Stability of Jahn-Teller distortion ordering in LaMn1-x ScxO3

We have investigated the role of Mn3+ Jahn-Teller distortion in driving ferromagnetism in the LaMn1-xScxO3 series. The replacement of Mn by Sc in LaMnO3 decreases the orthorhombic distortion of the Pbnm cell, but the unit cell remains distorted even in the LaScO3 sample. The analysis of the x-ray diffraction patterns indicates a continuous evolution from the typical Jahn-Teller distorted octahedron in LaMnO3 into a nearly regular one in LaScO3. Surprisingly, x-ray absorption spectroscopy measurements at the Mn and Sc K edges reveal the stability of both Jahn-Teller distorted MnO6 octahedron and nearly regular ScO6 octahedron along the whole Sc-substituted series. Moreover, the structure is described as a random distribution of Jahn-Teller distorted MnO6 octahedra spatially ordered as in LaMnO3 and nearly regular ScO6 octahedra. This result contrasts with the pseudocubic phase and the appearance of regular MnO6 octahedra in LaMn1-xGaxO3 for x>0.5. Thus the occurrence of Jahn-Teller distortion strongly depends on the distorted orthorhombic crystallographic structure of the matrix in which the Mn3+ atom is allocated. Besides, a ferromagnetic ground state is observed for x>0.5 in both series independently of the presence (or not) of Jahn-Teller distortions around Mn3+, which discards either the spin flipping or the vibronic superexchange models proposed for the ferromagnetism in LaMn1-xBxO3 (B=Sc or Ga).The authors thank ESRF, ALBA, and Elettra Synchrotrons for granting beam time. Financial support from the Spanish MINECO (Projects No. MAT2012-38213-C02-01 and No. MAT2011-23791) and the Diputacion General de Aragón (CAMRADS) are acknowledged.Peer Reviewe

Theory of Insulator Metal Transition and Colossal Magnetoresistance in Doped Manganites

The persistent proximity of insulating and metallic phases, a puzzling characterestic of manganites, is argued to arise from the self organization of the twofold degenerate e_g orbitals of Mn into localized Jahn-Teller(JT) polaronic levels and broad band states due to the large electron - JT phonon coupling present in them. We describe a new two band model with strong correlations and a dynamical mean-field theory calculation of equilibrium and transport properties. These explain the insulator metal transition and colossal magnetoresistance quantitatively, as well as other consequences of two state coexistence

Dependence of the Jahn-Teller distortion in LaMn1-xScxO3 on the isovalent Mn-site substitution

We investigated the relative importance of removing the Mn3+ Jahn-Teller distortion in driving ferromagnetism in LaMn1-xScxO3 combining x-ray powder diffraction and x-ray absorption spectroscopy at the Mn and Sc K-edges. By increasing the Sc content, the orthorhombic distortion of the Pbnm cell in LaMnO3 decreases but the unit-cell remains slightly distorted in LaScO3. Besides, the nearly tetragonal-distorted MO6 in LaMnO3 continuously evolves into a nearly regular one in LaScO3. On the other hand, x-ray absorption spectra show that the MnO6 octahedron remains Jahn-Teller distorted and the ScO6 octahedron is nearly regular along the whole series. Moreover, the ordering of the Mn3+ Jahn-Teller distortion is not disrupted in the ab plane for any Sc concentration. This contrasts with the Gasubstituted compounds, where a regular MnO6 is found for x > 0.5. However, both LaMn0.5Sc0.5O3 and LaMn0.5Ga0.5O3 show ferromagnetic behavior independently of the presence (or not) of Jahn-Teller distorted Mn3+. Thus, our results point to the Mn-sublattice dilution as the main effect in driving ferromagnetism in these manganites over local structure effects previously proposed by the spin flipping or the vibronic superexchange models

Deformation history of the eclogite- and jadeitite-bearing mélange from North Motagua Fault Zone, Guatemala: insights in the processes of a fossil subduction channel

In Guatemala, along the northern side of the Motagua Valley, a me ́lange consisting of blocks of eclogite and jadeitite set in a metaserpentinitic and metasedimentary matrix crops out. The metasedimentary rocks display a complex deformation history that includes four tectonic phases, from D1 to D4. The D1 phase occurs only as a relic and is characterized by a mineral assemblage developed under pressure temperature (P–T) conditions of 1.00–1.25GPa and 206–2638C. The D2 phase, characterized by isoclinal folds, schistosity and mineral/stretching lineation, developed at P–T conditions of 0.70–1.20 GPa and 279–4098C. The following D3 and D4 phases show deformations developed at shallower structural levels. Whereas the D1 phase can be interpreted as the result of underplating of slices of oceanic lithosphere during an intraoceanic subduction, the following phases have been acquired by the me ́lange during its progressive exhumation through different mechanisms. The deformations related to the D2 and D3 phases can be regarded as acquired by extrusion of the me ́lange within a subduction channel during a stage of oblique subduction. In addition, the structural evidences indicate that the coupling and mixing of different blocks occurred during the D2 phase, as a result of flow reverse and upward trajectory in the subduction channel. By contrast, the D4 phase can be interpreted as related to extension at shallow structural levels. In this framework, the exhumation- related structures in the me ́lange indicate that this process, probably long-lived, developed through different mechanisms, active in the subduction channel through time

Medical ovariectomy in menopausal breast cancer patients with high testosterone levels : a further step toward tailored therapy

Five years of adjuvant therapy with anti-estrogens reduce the incidence of disease progression by about 50% in estrogen receptor-positive breast cancer patients, but late relapse can still occur after anti-estrogens have been discontinued. In these patients, excessive androgen production may account for renewed excessive estrogen formation and increased risks of late relapse. In the 50% of patients who do not benefit with anti-estrogens, the effect of therapy is limited by de novo or acquired resistance to treatment. Androgen receptor and epidermal growth factor receptor overexpression are recognized mechanisms of endocrine resistance suggesting the involvement of androgens as activators of the androgen receptor pathway and as stimulators of epidermal growth factor synthesis and function. Data from a series of prospective studies on operable breast cancer patients, showing high serum testosterone levels are associated to increased risk of recurrence, provide further support to a role for androgens in breast cancer progression. According to the above reported evidence, we proposed to counteract excessive androgen production in the adjuvant setting of estrogen receptor-positive patients and suggested selecting postmenopausal patients with elevated levels of serum testosterone, marker of ovarian hyperandrogenemia, for adjuvant treatment with a gonadotropins-releasing hormone analogue (medical oophorectomy) in addition to standard therapy with anti-estrogens. The proposed approach provides an attempt of personalized medicine that needs to be further investigated in clinical trials

Effects of dislocation density on injection and temperature sensitivity of InGaN LED emission spectra: a combined experimental and simulation approach

The aim of this paper is to describe a combined simulation and characterization activity carried out on blue LEDs grown on templates with different threading dislocation densities (TDDs)

Fluid pressurisation and earthquake propagation in the Hikurangi subduction zone

In subduction zones, seismic slip at shallow crustal depths can lead to the generation of tsunamis. Large slip displacements during tsunamogenic earthquakes are attributed to the low coseismic shear strength of the fluid-saturated and non-lithified clay-rich fault rocks. However, because of experimental challenges in confining these materials, the physical processes responsible for the coseismic reduction in fault shear strength are poorly understood. Using a novel experimental setup, we measured pore fluid pressure during simulated seismic slip in clay-rich materials sampled from the deep oceanic drilling of the Pāpaku thrust (Hikurangi subduction zone, New Zealand). Here, we show that at seismic velocity, shear-induced dilatancy is followed by pressurisation of fluids. The thermal and mechanical pressurisation of fluids, enhanced by the low permeability of the fault, reduces the energy required to propagate earthquake rupture. We suggest that fluid-saturated clay-rich sediments, occurring at shallow depth in subduction zones, can promote earthquake rupture propagation and slip because of their low permeability and tendency to pressurise when sheared at seismic slip velocities

Information to the eye of the beholder: data visualization for many-objective optimization

The visualization gap is one of the important challenges posed by many-objective optimization problems (MaOPs). In this paper, we present an integrated data visualization method for MaOPs, called CAP-vis plot, combining the Chord diagram, the Angular mapping and the Parallel coordinates in the same visualization. The method follows the circular design layout, showing different levels of information. This new approach allows the spatial location of points in high dimensional spaces, the visualization of harmony and conflict between objectives, as well as the comparison of the approximation sets provided by different algorithms. With this work, we try to fill the visualization gap and bring information to the eye of the decision-maker and the optimizer, with an intuitive overview of the obtained results. Some experiments were performed using the Benchmark Functions proposed for the IEEE-CEC 2018 Competition on Many-Objective Optimization. We used the tool to visualize the results obtained by NSGA-III, HypE, RVEA, MOEA/DD, PICEA-g, using the PlatEMO MATLAB platform, with the same parameter settings of the competition. The results on the Benchmark Problems show the importance of the qualitative analysis of the data. The experiments show how visualization can help interpretation of the results and identification of strengths and drawbacks of MOEA.The authors would like to thank the Brazilian agencies CAPES, CNPq and FAPEMIG for the financial support

Machine learning-driven approach for large scale decision making with the analytic hierarchy process

The Analytic Hierarchy Process (AHP) multicriteria method can be cognitively demanding for large-scale decision problems due to the requirement for the decision maker to make pairwise evaluations of all alternatives. To address this issue, this paper presents an interactive method that uses online learning to provide scalability for AHP. The proposed method involves a machine learning algorithm that learns the decision maker’s preferences through evaluations of small subsets of solutions, and guides the search for the optimal solution. The methodology was tested on four optimization problems with different surfaces to validate the results. We conducted a one factor at a time experimentation of each hyperparameter implemented, such as the number of alternatives to query the decision maker, the learner method, and the strategies for solution selection and recommendation. The results demonstrate that the model is able to learn the utility function that characterizes the decision maker in approximately 15 iterations with only a few comparisons, resulting in significant time and cognitive effort savings. The initial subset of solutions can be chosen randomly or from a cluster. The subsequent ones are recommended during the iterative process, with the best selection strategy depending on the problem type. Recommendation based solely on the smallest Euclidean or Cosine distances reveals better results on linear problems. The proposed methodology can also easily incorporate new parameters and multicriteria methods based on pairwise comparisons.This research was funded by National Funds through the FCT—Portuguese Foundation for Science and Technology, References UIDB/05256/2020 and UIDP/05256/2020