1,873 research outputs found
Electrical Conductance of Molecular Wires
Molecular wires (MW) are the fundamental building blocks for molecular
electronic devices. They consist of a molecular unit connected to two continuum
reservoirs of electrons (usually metallic leads). We rely on Landauer theory as
the basis for studying the conductance properties of MW systems. This relates
the lead to lead current to the transmission probability for an electron to
scatter through the molecule. Two different methods have been developed for the
study of this scattering. One is based on a solution of the Lippmann-Schwinger
equation and the other solves for the {\bf t} matrix using Schroedinger's
equation. We use our methodology to study two problems of current interest. The
first MW system consists of 1,4 benzene-dithiolate (BDT) bonded to two gold
nanocontacts. Our calculations show that the conductance is sensitive to the
chemical bonding between the molecule and the leads. The second system we study
highlights the interesting phenomenon of antiresonances in MW. We derive an
analytic formula predicting at what energies antiresonances should occur in the
transmission spectra of MW. A numerical calculation for a MW consisting of
filter molecules attached to an active molecule shows the existence of an
antiresonance at the energy predicted by our formula.Comment: 14 pages, 5 figure
Brief clinical report: prune belly syndrome in an anencephalic male
We describe a postmature anencephalic infant with atrophy of the abdominal musculature (prune belly syndrome). Other associations of these conditions are noted
Effects of Friedreich's ataxia (GAA)(n)·(TTC)(n) repeats on RNA synthesis and stability
Expansions of (GAA)(n) repeats within the first intron of the frataxin gene reduce its expression, resulting in a hereditary neurodegenerative disorder, Friedreich's ataxia. While it is generally believed that expanded (GAA)(n) repeats block transcription elongation, fine mechanisms responsible for gene repression are not fully understood. To follow the effects of (GAA)(n)·(TTC)(n) repeats on gene expression, we have chosen E. coli as a convenient model system. (GAA)(n)·(TTC)(n) repeats were cloned into bacterial plasmids in both orientations relative to a promoter, and their effects on transcription and RNA stability were evaluated both in vitro and in vivo. Expanded (GAA)(n) repeats in the sense strand for transcription caused a significant decrease in the mRNA levels in vitro and in vivo. This decrease was likely due to the tardiness of the RNA polymerase within expanded (GAA)(n) runs but was not accompanied by the enzyme's dissociation and premature transcription termination. Unexpectedly, positioning of normal- and carrier-size (TTC)(n) repeats into the sense strand for transcription led to the appearance of RNA transcripts that were truncated within those repetitive runs in vivo. We have determined that these RNA truncations are consistent with cleavage of the full-sized mRNAs at (UUC)(n) runs by the E. coli degradosome
Synthesis and Isolation of {110}-Faceted Gold Bipyramids and Rhombic Dodecahedra
Two {110}-faceted gold nanostructuresârhombic dodecahedra and obtuse triangular bipyramidsâhave been synthesized via a Ag-assisted, seed-mediated growth method. The combination of a Clâ-containing surfactant with a low concentration of Ag+ plays a role in the stabilization of the {110} facets. To the best of our knowledge, this is the first reported synthesis of a {110}-faceted bipyramid structure
Synthesis and Isolation of {110}-Faceted Gold Bipyramids and Rhombic Dodecahedra
Two {110}-faceted gold nanostructuresârhombic dodecahedra and obtuse triangular bipyramidsâhave been synthesized via a Ag-assisted, seed-mediated growth method. The combination of a Clâ-containing surfactant with a low concentration of Ag+ plays a role in the stabilization of the {110} facets. To the best of our knowledge, this is the first reported synthesis of a {110}-faceted bipyramid structure
Analysis of Collectivism and Egoism Phenomena within the Context of Social Welfare
Comparative benefits provided by the basic social strategies including
collectivism and egoism are investigated within the framework of democratic
decision-making. In particular, we study the mechanism of growing "snowball" of
cooperation.Comment: 12 pages, 5 figures. Translated from Russian. Original Russian Text
published in Problemy Upravleniya, 2008, No. 4, pp. 30-3
A Directional Entropic Force Approach to Assemble Anisotropic Nanoparticles into Superlattices
Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/102143/1/14230_ftp.pdfhttp://deepblue.lib.umich.edu/bitstream/2027.42/102143/2/ange_201306009_sm_miscellaneous_information.pd
Towards a Tetravalent Chemistry of Colloids
We propose coating spherical particles or droplets with anisotropic
nano-sized objects to allow micron-scale colloids to link or functionalize with
a four-fold valence, similar to the sp3 hybridized chemical bonds associated
with, e.g., carbon, silicon and germanium. Candidates for such coatings include
triblock copolymers, gemini lipids, metallic or semiconducting nanorods and
conventional liquid crystal compounds. We estimate the size of the relevant
nematic Frank constants, discuss how to obtain other valences and analyze the
thermal distortions of ground state configurations of defects on the sphere.Comment: Replaced to improve figures. 4 figures Nano Letter
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