Thermo-mechanical properties and creep modelling of wine lees filled Polyamide 11 (PA11) and Polybutylene succinate (PBS) bio-composites

Solid wine wastes named wine lees (WL) have been mixed in different percentages (10, 20 and 40 phr) within Polyamide 11 (PA11) and Polybutylene Succinate (PBS) by twin-screw extrusion. Reactive extrusion has been also tested using 3-methacryloxypropyltrimethoxysilane tested as coupling agent. The obtained bio-composites have been characterized from a thermal (DSC, TGA, HDT), rheological (MFR), mechanical (tensile test) and thermo-mechanical (DMA, creep test) point of view. Micro-mechanics models of Voigt, Halpin-Tsai and Pukanszky have been fitted on tensile properties data meanwhile the creep behavior has been modeled and described through the models of Burger, Kohlrausch-Williams-Watts and Findley

Advances in Catalytic Routes for the Homogeneous Green Conversion of the Bio-Based Platform 5-Hydroxymethylfurfural

5-Hydroxymethylfufural (HMF) is an intriguing platform molecule that can be obtained from biomasses and that can lead to the production of a wide range of products, intermediates, or monomers. The presence of different moieties in HMF (hydroxy, aldehyde, furan ring) allows to carry out different transformations such as selective oxidations and hydrogenations, reductive aminations, etherifications, decarbonylations, and acetalizations. This is a great chance in a biorefinery perspective but requires the development of active and highly selective catalysts. In this view, homogeneous catalysis can lead to efficient conversion of HMF at mild reaction conditions. This Review discussed the recent achievements in homogeneous catalysts development and application to HMF transformations. The effects of metal nature, ligands, solvents, and reaction conditions were reported and critically reviewed. Current issues and future chances have been presented to drive future studies toward more efficient and scalable processes

On the spatial and temporal variability of atmospheric heat transport in a hierarchy of models

This is the final version of the article. Available from American Meteorological Society via the DOI in this record.The aquaplanet and heton model data are available upon request to the authors. The wavelet analysis was performed using code from C. Torrence and G. Compo, available at http://atoc.colorado.edu/research/wavelets/.The present study analyzes the spatial and temporal variability of zonally integrated meridional atmospheric heat transport due to transient eddies in a hierarchy of datasets. These include a highly idealized two-layer model seeded with point geostrophic vortices, an intermediate complexity GCM, and the European Centre for Medium-Range Weather Forecasts interim reanalysis (ERA-Interim) data. The domain of interest is the extratropics. Both the two-layer model and the GCM display a pronounced temporal variability in the zonally integrated meridional transport, with the largest values (or pulses) of zonally integrated transport being associated with extended regions of anomalously strong local heat transport. In the two-layer model these large-scale coherent transport regions, termed "heat transport bands," are linked to densely packed baroclinic vortex pairs and can be diagnosed as low-wavenumber streamfunction anomalies. In the GCM they are associated with both the warm and cold sectors of midlatitude weather systems. Both these features are also found in ERA-Interim: the heat transport bands match weather systems and occur primarily in the storm-track regions, which in turn correspond to planetary-scale climatological streamfunction anomalies. The authors hypothesize that the temporal variability of the zonally integrated heat transport is partly linked to oscillatory variations in the storm-track activity but also contains a background red noise component. The existence of a pronounced variability in the zonally integrated meridional heat transport can have important consequences for the interplay between midlatitude dynamics and the energy balance of the high latitudes.During this research, G. Messori has been funded by the U.K.’s Natural Environment Research Council (RAPID–RAPIT project), Sweden’s Vetenskapsrådet (MILEX project; Grant 2012-40395-98427-17), and the Department of Meteorology of Stockholm Universit

Designing epoxy viscosity for optimal mechanical performance of coated Glass Textile Reinforced Mortar (GTRM) composites

Preliminary epoxy coating of the reinforcing fabric provides an effective approach for improving matrix-to-fabric strength in inorganic matrix composites. We investigate the effect of epoxy resin dilution in acetone on uni-axial tensile performance of coated alkali-resistant (AR) glass fabric embedded in a lime-based matrix. Remarkably, it is found that dilution has a mixed effect on performance and this trend is consistently retrieved for strength, ductility and energy dissipation. Indeed, performance initially decays and then it suddenly raises to a level close to or even exceeding that of the undiluted specimens. It is postulated that this behaviour is caused by resin viscosity, that falls off exponentially with the dilution degree. Once a viscosity threshold is breached, epoxy is capable of penetrating inside the yarn and thereby prevents telescopic failure, that is the sliding of the outer over the inner glass filaments. Furthermore, the interphase surface area increases dramatically and this enhances performance and narrows scattering. Besides, optimal viscosity is reached at an unexpectedly high dilution degree, whence material cost is significantly reduced. A cost-to-performance comparison of common strengthening technologies is presented, which shows that diluted epoxy composites score comparably to FRPs. It is concluded that epoxy coating optimization plays an important role in designing inorganic matrix composites

Effect of high temperature exposure on epoxy-coated glass textile reinforced mortar (GTRM) composites

An experimental investigation on the mechanical performance of epoxy-coated Alkali-Resistant (AR) glass textile reinforced mortar subjected to elevated temperature is presented. Two epoxy coatings are considered, which differ by the hardening agent alone. After 56 days dry curing, specimens are heated up to four different temperatures. After cooling down to ambient temperature, specimens are assessed in uni-axial tensile test according to Annex A of AC434. First cracking strength and elongation, ultimate tensile strength and elongation, cracked and uncracked moduli, transition point location and energy dissipation capability are evaluated. It is found that, in the explored temperature range, degradation is surprisingly mild and strongly dependent on the resin which is taken as coating agent. Indeed, temperature exposure may lead to strength enhancement. This positive outcome takes place at the expense of ductility and it is traced back, through Differential Scanning Calorimetry (DSC), to a post-curing process. Nonetheless, energy dissipation still decreases with temperature and, remarkably, with the same power-law behaviour for both resins. Such behaviour is compatible with a cumulative Weibull distribution, that is adopted in thermal damage models for resins, and it indicates that the underlying damage mechanism indeed operates on the resin at the fabric-to-matrix interface. (C) 2019 Elsevier Ltd. All rights reserved

Effect of high temperature exposure on epoxy-coated glass textile reinforced mortar (GTRM) composites

An experimental investigation on the mechanical performance of epoxy-coated Alkali-Resistant (AR) glass textile reinforced mortar subjected to elevated temperature is presented. Two epoxy coatings are considered, which differ by the hardening agent alone. After 56 days dry curing, specimens are heated up to four different temperatures. After cooling down to ambient temperature, specimens are assessed in uni-axial tensile test according to Annex A of AC434. First cracking strength and elongation, ultimate tensile strength and elongation, cracked and uncracked moduli, transition point location and energy dissipation capability are evaluated. It is found that, in the explored temperature range, degradation is surprisingly mild and strongly dependent on the resin which is taken as coating agent. Indeed, temperature exposure may lead to strength enhancement. This positive outcome takes place at the expense of ductility and it is traced back, through Differential Scanning Calorimetry (DSC), to a post-curing process. Nonetheless, energy dissipation still decreases with temperature and, remarkably, with the same power-law behaviour for both resins. Such behaviour is compatible with a cumulative Weibull distribution, that is adopted in thermal damage models for resins, and it indicates that the underlying damage mechanism indeed operates on the resin at the fabric-to-matrix interface. (C) 2019 Elsevier Ltd. All rights reserved

Designing epoxy viscosity for optimal mechanical performance of coated Glass Textile Reinforced Mortar (GTRM) composites

Preliminary epoxy coating of the reinforcing fabric provides an effective approach for improving matrix-to-fabric strength in inorganic matrix composites. We investigate the effect of epoxy resin dilution in acetone on uni-axial tensile performance of coated alkali-resistant (AR) glass fabric embedded in a lime-based matrix. Remarkably, it is found that dilution has a mixed effect on performance and this trend is consistently retrieved for strength, ductility and energy dissipation. Indeed, performance initially decays and then it suddenly raises to a level close to or even exceeding that of the undiluted specimens. It is postulated that this behaviour is caused by resin viscosity, that falls off exponentially with the dilution degree. Once a viscosity threshold is breached, epoxy is capable of penetrating inside the yarn and thereby prevents telescopic failure, that is the sliding of the outer over the inner glass filaments. Furthermore, the interphase surface area increases dramatically and this enhances performance and narrows scattering. Besides, optimal viscosity is reached at an unexpectedly high dilution degree, whence material cost is significantly reduced. A cost-to-performance comparison of common strengthening technologies is presented, which shows that diluted epoxy composites score comparably to FRPs. It is concluded that epoxy coating optimization plays an important role in designing inorganic matrix composites

Effect of high temperature exposure on epoxy-coated glass textile reinforced mortar (GTRM) composites

An experimental investigation on the mechanical performance of epoxy-coated Alkali-Resistant (AR) glass textile reinforced mortar subjected to elevated temperature is presented. Two epoxy coatings are considered, which differ by the hardening agent alone. After 56 days dry curing, specimens are heated up to four different temperatures. After cooling down to ambient temperature, specimens are assessed in uni-axial tensile test according to Annex A of AC434. First cracking strength and elongation, ultimate tensile strength and elongation, cracked and uncracked moduli, transition point location and energy dissipation capability are evaluated. It is found that, in the explored temperature range, degradation is surprisingly mild and strongly dependent on the resin which is taken as coating agent. Indeed, temperature exposure may lead to strength enhancement. This positive outcome takes place at the expense of ductility and it is traced back, through Differential Scanning Calorimetry (DSC), to a post-curing process. Nonetheless, energy dissipation still decreases with temperature and, remarkably, with the same power-law behaviour for both resins. Such behaviour is compatible with a cumulative Weibull distribution, that is adopted in thermal damage models for resins, and it indicates that the underlying damage mechanism indeed operates on the resin at the fabric-to-matrix interface. (C) 2019 Elsevier Ltd. All rights reserved

Thermal and UV aging of polypropylene stabilized by wine seeds wastes and their extracts

A commercial tannin wine seed extract powder (T), a seed polyphenol extract (Sext) and virgin wine seeds wastes (Se) have been mixed with polypropylene (PP) and tested as long-term stabilizers. Their stabilizing activity has been compared with that of a synthetic antioxidant commonly used within PP (Irganox 1010). Each sample has been subject to both UV and thermal aging. The PP-based films photo-oxidation has been followed through the C=O formation over the aging time by FT-IR. The PP-based tensile specimens have been oven aged and the mechanical properties loss has been investigated monitoring the variation of the elongation at break. Melt Flow Index (MFI) measures and Different Scanning Calorimetry analysis have been conducted on thermally aged samples. At the same time, wine derived additives have been characterized in terms of total polyphenol content, FT-IR and UV/VIS spectra meanwhile catechin and gallic acid have been quantified by LC-MS. Experimental results have evidenced the ability of all the wine derived additives to withstand both to thermal and UV long-term degradation. In particular, wine seeds extracts exhibit the best results in terms of stabilization (even better than Irganox 1010) without compromising the PP mechanical, thermal, morphological and rheological properties

Metallo therapeutics for COVID-19. Exploiting metal-based compounds for the discovery of new antiviral drugs

Introduction: The COVID-19 pandemic poses an unprecedented challenge for the rapid discovery of drugs against this life-threatening disease. Owing to the peculiar features of the metal centers that are currently used in medicinal chemistry, metallodrugs might offer an excellent opportunity to achieve this goal. Areas covered: Two main strategies for developing metal-based drugs against the SARS-CoV-2 are herein illustrated. Firstly, a few clinically approved metallodrugs could be evaluated in patients according to a ‘drug repurposing’ approach. To this respect, the gold drug auranofin seems a promising candidate, but some other clinically established metal compounds are worthy of a careful evaluation as well. On the other hand, libraries of inorganic compounds, featuring a large chemical diversity, should be screened to identify the most effective molecules. This second strategy might be assisted by a pathway-driven discovery approach arising from a preliminary knowledge of the mode of action, exploitable to inhibit the functional activities of the key viral proteins. Also, attention must be paid to selectivity and toxicity issues. Expert opinion: The medicinal inorganic chemistry community may offer a valuable contribution against COVID-19. The screening of metallodrugs’ libraries can expand the explored ‘chemical space’ and increase the chance of finding effective anti-COVID agents