High-Precision U-Pb CA-TIMS Calibration of Middle Permian to Lower Triassic Sequences, Mass Extinction and Extreme Climate-Change in Eastern Australian Gondwana

Twenty-eight new high-precision Chemical Abrasion Isotope Dilution Thermal Ionisation Mass Spectrometry U-Pb zircon dates for tuffs in the Sydney and Bowen Basins are reported. Based on these new dates, the Guadalupian-Lopingian/Capitanian-Wuchiapingian boundary is tentatively placed at the level of the Thirroul Sandstone in the lower part of the Illawarra Coal Measures in the Sydney Basin. The Wuchiapingian-Changhsingian boundary is at or close to the Kembla Sandstone horizon in the Illawarra Coal Measures, southern Sydney Basin, in the middle part of the Newcastle Coal Measures in the northern Sydney Basin, and in the middle of the Black Alley Shale in the southern Bowen Basin. The end-Permian mass extinction is recognised at the base of the Coal Cliff Sandstone in the southern Sydney Basin, at the top of the Newcastle Coal Measures in the northern Sydney Basin, and close to the base of the Rewan Group in the Bowen Basin and is dated at c. 252.2 Ma. The end-Permian mass extinction is interpreted to be synchronous globally in both marine and terrestrial environments, and in high and low latitudes (resolution \u3c 0.5 my). The GSSP-defined Permian-Triassic boundary is interpreted to be approximately at the level of the Scarborough Sandstone in the lower Narrabeen Group, Sydney Basin, and in the lower Rewan Group, Bowen Basin. New dates presented here suggest that the P3 and P4 glacial episodes in the Permian of eastern Australia are early Roadian to early Capitanian, and late Capitanian to mid Wuchiapingian in age respectively. The greenhouse crisis in the uppermost Pebbly Beach and Rowan Formations of the Sydney Basin is interpreted as early mid Roadian, a mid-Capitanian age for the crisis at the base of the Illawarra/Whittingham Coal Measures is confirmed. Greenhouse crises in the upper Illawarra/Newcastle Coal Measures and lower Narrabeen Group of the Sydney Basin are dated as upper Changhsingian-Induan, and in the upper Narrabeen Group/lower Hawksbury Sandstone as upper Olenekian

A Quantitative Evaluation of the Galaxy Component of COSMOS and APM Catalogs

We have carried out an independent quantitative evaluation of the galaxy component of the "COSMOS/UKST Southern Sky Object Catalogue" (SSC) and the "APM/UKST J Catalogue" (APM). Using CCD observations our results corroborate the accuracy of the photometry of both catalogs, which have an overall dispersion of about 0.2 mag in the range 17 <= b_J <= 21.5. The SSC presents externally calibrated galaxy magnitudes that follow a linear relation, while the APM instrumental magnitudes of galaxies, only internally calibrated by the use of stellar profiles, require second-order corrections. The completeness of both catalogs in a general field falls rapidly fainter than b_J = 20.0, being slightly better for APM. The 90% completeness level of the SSC is reached between b_J = 19.5 and 20.0, while for APM this happens between b_J = 20.5 and 21.0. Both SSC and APM are found to be less complete in a galaxy cluster field. Galaxies misclassified as stars in the SSC receive an incorrect magnitude because the stellar ones take saturation into account besides using a different calibration curve. In both cases, the misclassified galaxies show a large diversity of colors that range from typical colors of early-types to those of blue star-forming galaxies. A possible explanation for this effect is that it results from the combination of low sampling resolutions with properties of the image classifier for objects with characteristic sizes close to the instrumental resolution. We find that the overall contamination by stars misclassified as galaxies is < 5% to b_J = 20.5, as originally estimated for both catalogs. Although our results come from small areas of the sky, they are extracted from two different plates and are based on the comparison with two independent datasets.Comment: 14 pages of text and tables, 8 figures; to be published in the Astronomical Journal; for a single postscript version file see ftp://danw.on.br/outgoing/caretta/caretta.p

Towards efficient use of noble metals : via exsolution exemplified for CO oxidation

Many catalysts and in particular automotive exhaust catalysts usually consist of noble metal nanoparticles dispersed on metal oxide supports. While highly active, such catalysts are expensive and prone to deactivation by sintering and thus alternative methods for their production are being sought to ensure more efficient use of noble metals. Exsolution has been shown to be an approach to produce confined nanoparticles, which in turn are more stable against agglomeration, and, at the same time strained, displaying enhanced activity. While exsolution has been extensively investigated for relatively high metal loadings, it has yet to be explored for dilute loadings which is expected to be more challenging but more suitable for application of noble metals. Here we explore the substitution of Rh into an A-site deficient perovskite titante aiming to investigate the possibility of exsolving from dilute amounts of noble metal substituted perovskites. We show that this is possible and in spite of certain limitations, they still compete well against conventionally prepared samples with higher apparent surface loading when applied for CO oxidation

Galaxy number counts- IV. surveying the Herschel deep field in the near-infrared

(abridged) We present results from two new near-infrared imaging surveys. One covers 47.2 arcmin^2 to K(3\sigma)<20 whilst a second, deeper survey covers a sub-area of 1.8 arcmin^2 to K(3\sigma)<22.75. Over the entire area we have extremely deep UBRI photometry. Our K- counts are consistent with the predictions of non-evolving models with 0 < q0 <0.5. The K-selected (B-K) galaxy colour distributions move sharply bluewards fainter than K~20 and at at brighter magnitudes (K<20) our observed colour distributions indicate a deficiency of red, early-type galaxies at z~1 in comparison with passively evolving models. This implies either a pure luminosity evolution (PLE) model with a low level of continuing star-formation following an an initial burst, or dynamical merging. At fainter magnitudes, the continuing bluewards trend observed in (B-K) can be explained purely in terms of passively evolving PLE models. Our observed numbers of (I-K)>4 galaxies at K<20 exhibit the same deficiency, suggesting that at least part of the larger deficit observed in (B-K) at K<20 may be due to star-formation rather than dynamical merging. Finally, as we and others have noted, the number-redshift distribution at 18<K<19 of recent, deep K- selected redshift surveys is well fitted by non-evolving models; passively evolving models with a Salpeter or Scalo initial mass functions overpredict the numbers of galaxies with z>1. Dynamical merging is one possible solution to reduce the numbers of these galaxies but a dwarf-dominated IMF for early-type galaxies could offer an alternative explanation; we show that this model reproduces both the optical-infrared colour distributions and the K- band galaxy counts.Comment: 15 pages, 9 figures, revised version, requires astrobib.sty, mn-abs.sty, submitted to MNRA

End stage renal disease and survival in people with diabetes:a national database linkage study

© The Author 2014. Published by Oxford University Press on behalf of the Association of Physicians. Funding This work was supported by the Wellcome Trust through the Scottish Health Informatics Programme (SHIP). The SHIP is collaboration between the Universities of Aberdeen, Dundee, Edinburgh, Glasgow and St Andrews and the Information Services Division of National Health Service National Service Scotland. Funding for diabetes register linkage and data extraction was provided by the Chief Scientist’s Office of the Scottish Government. The Scottish Diabetes Research Network receives financial support from National Health Services Research Scotland. The Scottish Renal Registry is funded by the Information Services Division of National Health Service National Services Scotland but relies heavily on the goodwill of the contributing renal units who spent a large amount time working with Scottish Renal Registry staff to ensure that the data held within the register are accurate and complete.Peer reviewedPublisher PD

Pre-avalanche instabilities in a granular pile

We investigate numerically the transition between static equilibrium and dynamic surface flow of a 2D cohesionless granular system driven by a continuous gravity loading. This transition is characterized by intermittent local dynamic rearrangements and can be described by an order parameter defined as the density of critical contacts, e.g. contacts where the friction is fully mobilized. Analysis of the spatial correlations of critical contacts shows the occurence of ``fluidized'' clusters which exhibit a power-law divergence in size at the approach of the stability limit. The results are compatible with recent models that describe the granular system during the static/dynamic transition as a multi-phase system.Comment: 9 pages, 6 figures, submitted to Phys. Rev. Let

Smooth-filamental transition of active tracer fields stirred by chaotic advection

The spatial distribution of interacting chemical fields is investigated in the non-diffusive limit. The evolution of fluid parcels is described by independent dynamical systems driven by chaotic advection. The distribution can be filamental or smooth depending on the relative strength of the dispersion due to chaotic advection and the stability of the chemical dynamics. We give the condition for the smooth-filamental transition and relate the H\"older exponent of the filamental structure to the Lyapunov exponents. Theoretical findings are illustrated by numerical experiments.Comment: 4 pages, 3 figure

Stellar ages and convective cores in field main-sequence stars: first asteroseismic application to two Kepler targets

Using asteroseismic data and stellar evolution models we make the first detection of a convective core in a Kepler field main-sequence star, putting a stringent constraint on the total size of the mixed zone and showing that extra mixing beyond the formal convective boundary exists. In a slightly less massive target the presence of a convective core cannot be conclusively discarded, and thus its remaining main-sequence life time is uncertain. Our results reveal that best-fit models found solely by matching individual frequencies of oscillations corrected for surface effects do not always properly reproduce frequency combinations. Moreover, slightly different criteria to define what the best-fit model is can lead to solutions with similar global properties but very different interior structures. We argue that the use of frequency ratios is a more reliable way to obtain accurate stellar parameters, and show that our analysis in field main-sequence stars can yield an overall precision of 1.5%, 4%, and 10% in radius, mass and age, respectively. We compare our results with those obtained from global oscillation properties, and discuss the possible sources of uncertainties in asteroseismic stellar modeling where further studies are still needed.Comment: 46 pages, 10 figures, ApJ accepte