Performance Prediction of Microwave Absorbers Based on POMA/Carbon Black Composites in the Frequency Range of 8.2 to 20 GHz

<div><p>ABSTRACT: This paper presents a comparative study involving experimental and numerical behaviors of radar absorbing materials (RAM), based on conducting composites of poly(o-methoxyaniline) (POMA) and carbon black (CB). Samples of POMA/CB in epoxy resin matrix were prepared. First, these samples were experimentally characterized by electric permittivity and magnetic permeability measurements in the frequency range of 8.2 to 12.4 GHz. Afterwards, a linear extrapolation of these electromagnetic parameters until 20 GHz was carried out. These amounts were used as parameters for a set of simulations, developed from numerical implementation of theoretical predictions. The main advantage of the performed simulations is to know the behavior of the POMA/CB/epoxy resin as RAM in a wide range of frequencies (8.2-20 GHz), previously to the experimental work. The validation of the simulations with experimental reflection loss measurements showed a good fit and allowed predicting the material behavior as RAM. The results show that the studied RAM presents good return loss values in different frequencies, for example, -32 dB (~99.95% of absorption) at 14.6 GHz and -18 dB at 19.2 GHz, for samples with 7 and 9 mm-thickness values, respectively. The simulation tool used in this study was adequate to optimize the RAM production, contributing to the reduction of development costs and processing time of this kind of material.</p></div

Effect of the Morphology and Structure on the Microwave Absorbing Properties of Multiwalled Carbon Nanotube Filled Epoxy Resin Nanocomposites

<div><p>The current research shows the effect of structural and morphological differences of multilayer carbon nanotubes (CNT) on radar absorbing materials (RAM) performance. Two CNT samples, from different manufacturers, had their morphological and structural aspects investigated by XRD, SEM and SEM-FEG analyses. CNT/epoxy resin based nanostructured composites were prepared and characterized by reflectivity measurements in the X-band. SEM results show the formation of agglomerates in the composites and the XRD patterns show structural differences between the two CNT samples. The best RAM performance (-25 dB) was determined for the nanocomposite based on the CNT with the smallest stacking layers (Lc = 26.9 Å) associated to the longest length of nanofilament (10-20 µm). This characteristic can have contributed to the formation of an interconnected network in the composite favoring electrical conductivity and dielectric properties, with the consequent increase of the wave attenuation.</p></div

Influence of reaction time on the structure of polyaniline synthesized on a pre-pilot scale

<div><p>Abstract The aim of this work is to follow the structural variations of polyaniline (PAni) obtained by chemical oxidation on a pre-pilot scale, with different reaction times. Synthesis of PAni is well known, but when it is carried out on a pre-pilot scale, several factors can lead to structural changes and understanding these changes is important to improve controls on the synthesis process. The polymers formed were characterized by spectroscopic techniques (Raman spectroscopy, Fourier Transform Infrared - FTIR and UV-Visible). Degree of oxidation and yield were calculated for each reaction time. The analysis by FTIR, the calculated degree of oxidation and the yield showed significant changes in polymer structure at reaction times of 65 and 80 min. This result was attributed to the excessive oxidation of PAni, with the breaking of its polymer chain. The changes observed in the structure of PAni gave subsidies to the optimization of the process of obtaining polyaniline by chemical synthesis.</p></div

Effect of PANI on Thermal, Mechanical and Electromagnetic Properties of HDPE/LLDPE/PANI Composites

<div><p>In this work, polyaniline (PANI) in emeraldine-base form, synthesized by chemical oxidation polymerization, was protonated with hydrochloric acid (HCl). Composites based on high-density polyethylene (HDPE) and linear-low density polyethylene (LLDPE) blends with PANI were prepared in molten condition using a torque rheometer. The effect of compatibilizer agent (maleic anhydride-grafted high density polyethylene, HDPE-g-MA) and different contents of PANI on the blends-based composites was also investigated. Thermal, mechanical, and electromagnetic (electric permittivity) measurements and morphological aspects of the composites were evaluated. The addition of PANI content in the composites decreases the degree of crystallinity of HDPE and LLDPE blends, which implies that PANI particles make it difficult for co-crystallization to occur in the HDPE and LLDPE, respectively. On the other hand, the addition of compatibilizer agent in the HDPE and LLDPE blends increased the degree of crystallinity. The complex parameters of permittivity in the frequency range of 8.2 to 12.4 GHz varied as a function of the PANI content in the blend. It was also observed that the compatibilizer agent increased the composite stiffness and decreased the electric permittivity values. This result shows that the increasing rigidity of the molecular structure of the polyethylene matrix hindered the dissipation of the electromagnetic energy in the sample.</p></div