback, job identity and job autonomy are positively related to the four components of psychological capital. Moreover, hope, self-efficacy and resilience were positively related to task performance. However, Egyptian employees’ optimism was not found to be related to task performance. Research implications/limitations – Results contribute to a better understanding of what enhances psychological capital in the workplace. Originality/value/contribution – The current study is the first to integrate the theory of work design with the psychological capacities of hope, optimism, resilience and self-efficacy. Research on the development of psychological capital has been limited to interventions with little or no attention given to macro or organisational factors that could contribute to its enhancement. Moreover, it is the first to link psychological capital to job performance in an Arab country

Segmentation of Brain Magnetic Resonance Images (MRIs): A Review

Abstract MR imaging modality has assumed an important position in studying the characteristics of soft tissues. Generally, images acquired by using this modality are found to be affected by noise, partial volume effect (PVE) and intensity nonuniformity (INU). The presence of these factors degrades the quality of the image. As a result of which, it becomes hard to precisely distinguish between different neighboring regions constituting an image. To address this problem, various methods have been proposed. To study the nature of various proposed state-of-the-art medical image segmentation methods, a review was carried out. This paper presents a brief summary of this review and attempts to analyze the strength and weaknesses of the proposed methods. The review concludes that unfortunately, none of the proposed methods has been able to independently address the problem of precise segmentation in its entirety. The paper strongly favors the use of some module for restoring pixel intensity value along with a segmentation method to produce efficient results

Metal Complexes of Macrocyclic Schiff-Base Ligand: Preparation, Characterisation, and Biological Activity

A new macrocyclic multidentate Schiff-base ligand Na4L consisting of two submacrocyclic units (10,21-bis-iminomethyl-3,6,14,17-tricyclo[17.3.1.18,12]tetracosa-1(23),2,6,8,10,12(24),13,17,19,21,-decaene-23,24-disodium) and its tetranuclear metal complexes with Mn(II), Co(II), Ni(II), Cu(II), and Zn(II) are reported. Na4L was prepared via a template approach, which is based on the condensation reaction of sodium 2,4,6-triformyl phenolate with ethylenediamine in mole ratios of 2 : 3. The tetranuclear macrocyclic-based complexes were prepared from the reaction of the corresponding metal chloride with the ligand. The mode of bonding and overall geometry of the compounds were determined through physicochemical and spectroscopic methods. These studies revealed tetrahedral geometries about Mn, Co, and Zn atoms. However, square planar geometries have been suggested for NiII and CuII complexes. Biological activity of the ligand and its metal complexes against Gram positive bacterial strain Staphylococcus aureus and Gram negative bacteria Escherichia coli revealed that the metal complexes become more potentially resistive to the microbial activities as compared to the free ligand. However, these metal complexes do not exhibit any effects on the activity of Pseudomonas aeruginosa bacteria. There is therefore no inhibition zone