Applicability of BaTiO 3 /graphene oxide (GO) composite for enhanced photodegradation of methylene blue (MB) in synthetic wastewater under UV–vis irradiation

Abstract(#br)Methylene blue (MB) is a dye pollutant commonly present in textile wastewater. We investigate and critically evaluate the applicability of BaTiO 3 /GO composite for photodegradation of MB in synthetic wastewater under UV–vis irradiation. To enhance its performance, the BaTiO 3 /GO composite is varied based on the BaTiO 3 weight. To compare and evaluate any changes in their morphologies and crystalline structures before and after treatment, BET (Brunauer–Emmett–Teller), XRD (X-ray diffraction), FTIR (Fourier transform infrared spectroscopy), SEM (scanning electron microscopy) and TEM (transmission electron microscopy) tests are conducted, while the effects of reaction time, pH, dose of photocatalyst and initial MB concentration on its photodegradation by the composite are also investigated under identical conditions. The degradation pathways and removal mechanisms of MB by the BaTiO 3 /GO are elaborated. It is evident from this study that the BaTiO 3 /GO composite is promising for MB photodegradation through ·OH. Under optimized conditions (0.5 g/L of dose, pH 9.0, and 5 mg/L of MB concentration), the composite with 1:2 dose ratio of BaTiO 3 /GO has the highest MB degradation rate (95%) after 3 h of UV vis irradiation. However, its treated effluents still could not comply with the discharge standard limit of less than 0.2 mg/L imposed by national environmental legislation. This suggests that additional biological treatments are still required to deal with the remaining oxidation by-products of MB, still present in the wastewater samples such as 3,7-bis (dimethyl-amino)-10H-phenothiazine 5-oxide

Applicability of BaTiO3/graphene oxide (GO) composite for enhanced photodegradation of methylene blue (MB) in synthetic wastewater under UV-vis irradiation.

Methylene blue (MB) is a dye pollutant commonly present in textile wastewater. We investigate and critically evaluate the applicability of BaTiO3/GO composite for photodegradation of MB in synthetic wastewater under UV-vis irradiation. To enhance its performance, the BaTiO3/GO composite is varied based on the BaTiO3 weight. To compare and evaluate any changes in their morphologies and crystalline structures before and after treatment, BET (Brunauer-Emmett-Teller), XRD (X-ray diffraction), FTIR (Fourier transform infrared spectroscopy), SEM (scanning electron microscopy) and TEM (transmission electron microscopy) tests are conducted, while the effects of reaction time, pH, dose of photocatalyst and initial MB concentration on its photodegradation by the composite are also investigated under identical conditions. The degradation pathways and removal mechanisms of MB by the BaTiO3/GO are elaborated. It is evident from this study that the BaTiO3/GO composite is promising for MB photodegradation through ·OH. Under optimized conditions (0.5 g/L of dose, pH 9.0, and 5 mg/L of MB concentration), the composite with 1:2 dose ratio of BaTiO3/GO has the highest MB degradation rate (95%) after 3 h of UV vis irradiation. However, its treated effluents still could not comply with the discharge standard limit of less than 0.2 mg/L imposed by national environmental legislation. This suggests that additional biological treatments are still required to deal with the remaining oxidation by-products of MB, still present in the wastewater samples such as 3,7-bis (dimethyl-amino)-10H-phenothiazine 5-oxide

Applicability of TiO2(B) nanosheets@hydrochar composites for adsorption of tetracycline (TC) from contaminated water

We test the feasibility of TiO2(B)@carbon composites as adsorbents, derived from wheat straws, for tetracycline (TC) adsorption from aqueous solutions. Hydrochar (HC), biochar (BC), and hydrochar-derived pyrolysis char (HDPC) are synthesized hydrothermally from the waste and then functionalized with TiO2(B), named as ‘Composite-1′ , ‘Composite-2′ , and ‘Composite-3′ , respectively. A higher loading of TiO2(B) into the HC was also synthesized for comparison, named as ‘Composite-4′ . To compare their physico-chemical changes before and after surface modification, the composites are characterized using FESEM-EDS, XRD, BET, FRTEM, and FTIR. The effects of H2O2 addition on TC removal are investigated. Adsorption kinetics and isotherms of TC removal are studied, while TC adsorption mechanisms are elaborated. We found that the Composite-4 has the highest TC removal (93%) at pH 7, 1 g/L of dose, and 4 h of reaction time at 50 mg/L of TC after adding H2O2 (10 mM). The TC adsorption capacities of the Composite-1 and Composite-4 are 40.65 and 49.26 mg/g, respectively. The TC removal by the Composite-1 follows the pseudo-second order. Overall, this suggests that converting the wheat straw into HC and then functionalizing its surface with TiO2(B) as a composite has added values to the waste as an adsorbent for wastewater treatment

The Impact of Tourism on Ecosystem Services Value: A Spatio-Temporal Analysis Based on BRT and GWR Modeling

The healthy development of the ecosystem and tourism in destinations plays an essential role in sustainable development. Taking Shennongjia as an example, we analyzed the spatial–temporal variation in the ecosystem services value (ESV) and investigated the impacts of tourism on ESV and their spatial heterogeneity using the geographically weighted regression (GWR) and boosting regression tree (BRT) models. The results showed that (1) the types of ecosystem services (ESs) were dominated by climate regulation and biodiversity. The ESV increased from 3.358 billion yuan to 8.910 billion yuan from 2005 to 2018 and showed significant spatial divergence, maintaining a long-term distribution pattern of high in the center and low at the border. (2) The GWR and BRT results showed that the Distance to Scenic Spots (DSS) and the Distance to Residential Areas (DRA) are important factors influencing ESV, with the Distance to Hotels (DH) and the Distance to Roads (DR) having a relatively weak influence on ESV. (3) The influencing factors presented positive and negative effects, and the degree of influence has spatial heterogeneity. The DRA and DH inhibited the increase in ESV in nearby areas, while DR was the driving factor for increasing ESV. The assessment results of DSS vary according to the models

Correlation between p-STAT3 overexpression and prognosis in lung cancer: A systematic review and meta-analysis.

Previous studies have shown the correlation between p-STAT3 overexpression and prognosis in a variety of human tumors. However, their correlation in lung cancer remains controversial. We performed a systematic review and meta-analysis to explore the correlation between p-STAT3 overexpression and prognosis in lung cancer patients.We searched PubMed, Embase, Web of Science, CNKI, VIP, and WanFang Data to identify relevant studies. Two reviewers independently screened the literature search results, extracted data, and assessed the methodological quality of the included studies. Then, meta-analysis was performed by using Review Manager 5.3 and STATA 14 software. A random-effect model was employed to evaluate all related pooled results. Statistical heterogeneity of each study was assessed by I2. Publication bias was determined by funnel plot and the Begg's or Egger's tests.Eventually, 13 studies were included in present meta-analysis. Among these 13 studies, 8 studies were associated with the overall survival of lung cancer and 10 studies with other clinicopathological characteristics. The results of this meta-analysis suggested that p-STAT3 overexpression may be a poor prognosis biomarker in lung cancer (HR: 1.23; 95% CI: 1.04-1.46; P = 0.02). In terms of other clinicopathological characteristics, p-STAT3 overexpression was more frequent to advanced TNM stages ranging from III to IV (OR: 1.92; 95% CI: 1.13-3.27; P = 0.02) and lymphatic node metastasis (OR: 1.81; 95% CI: 1.20-2.72; P = 0.004). But, it was not associated with tumor differentiation (OR: 0.82; 95% CI: 0.44-1.53; P = 0.54).p-STAT3 overexpression has significant correlation with poorer overall survival of lung cancer patients, as well as with more advanced TNM stages and lymph node metastasis. Thus, it may serve a biomarker for poor prognosis in lung cancer. Nevertheless, our findings should be confirmed by large prospective studies

Determination of iodine-129 in twenty soil and sediment reference materials

Increasing attention has been paid to I-129 in soils and sediments for the purpose of environmental radioactivity monitoring, and understanding historic nuclear activities and their impacts. Accurate measurement of I-129 is vital, which greatly increases the requirement of various certified reference materials (CRMs). However, only a few CRMs with low levels of I-129 are available for accurate determination of I-129 in samples remote from nuclear sites and facilities. Here, this work investigated the concentrations of I-129 and I-127, and I-129/I-127 atomic ratios in twenty Chinese soil and sediment CRMs commercially available, as well as one in-house soil standard material (XASTD), with high-temperature pyrolysis combustion coupled with ICP-MS and accelerator mass spectrometry (AMS) measurements. This study demonstrates that I-129 concentrations in the twenty CRMs and one laboratory soil standard range from 0.31 x 10(6) atoms per g to 34.7 x 10(6) atoms per g, which were 1-4 orders of magnitude lower than those of the reference materials in use. For accurate measurement of I-129, the effect of salinity content in the samples on the iodine current intensity of the AMS measurement is firstly discussed. Significant salinity effect occurred when a high-salinity sample is analysed, which is likely due to the formation of abundant strong oxidants during the pyrolysis process, resulting in the existence of iodine as iodate instead of iodide. And finally, an analytical procedure is recommended for the low- and high-salinity soil and sediment samples. In summary, the reported data of the CRMs and the laboratory in-house control soil standard would broaden the group of available reference materials, be useful for method development of low-level I-129 samples, interlaboratory comparison and short- and long-term quality control, as well as extend I-129 applications in geological, environmental and nuclear sciences

Seizures in PPT1 Knock-In Mice Are Associated with Inflammatory Activation of Microglia

Infantile neuronal ceroid lipofuscinosis (INCL), the most severe form of neuronal ceroid lipofuscinoses, is caused by mutations in the lysosomal enzyme palmitoyl protein thioesterase 1 (PPT1). Typical symptoms of this disease include progressive psychomotor developmental retardation, visual failure, seizures, and premature death. Here, we investigated seizure activity and relevant pathological changes in PPT1 knock-in mice (PPT1 KI). The behavior studies in this study demonstrated that PPT1 KI mice had no significant seizure activity until 7 months of age, and local field potentials also displayed epileptiform activity at the same age. The expression levels of Iba-1 and CD68 demonstrated, by Western blot analysis, the inflammatory cytokine TNF-α content measured with enzyme-linked immunosorbent assay, and the number of microglia demonstrated by immunohistochemistry (IHC) were significantly increased at age of 7 months, all of which indicate microglia activation at an age of seizure onset. The increased expression of GFAP were seen at an earlier age of 4 months, and such an increase reached its peak at age of 6 months, indicating that astrocyte activation precedes microglia. The purinergic P2X7 receptor (P2X7R) is an ATP-sensitive ionic channel that is highly expressed in microglia and is fundamental to microglial activation, proliferation, cytokines release and epilepsy. We show that the ATP concentration in hippocampal tissue in PPT1 KI mice was increased using an enhanced ATP assay kit and demonstrated that the antagonist of P2X7R, A-438079, significantly reduced seizures in PPT1 KI mice. In contrast to glial cell activation and proliferation, a significant reduction in synaptic proteins GABAAR was seen in PPT1 KI mice. These results indicate that seizure in PPT1 KI mice may be associated with microglial activation involved in ATP-sensitive P2X7R signaling and impaired inhibitory neurotransmission

Applicability of BaTiO 3/graphene oxide (GO) composite for enhanced photodegradation of methylene blue (MB) in synthetic wastewater under UV-vis irradiation

Methylene blue (MB) is a dye pollutant commonly present in textile wastewater. We investigate and critically evaluate the applicability of BaTiO3/GO composite for photodegradation of MB in synthetic wastewater under UV–vis irradiation. To enhance its performance, the BaTiO3/GO composite is varied based on the BaTiO3 weight. To compare and evaluate any changes in their morphologies and crystalline structures before and after treatment, BET (Brunauer–Emmett–Teller), XRD (X-ray diffraction), FTIR (Fourier transform infrared spectroscopy), SEM (scanning electron microscopy) and TEM (transmission electron microscopy) tests are conducted, while the effects of reaction time, pH, dose of photocatalyst and initial MB concentration on its photodegradation by the composite are also investigated under identical conditions. The degradation pathways and removal mechanisms of MB by the BaTiO3/GO are elaborated. It is evident from this study that the BaTiO3/GO composite is promising for MB photodegradation through ·OH. Under optimized conditions (0.5 g/L of dose, pH 9.0, and 5 mg/L of MB concentration), the composite with 1:2 dose ratio of BaTiO3/GO has the highest MB degradation rate (95%) after 3 h of UV vis irradiation. However, its treated effluents still could not comply with the discharge standard limit of less than 0.2 mg/L imposed by national environmental legislation. This suggests that additional biological treatments are still required to deal with the remaining oxidation by-products of MB, still present in the wastewater samples such as 3,7-bis (dimethyl-amino)-10H-phenothiazine 5-oxide

Synthesis, characterization and tribological evaluation of novel 1,4-diazabicyclo[2.2.2]octane based dicationic ionic liquids as efficient antiwear lubricant additives

Synthesis, characterization and tribological evaluation of novel 1,4-diazabicyclo[2.2.2]octane based dicationic ionic liquids as efficient antiwear lubricant additive

Forest plot for the association of p-STAT3 overexpression with tumor differentiation in lung cancer patients.

<p>Forest plot for the association of p-STAT3 overexpression with tumor differentiation in lung cancer patients.</p