Cotton soot derived carbon nanoparticles for NiO supported processing temperature tuned ambient perovskite solar cells

The emergence of perovskite solar cells (PSCs) in a "catfish effect" of other conventional photovoltaic technologies with the massive growth of high-power conversion efficiency (PCE) has given a new direction to the entire solar energy field. Replacing traditional metal-based electrodes with carbon-based materials is one of the front-runners among many other investigations in this field due to its cost-effective processability and high stability. Carbon-based perovskite solar cells (c-PSCs) have shown great potential for the development of large scale photovoltaics. First of its kind, here we introduce a facile and cost-effective large scale carbon nanoparticles (CNPs) synthesis from mustard oil assisted cotton combustion for utilization in the mesoporous carbon-based perovskite solar cell (PSC). Also, we instigate two different directions of utilizing the carbon nanoparticles for a composite high temperature processed electrode (HTCN) and a low temperature processed electrode (LTCN) with detailed performance comparison. NiO/CNP composite thin film was used in high temperature processed electrodes, and for low temperature processed electrodes, separate NiO and CNP layers were deposited. The HTCN devices with the cell structure FTO/c-TiO2/m-TiO2/m-ZrO2/high-temperature NiO-CNP composite paste/infiltrated MAPI (CH3NH3PbI3) achieved a maximum PCE of 13.2%. In addition, high temperature based carbon devices had remarkable stability of ~ 1000 h (ambient condition), retaining almost 90% of their initial efficiency. In contrast, LTCN devices with configuration FTO/c-TiO2/m-TiO2/m-ZrO2/NiO/MAPI/low-temperature CNP had a PCE limit of 14.2%, maintaining ~ 72% of the initial PCE after 1000 h. Nevertheless, we believe this promising approach and the comparative study between the two different techniques would be highly suitable and adequate for the upcoming cutting-edge experimentations of PSC

Hopping frequency and conductivity relaxation of promising chalcogenides: AC conductivity and dielectric relaxation approaches

Ag _2 S doped chalcogenide glassy systems have been characterised on the basis of AC conductivity and electric modulus formalism. Various nanophases such as Ag _2 Se, Te _0.5 Se _3.5 etc. and dislocation (defects) have been identified and their roles in the conduction process have been established. XRD analysis provides that incorporation of more Ag _2 S content in the present system should play important role to enhance the dislocation and to decrease the crystallite sizes. The Fourier transform infrared spectra (FT-IR) confirm the characteristic vibration of Ag–S at 500–650 cm ^−1 , stretching vibrations of the O–H bond near 3400 cm ^−1 and bending vibrations of the adsorbed H _2 O molecules on the surface of Ag _2 S near 1600 cm ^−1 . Composition dependent optical phonon frequency (ν _0 ) and Debye temperature ( θ _D ) have been estimated from FT-IR and it is noteworthy that θ _D increases with Ag _2 S content in the compositions up to x = 0.1, but decreases for x = 0.2. This result suggests higher kinetic energy of the constituent atoms/molecules, which may refer to higher electrical conductivity due to polaron hopping. Correlated barrier hopping (CBH) model in its modified version has been found most suitable model to explore the conduction mechanism. Short time relaxation process may be considered to be trivially associated with conduction of polaron. universal scaling approach proposed by Ghosh and Pan has been adopted to interpret electrical relaxation process from time-temperature superposition principle. AC conductivity spectra at various temperatures exhibit a perfect overlap into a single master curve. This feature must be an indication of the temperature independent relaxation process. On the other hand, conductivity spectra of all the compositions at a particular temperature do not exhibit perfect overlapping into a single master curve. This result indicates that the relaxation dynamics of charge carriers (polarons) is strongly dependent on compositions

Cotton soot derived carbon nanoparticles for NiO supported processing temperature tuned ambient perovskite solar cells

The emergence of perovskite solar cells (PSCs) in a "catfish effect" of other conventional photovoltaic technologies with the massive growth of high-power conversion efficiency (PCE) has given a new direction to the entire solar energy field. Replacing traditional metal-based electrodes with carbon-based materials is one of the front-runners among many other investigations in this field due to its cost-effective processability and high stability. Carbon-based perovskite solar cells (c-PSCs) have shown great potential for the development of large scale photovoltaics. First of its kind, here we introduce a facile and cost-effective large scale carbon nanoparticles (CNPs) synthesis from mustard oil assisted cotton combustion for utilization in the mesoporous carbon-based perovskite solar cell (PSC). Also, we instigate two different directions of utilizing the carbon nanoparticles for a composite high temperature processed electrode (HTCN) and a low temperature processed electrode (LTCN) with detailed performance comparison. NiO/CNP composite thin film was used in high temperature processed electrodes, and for low temperature processed electrodes, separate NiO and CNP layers were deposited. The HTCN devices with the cell structure FTO/c-TiO2/m-TiO2/m-ZrO2/high-temperature NiO-CNP composite paste/infiltrated MAPI (CH3NH3PbI3) achieved a maximum PCE of 13.2%. In addition, high temperature based carbon devices had remarkable stability of ~ 1000 h (ambient condition), retaining almost 90% of their initial efficiency. In contrast, LTCN devices with configuration FTO/c-TiO2/m-TiO2/m-ZrO2/NiO/MAPI/low-temperature CNP had a PCE limit of 14.2%, maintaining ~ 72% of the initial PCE after 1000 h. Nevertheless, we believe this promising approach and the comparative study between the two different techniques would be highly suitable and adequate for the upcoming cutting-edge experimentations of PSC

Transdermal Therapeutic System: Study of Cellulose Nanocrystals Influenced Methylcellulose-Chitosan Bionanocomposites

Over the past few years, there is a drive toward the fabrication and application of bio-based non-cytotoxic drug carriers. Cellulose nanocrystals (CNCs) have gotten immense research attention as a promising bioderived material in the biomedical field due to its remarkable properties. The delivery of analgesic and anti-inflammatory drug, ketorolac tromethamine (KT) by transdermal route is stipulated herewith to fabricate suitable transdermal therapeutic systems. We have synthesized CNCs from jute fibers and aim to develop a non-cytotoxic polymer-based bionanocomposites (BNCs) transdermal patch, formulated with methylcellulose (MC), chitosan (CH), along with exploration of CNCs for sustained delivery of KT, where CNCs act as nanofiller and elegant nanocarrier. CNCs reinforced MCCH blends were prepared via the solvent evaporation technique. The chemical structure, morphology, and thermal stability of the prepared bionanocomposites formulations were studied by Fourier transform infrared (FTIR) spectroscopy, X-ray diffraction (XRD), TGA, DSC, DMA, and SEM. The In vitro drug release studies were executed using Franz diffusion cells. The BNC patches showed in-vitro cytocompatibility and the drug release study revealed that BNC containing 1 wt% CNCs presented the best-sustained drug release profile. The bioderived CNCs appear to enhance the BNCs drug\u27s bioavailability, which could have a broad prospect for TDD applications