Efficient T-CONT-agnostic Bandwidth and Wavelength Allocation for NG-PON2

Dynamic bandwidth and wavelength allocation are used to demonstrate high quality of service (QoS) in time wavelength-division multiplexed–passive optical networks (TWDM-PONs). Both bandwidth and wavelength assignment are performed on the basis of transmission containers (T-CONTs) and therefore by means of upstream service priority traffic flows. Our medium access control (MAC) protocol therefore ensures consistency in processing alike classes of service across all optical network units (ONUs) in agreement with their QoS figures. For evaluation of the MAC protocol performance, a simulator has been implemented in OPNET featuring a 40 km, 40 Gbps TWDM-PON with four stacked wavelengths at 10 Gbps each and 256 ONUs. Simulation results have confirmed the efficiency of allocating bandwidth to each wavelength and the significant increase of network traffic flow due to adaptive polling from 9.04 to 9.74 Gbps. The benefit of T-CONT-centric allocation has also been measured with respect to packet delay and queue occupancy, achieving low packet delay across all T-CONTs. Therefore, improved NG-PON2 performance and greater efficiency are obtained in this first demonstration of T-CONTs allocated to both wavelength and time.Peer reviewe

Industrial Application of Nanocelluloses in Papermaking: A Review of Challenges, Technical Solutions, and Market Perspectives

Nanocelluloses (NC) increase mechanical and barrier paper properties allowing the use of paper in applications actually covered by other materials. Despite the exponential increase of information, NC have not been fully implemented in papermaking yet, due to the challenges of using NC. This paper provides a review of the main new findings and emerging possibilities in this field by focusing mainly on: (i) Decoupling the effects of NC on wet-end and paper properties by using synergies with retention aids, chemical modification, or filler preflocculation; (ii) challenges and solutions related to the incorporation of NC in the pulp suspension and its effects on barrier properties; and (iii) characterization needs of NC at an industrial scale. The paper also includes the market perspectives. It is concluded that to solve these challenges specific solutions are required for each paper product and process, being the wet-end optimization the key to decouple NC effects on drainage and paper properties. Furthermore, the effect of NC on recyclability must also be taken into account to reach a compromise solution. This review helps readers find upscale options for using NC in papermaking and identify further research needs within this field

Modelling the Mineralization of Formaldehyde by Treatment with Nitric Acid

Formaldehyde is a recalcitrant pollutant, which is difficult to remove from wastewater using conventional and advanced treatments. The objective of this research was to remove the organic matter from formaldehyde from an industrial wastewater, achieving its total mineralization and allowing the reuse of the water. The treatment was based on the reaction of formaldehyde with nitric acid, which was first studied and modelled with synthetic waters. Results show that it was possible to almost completely mineralize the formaldehyde (>95% TOC removal) at the best conditions studied (1.72 M of nitric acid and 85 °C of temperature). The addition of NaNO2 accelerated this reaction; however, after 2 h of reaction time, its effect was negligible at the maximum concentration of HNO3 studied. The results obtained with industrial wastewater fit well with the model. It is concluded that formaldehyde in actual wastewaters can be successfully removed through direct mineralization with nitric acid, under selected conditions

Effect of Bleached Eucalyptus and Pine Cellulose Nanofibers on the Physico-Mechanical Properties of Cartonboard

Extending the limits of paper recycling by increasing the number of recycling cycles results in decreased mechanical properties due to the irreversible hornification of cellulose fibers. This process alters the fiber structure and properties because of the repeated chemical and mechanical treatments that occur during wetting and drying. As a result, poor tensile strength is the main source of customer complaints to paper manufacturers. Cellulose nanofibers (CNF) from bleached eucalyptus and pine pulps were investigated as potential strength additives because of their proven contribution to interfiber bonding. These results were compared to the results obtained using different families of strength additives. The effects on the mechanical properties of recycled old corrugated containers were studied by measuring bursting, tensile, and short span compressive strength. Cellulose nanofibers and cationic polyacrylamide (cPAM) improved the mechanical strength properties when they were added at doses around 4 wt.%. A combination of CNF and cPAM was also tested. The effects of the combined additives were not as high as expected compared to the results achieved individually. The CNF from pine pulp resulted in the highest increase in bursting index when combined with cPAM, achieving an increase of over 93%. The combination of CNF from eucalyptus pulp and cPAM increased the bursting index over 60%

Ni(II) and Pb(II) Removal Using Bacterial Cellulose Membranes

Bacterial cellulose (BC) is a highly crystalline nanosized material with a high number of active groups. This study focuses on the synthesis of BC membranes through fermentation, their characterization and application to remove Ni(II) and Pb(II) from wastewater by adsorption under different conditions. Four-day-grown BC membranes form three-dimensional nanofibril networks with a pH of 6.3 and a high cationic demand (52.5 μeq·g−1). The pseudo-second-order kinetic model and the Sips isotherm model best describe the adsorption of both metals. The intraparticle diffusion model of Ni(II) revealed a three-step mechanism of adsorption-plateau-adsorption, while Pb(II) adsorption followed a typical reducing-slope trend up to saturation. The highest removal of Ni(II) and Pb(II) was obtained at pH 4 with a BC dosage of 400 mg·L−1. The maximum adsorption capacities were 28.18 mg·g−1 and 8.49 mg·g−1 for Ni(II) and Pb(II), respectively, involving the total coverage of the material active sites. Thermodynamically, Ni(II) adsorption was exothermic, and Pb(II) was endothermic. The obtained values of sorption heat, activation and Gibbs’ energy depicted a physisorption process. Ni(II) removal mechanism was ruled by crystallization on the metals adsorbed on the BC active groups, while Pb(II) was driven by the adsorption process, as shown by TEM images of the spent material

Interactions between cellulose nanofibers and retention systems in flocculation of recycled fibers

Although the positive effect that cellulose nanofibers (CNF) can have on paper strength is known, their effect on flocculation during papermaking is not well understood, and most relevant studies have been carried out in presence of only cationic starch. Flocculation is the key to ensuring retention of fibers, fines, and fillers, and furthermore floc properties have a great influence on paper quality. The aim of this research is to study the interactions between CNF and flocculants by assessing the effect of two types of CNF, from eucalyptus and corn, on the flocculation process induced by three different retention systems [a dual system, polyvinylamine (PVA), and cationic starch as reference]. The results showed that CNF interacted with the flocculants in different ways, affecting flocculation efficiency and floc properties. In general, addition of CNF increased floc stability and minimized overdosing effects. Moreover, presence of CNF increased floc size for given PVA dose; therefore, CNF addition could contribute to improve the wet end in the paper machine if combined with the optimal flocculant and dose.Economy and Competitiveness Ministry of Spain (MINECO)Depto. de Ingeniería Química y de MaterialesFac. de Ciencias QuímicasTRUEpu

No aplica

Agro-wastes valorization focusses on production of high value-added products, such as cellulose nanofibers (CNF), and contributes to reduce the environmental impact of these residues. CNF have been used successfully as papermaking additives and some previsions maintain that this sector will become the most important, demanding CNF at a reasonable cost. Furthermore, the optimization of the production process of CNF from agricultural residues would contribute to the goals of a circular economy, the development of rural areas and the costs reduction by producing CNF of the minimum quality fit-for-use in recycled paper. In this study, CNF was produced from two agricultural residues; corn (C-CNF) and rape (R-CNF) stalk pulps, pretreated with bleaching, refining and TEMPO-mediated oxidation. Coagulant and cationic polyacrylamide (dual system) and chitosan were the retention systems. Results show the difficulty of predicting the effect of CNF based on their properties, as fibrillation degree or anionic charge, on the improvement of mechanical properties of recycled paper. That is proved by the low differences in tensile index (TI) improvement (similar to 15% by adding 0.5% C-CNF combined with dual system), obtained with CNF with very different properties. The expensive TEMPO pretreatment could be avoid by applying bleaching pretreatment to the corn pulp, increasing the TI up to 15% without affecting drainage and decoupling the simultaneous deterioration of drainage with TI improvement (drainage time decreased nearly 50% and 20% adding bleached R-CNF and C-CNF, respectively, combined with chitosan). Similar improvements on TI can be achieved by replacing the dual retention system by chitosan without addition of CNF, but the combination of CNF and chitosan allows achieving the highest TI values.Economy and Competitiveness Ministry of Spain (MINECO)Depto. de Ingeniería Química y de MaterialesFac. de Ciencias QuímicasTRUEpu

Synergies between cellulose nanofibers and retention additives to improve recycled paper properties and the drainage process

Cellulose nanofibers (CNF) have increasing relevance in different applications, for instance, in the paper industry as a sustainable strength additive. This application is especially beneficial for recycled paper, which reaches higher product quality despite its limitations. CNF change paper properties and also can affect the production process, especially the drainage stage, in which retention additives (RA) are commonly used to promote interaction of cellulose fibers. CNF probably interact with fibers and RA, affecting the drainage stage. However, these interactions vary depending on the type and flocculation mechanism of RA. This research is aimed at establishing possible synergies between CNF and RA to improve paper strength, avoiding negative effects on the drainage process. No further RA were used to retain CNF, taking advantage of the RA already used in the process. Polyvinylamine, chitosan, cationic starch, C-PAM, and C-PAM-B were selected as RA. CNF from eucalyptus kraft pulp and corn stalk organosolv pulp were tested. Strength properties of laboratory sheets were studied, and interactions were assessed by measuring Z-potential. Synergies between PVA, chitosan, C-PAM, and C-PAM-B with CNF were found. Drainage time decreased ranging between 30 and more than 40% using CNF. Strength depended on RA and formation quality. Among the studied options, CNF with C-PAM-B or chitosan resulted in the best formation and higher strengths with a significant drainage time reduction.Economy and Competitiveness Ministry of Spain (MINECO)Depto. de Ingeniería Química y de MaterialesFac. de Ciencias QuímicasTRUEpu

Smart Sorption: Novel applications of cellulosic nanomaterials for selective critical metal recovery from black mass leachates through multibatch processes

International audienceSelective critical metal recovery from black mass leachates (BML) is a great challenge for the Li-ion batteries recycling sector. This paper shows the potential of nanocellulose products as green adsorbents for a selective recovery of critical metals through multibatch sorption processes. Cellulose nanocrystals (CNCs) and cellulose nanofibers (CNFs) of 0.4 and 1.5 meq/g cationic demand, respectively, have been produced and used as biosorbents. Metal leaching from non-pyrolyzed black mass with HCl presented the highest critical metal extraction yield, obtaining up to 10 g/L of Co and more than 1 g/L of Cu, Mn and Ni. The adsorbents were tested under different dosages and pH conditions for the treatment of both synthetic multimetal solution (MMS), with Mn, Cu, Co, and Ni, and real BML, through a multiple step batch treatment to increase the selectivity towards each critical metal. For MMS treatments, the lowest pH (1–2) conditions are favorable for Co separation, reaching 135 g/g, while higher pH values (4–5) are better to recover Cu and Ni. Selectivity indexes between metals could reached values above 40 for the optimal conditions. For the treatment of BML, pH around 3 enhanced the selectivity of Al and pH of 5 of the Li. In this case, metal recoveries were higher than 30 g/g. When CNCs were used, more than 4 g/g of Co was adsorbed, recovering more than 99 % of the Co present in the waste. 99 % of Co purity was obtained at the optimal Co selective recovery conditions. Although the studied critical metals were strongly sorbed onto the nanocelluloses, a solution with a concentration of 2.5–5 g/L of these metals could be extracted from desorption tests