282 research outputs found
Fabrication of a new type of organic-inorganic hybrid superlattice films combined with titanium oxide and polydiacetylene
We fabricated a new organic-inorganic hybrid superlattice film using molecular layer deposition [MLD] combined with atomic layer deposition [ALD]. In the molecular layer deposition process, polydiacetylene [PDA] layers were grown by repeated sequential adsorption of titanium tetrachloride and 2,4-hexadiyne-1,6-diol with ultraviolet polymerization under a substrate temperature of 100°C. Titanium oxide [TiO2] inorganic layers were deposited at the same temperatures with alternating surface-saturating reactions of titanium tetrachloride and water. Ellipsometry analysis showed a self-limiting surface reaction process and linear growth of the nanohybrid films. The transmission electron microscopy analysis of the titanium oxide cross-linked polydiacetylene [TiOPDA]-TiO2 thin films confirmed the MLD growth rate and showed that the films are amorphous superlattices. Composition and polymerization of the films were confirmed by infrared spectroscopy. The TiOPDA-TiO2 nanohybrid superlattice films exhibited good thermal and mechanical stabilities
Temperature-Dependent Electron-Electron Interaction in Graphene on SrTiO3
The electron band structure of graphene on SrTiO3 substrate has been
investigated as a function of temperature. The high-resolution angle-resolved
photoemission study reveals that the spectral width at Fermi energy and the
Fermi velocity of graphene on SrTiO3 are comparable to those of graphene on a
BN substrate. Near the charge neutrality, the energy-momentum dispersion of
graphene exhibits a strong deviation from the well-known linearity, which is
magnified as temperature decreases. Such modification resembles the
characteristics of enhanced electron-electron interaction. Our results not only
suggest that SrTiO3 can be a plausible candidate as a substrate material for
applications in graphene-based electronics, but also provide a possible route
towards the realization of a new type of strongly correlated electron phases in
the prototypical two-dimensional system via the manipulation of temperature and
a proper choice of dielectric substrates.Comment: 16 pages, 3 figure
Gapped Nearly Free-Standing Graphene on an SiC(0001) Substrate Induced by Manganese Atoms
The electron band structure of manganese-adsorbed graphene on an SiC(0001)
substrate has been studied using angle-resolved photoemission spectroscopy.
Upon introducing manganese atoms, the conduction band of graphene completely
disappears and the valence band maximum is observed at 0.4 eV below Fermi
energy. At the same time, the slope of the valence band decreases, approaching
the electron band structure calculated using the local density approximation
method. While the former provides experimental evidence of the formation of
nearly free-standing graphene on an SiC substrate, concomitant with a
metal-to-insulator transition, the latter suggests that its electronic
correlations can be modified by foreign atoms. These results pave the way for
promising device applications using graphene that is semiconducting and charge
neutral.Comment: 16 pages, 3 figure
Visualization of multifractal superconductivity in a two-dimensional transition metal dichalcogenide in the weak-disorder regime
Eigenstate multifractality is a distinctive feature of non-interacting
disordered metals close to a metal-insulator transition, whose properties are
expected to extend to superconductivity. While multifractality in three
dimensions (3D) only develops near the critical point for specific
strong-disorder strengths, multifractality in 2D systems is expected to be
observable even for weak disorder. Here we provide evidence for multifractal
features in the superconducting state of an intrinsic weakly disordered
single-layer NbSe by means of low-temperature scanning tunneling
microscopy/spectroscopy. The superconducting gap, characterized by its width,
depth and coherence peaks' amplitude, shows a characteristic spatial modulation
coincident with the periodicity of the quasiparticle interference pattern.
Spatial inhomogeneity of the superconducting gap width, proportional to the
local order parameter in the weak-disorder regime, follows a log-normal
statistical distribution as well as a power-law decay of the two-point
correlation function, in agreement with our theoretical model. Furthermore, the
experimental singularity spectrum f() shows anomalous scaling behavior
typical from 2D weakly disordered systems
Metallic surface states in a correlated d-electron topological Kondo insulator candidate FeSb2
The resistance of a conventional insulator diverges as temperature approaches
zero. The peculiar low temperature resistivity saturation in the 4f Kondo
insulator (KI) SmB6 has spurred proposals of a correlation-driven topological
Kondo insulator (TKI) with exotic ground states. However, the scarcity of model
TKI material families leaves difficulties in disentangling key ingredients from
irrelevant details. Here we use angle-resolved photoemission spectroscopy
(ARPES) to study FeSb2, a correlated d-electron KI candidate that also exhibits
a low temperature resistivity saturation. On the (010) surface, we find a rich
assemblage of metallic states with two-dimensional dispersion. Measurements of
the bulk band structure reveal band renormalization, a large
temperature-dependent band shift, and flat spectral features along certain high
symmetry directions, providing spectroscopic evidence for strong correlations.
Our observations suggest that exotic insulating states resembling those in SmB6
and YbB12 may also exist in systems with d instead of f electrons
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