In-Situ Colloidal MnO2 Deposition and Ozonation of 2,4-Dinitrotoluene

Laboratory experiments are presented that demonstrate a novel in situ semipassive reactive barrier for the degradation of 2,4 dinitrotoluene created by coating aquifer surfaces by deposition of colloidal MnO2, which catalyzes ozone degradation and enhances contaminant oxidation. Ozone is added to the reactive barrier and is transported through the zone with the contaminants by existing hydraulic gradients. The communication presents the preliminary laboratory investigation demonstrating the viability of this method. Studies were conducted by coating Ottawa sand with colloidal MnO2. Results show that concentrations of MnO2 in the range of 0.2 mg/g can be deposited with no measurable change in hydraulic conductivity, that there is significant coverage of the sand material by MnO2, and the deposition was not reversible under a wide range of chemical conditions. Ozonation of 2,4-dinitrotoluene in the presence of MnO2- coated sand was demonstrated to result in pseudo-first-order degradation kinetics with respect to DNT with half-lives ranging from 28 to 22 min (at pH 6 and 7, respectively), approximately 25% faster than experiments performed in the absence of MnO2

Seismic Performance Testing of Partially and Fully Anchored Wood-Frame Shear Walls

Earthquake performance of wood-frame shear walls was evaluated by comparing fully and partially anchored walls under monotonic, cyclic, and earthquake loads and comparing with code measures. Suitability of monotonic and cyclic testing to predict seismic performance was examined. Earthquake tests were conducted on 2440-mm-square walls with Douglas-fir studs. Two oriented strandboard panels were fastened to the frame with two gypsum wallboard panels on the opposite side. Partially anchored walls had two anchor bolts on the sill plate. Fully anchored walls had hold-downs at the ends. Four time histories were tested: three subduction zone ground motions and a strike-slip fault, all scaled to the Seattle design level. For fully anchored walls, subduction zone tests had capacities, energy dissipation, and failure modes most similar to cyclic tests. Wall displacement at maximum load was under-estimated by cyclic and overestimated by monotonic tests. For partially anchored walls, subduction zone and strike-slip earthquake tests had capacity, displacement at maximum load, initial stiffness, and ductility most similar to cyclic tests. Energy dissipation was most similar to monotonic tests, and failure modes were consistent with monotonic and cyclic tests. Partially anchored walls had lower capacity, displacement at maximum load, energy dissipation, and stiffness as compared with fully anchored walls

Cryogenic Refractive Indices of S-LAH55, S-LAH55V, S-LAH59, S-LAM3, S-NBM51, S-NPH2, S-PHM52, and S-TIH14 Glasses

The Transiting Exoplanet Survey Satellite (TESS) is an explorer-class planet finder, whose principal goal is to detect small planets with bright host starts in the solar neighborhood. The TESS payload consists of four identical cameras with seven optical elements each that include various types of Ohara glass substrates. The successful implementation both panchromatic and thermal lens assembly designs for these cameras requires a fairly accurate (up to 1E-6) knowledge of the temperature and wavelength dependence of the refractive index in the wavelength and temperature range of operation. Hence, this paper is devoted to report on measurements of the refractive index over the wavelength range of 0.42-1.15 um and temperature range of 110-310 K for the following Ohara glasses: S-LAH55, S-LAH55V, SLAH59, S-LAM3, S-NBM51, S-NPH2, S-PHM52, and S-TIH14. The measurements were performed utilizing the Cryogenic High Accuracy Refraction Measuring System (CHARMS) facility at NASA's Goddard Space Flight Center. A dense coverage of the absolute refractive index for the title substrates in the aforementioned wavelength and temperature ranges was used to determine the thermo-optic coefficient (dn/dT) and dispersion relation (dn/d lambda) as a function of wavelength and temperature. A comparison of the measured indices with literature values, specifically the temperature-dependent refractive indices of S-PHM52 and S-TIH14, will be presented

Correlated X-ray and Optical Variability in Mkn 509

We present results of a 3 year monitoring campaign of the Seyfert 1 galaxy Markarian 509, using X-ray data from the Rossi X-ray Timing Explorer (RXTE) and optical data taken by the SMARTS consortium. Both light curves show significant variations, and are strongly correlated with the optical flux leading the X-ray flux by 15 days. The X-ray power spectrum shows a steep high-frequency slope of -2.0, breaking to a slope of -1.0 at at timescale of 34 days. The lag from optical to X-ray emission is most likely caused by variations in the accretion disk propagating inward.Comment: 13 pages, 3 figures. Accepted for publication in the Astrophysical Journa

From Bonaventure to Goddard: How I Got to NASA and What I Am Doing There

The presentation, accompanied by slides when appropriate, will describe how a young physics major travelled from the classrooms of Saint Bonaventure, to the graduate research laboratories of the University of Florida in Gainesville, and finally to the government laboratories of NASA at the Goddard Space Flight Center just north of Washington, D.C. The main portion of the presentation concerns NASA missions of interest to the general public and supported in part by research work he does. Such, for example, is the current flagship mission of NASA, the James Webb Space Telescope that is destined to replace very soon the Hubble Space Telescope. In addition to these NASA telescope missions, a mission to an asteroid, coined the OSIRIS REX program, is in process and will be described

NASA's Work in Exoplanet Hunting Satellites and Robotic Servicing of Satellites

An overview of three missions connected with NASA's Goddard Space Flight Center at the present time: (1) NASA's flagship mission, the James Webb Space Telescope, is nearing its 2021 launch date. The James Webb, which is considered the successor to the Hubble Space Telescope, will orbit at the Earth-Sun Lagrangian Point Two where it will peer back in time, using infrared detectors, to the beginnings of our Universe. (2) NASA is conducting pioneering work in the field of robotic satellite servicing in earth orbit. The RESTORE-L project, which is slated for a 2021 launch date, is expected to pave the way for the inception of robotic assembly for deep space exploration as well as the commercialization of satellite servicing. (3) The Transiting Exoplanet Survey Satellite (TESS) has been orbiting the Earth actively searching for new planets since April of 2018. The discoveries that TESS has made to-date have benefited from a careful characterization of the refractive lens assemblies on its science instruments. The presentation will provide a detailed description of how the index of refraction of the glasses used to fabricate the TESS lens assemblies were measured at Goddard to an accuracy that enables the ability to make exoplanet discoveries hundreds of light years from Earth

Cryogenic Refractive Indices of S-LAH55, S-LAH55V, S-LAH59, S-LAM3, S-NBM51, S-NPH2, S-PHM52, and S-TIH14 Glasses

The Transiting Exoplanet Survey Satellite (TESS) is an explorer-class planet finder, whose principal goal is to detect small planets with bright host starts in the solar neighborhood. The TESS payload consists of four identical cameras and a Data Handling Unit (DHU) fitted with CCD detectors and associated electronics. Each camera consist of a lens assembly with seven optical elements that include various types of Ohara glass substrates. The successful implementation of a panchromatic and a thermal lens assembly design for these cameras requires a fairly accurate (up to 0.000001 (1e-6)) knowledge of the temperature- and wavelength-dependent of the refractive index in the wavelength and temperature range of operation. Hence, this paper is devoted to report on measurements of the refractive index over the wavelength range of 0.42-1.15 micrometers and temperature range of 110-300 K for the following Ohara glasses: S-LAH55, S-LAH55V, S-LAH59, S-LAM3, S-NBM51, S-NPH2, S-PHM52, and S-TIH14. The measurements were performed utilizing the Cryogenic High Accuracy Refraction Measuring System (CHARMS) facility at NASA's Goddard Space Flight Center. A dense coverage of the absolute refractive index for all these substrates in the aforementioned wavelength and temperature ranges was used to determine the thermo-optic coefficient (dndT) and dispersion relation (dnd) as a function of wavelength and temperature. A comparison of the measured indices with literature values, specifically the temperature-dependent refractive indices of S-PHM52 and S-TIH14 reported by Yamamuro et al. [Yamamuro et al., Opt. Eng. 45(8), 083401 (2006)], will be presented