Chemical Composition of Fine and Coarse Aerosol Particles in the Central Mediterranean Area during Dust and Non-Dust Conditions

A two-month field campaign was carried out from May to June 2010 at a remote site (Trisaia ENEA Research Centre) in the Southern Italy aiming to identify and quantify the changes of aerosol chemical composition in the presence of Saharan dust. The 24-hr PM_(10) and PM_(2.5) filter samples were analyzed by mass, carbonaceous species, inorganic ions and elemental composition. Saharan dust transport events were identified with two approaches: one recommended by EC (2011) and one based on indicators derived from measurements. Three indicators were used: PM_(2.5)/PM_(10) mass concentrations ratio, Ca/Al ratio and Al concentration. Based on these criteria, four Saharan dust transport events were identified, but only one had elevated dust concentration and leaded to an exceedance of the European short-term (24 hour) limit value of 50 μg/m^3 for PM_(10) (June 16^(th)). The comparison of chemical composition of fine and coarse aerosol fractions during dust and non-dust conditions shows that the presence of dust increases NH_4 and nssSO_4 concentrations in the fine fraction and NO_3 and nssSO_4 concentrations in the coarse fraction. OC and EC concentrations also increase in the fine fraction during dust transport. The uptake of primary and secondary species, inorganic and organic, by dust particles changes their composition and, thus, their properties and this may have implications for human health and climate change

comparison of online and offline methods for measuring fine secondary inorganic ions and carbonaceous aerosols in the central mediterranean area

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source apportionment and macro tracer integration of independent methods for quantification of woody biomass burning contribution to pm10

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Emission Factors of CO2 and Airborne Pollutants and Toxicological Potency of Biofuels for Airplane Transport: A Preliminary Assessment

Aviation is one of the sectors affecting climate change, and concerns have been raised over the increase in the number of flights all over the world. To reduce the climate impact, efforts have been dedicated to introducing biofuel blends as alternatives to fossil fuels. Here, we report environmentally relevant data on the emission factors of biofuel/fossil fuel blends (from 13 to 17% v/v). Moreover, in vitro direct exposure of human bronchial epithelial cells to the emissions was studied to determine their potential intrinsic hazard and to outline relevant lung doses. The results show that the tested biofuel blends do not reduce the emissions of particles and other chemical species compared to the fossil fuel. The blends do reduce the elemental carbon (less than 40%) and total volatile organic compounds (less than 30%) compared to fossil fuel emissions. The toxicological outcomes show an increase in oxidative cellular response after only 40 min of exposure, with biofuels causing a lower response compared to fossil fuels, and lung-deposited doses show differences among the fuels tested. The data reported provide evidence of the possibility to reduce the climate impact of the aviation sector and contribute to the risk assessment of biofuels for aviation

The Role of Vegetation on Urban Atmosphere of Three European Cities—Part 1: Evaluation of Vegetation Impact on Meteorological Conditions

This study quantifies the vegetation impact on urban meteorology by means of the numerical model WRF (Weather Research and Forecasting model). The assessment was made for two months: July and January. These were considered as representative for the summer and winter seasons, for the reference year 2015 in three European cities: Bologna, Milano, and Madrid. Two simulations at 1 km resolution were conducted over the cities with and without the actual urban vegetation, called VEG and NOVEG, respectively, in the model input. Then, the impact of vegetation was evaluated as the difference between the two simulations (VEG-NOVEG) for temperature, relative humidity, and wind speed fields. In general, we found that, as can be expected, urban vegetation tends to cool the atmosphere, enhance the humidity, and reduce the wind speed. However, in some cases, areas with the opposite behaviour exist, so that no a priori results can be attributed to the presence of urban vegetation. Moreover, even when major impact is confined around grid cells where urban vegetation is present, changes in meteorological quantities can be observed elsewhere in the city’s area. The magnitude of urban vegetation impact is higher in summer than in winter and it depends on the city’s morphological peculiarities, such as urban texture and vegetation types and distribution: average July temperature variations due to the presence of urban vegetation reach peaks of −0.8 °C in Milano, −0.6 °C Madrid, and −0.4 °C in Bologna, while in January, the values range between −0.3 and −0.1 °C. An average heating effect of ca. +0.2 °C is found in some parts of Madrid in January. For relative humidity, we found increments of 2%–3% in July and 0.5%–0.8% in January, while a decrease in wind speed was found between 0.1 and 0.5 m/s, with the highest occurring in Madrid during July