Multi-layer distribution of Black Carbon and Inorganic Ions in the Snow-packs of western Himalayas and Snow Albedo Forcing

The plausible impact of light-absorbing aerosols on snow darkening and subsequent retreating of glaciers is a global climatic concern. In this study, we present the characteristics of multi-layer distribution and effects of Black Carbon (BC) and inorganic ions in the snowpacks of Khardung (KG) and Phuche (PG) glaciers (> 5 km a.s.l.) in the western Himalayas. We observed significant vertical heterogeneity of BC in the snowpacks of KG (-42-428 ng g-1) and PG (-59 and 299 ng g-1), with higher concentrations in aged snow. Similar to BC, ions in the multi-layer snowpack also depicted prominent vertical heterogeneity with strong crustal influence (as indicated by abundant nssCa2+) in the aged snow layers of KG, which also possess a higher snow-melt rate as compared to PG. Among the other inorganic ions, the vertical profiles of nssSO42- and NO3- indicated elution and refreezing effects. The computation of the effective snow albedo for different snow-darkening and snow-physical processes vindicated the need of considering the multilayer model for the accurate quantification of effects of heterogeneous distributions of light absorbing aerosols (LAA) in the snowpacks. Following this, the multi-layer simulations of snow-albedo in the SNICAR model demonstrated the change in snow albedo by 2.5-9.0% for the amount of LAA observed in our study. This resulted in snow albedo forcing of 49.2 Wm-2 for PG, 30.8 Wm-2 for KG1 and 29.6 Wm-2 for KG2 for the typical snow-physical properties in the study region. Comprehensive data sets comprising physical, morphological and chemical properties of aerosols and snow are imperative to predict aerosol-induced snow darkening and the associated anomalous melting of snow/glacier over the Himalayan region.Peer reviewe

Origin and Sources of Dissolved Organic Matter in Snow on the East Antarctic Ice Sheet

Polar ice sheets hold a significant pool of the world’s carbon reserve and are an integral component of the global carbon cycle. Yet, organic carbon composition and cycling in these systems is least understood. Here, we use ultrahigh resolution mass spectrometry to elucidate, at an unprecedented level, molecular details of dissolved organic matter (DOM) in Antarctic snow. Tens of thousands of distinct molecular species are identified, providing clues to the nature and sources of organic carbon in Antarctica. We show that many of the identified supraglacial organic matter formulas are consistent with material from microbial sources, and terrestrial inputs of vascular plant-derived materials are likely more important sources of organic carbon to Antarctica than previously thought. Black carbon-like material apparently originating from biomass burning in South America is also present, while a smaller fraction originated from soil humics and appears to be photochemically or microbially modified. In addition to remote continental sources, we document signals of oceanic emissions of primary aerosols and secondary organic aerosol precursors. The new insights on the diversity of organic species in Antarctic snowpack reinforce the importance of studying organic carbon associated with the Earth’s polar regions in the face of changing climate

Analysis of a regional change in the sign of the SAM-temperature relationship in Antarctica

This study examines regional atmospheric circulation changes associated with a reversal in the sign of the relationship between the Southern Annular Mode (SAM) and near-surface temperatures at Halley station, East Antarctica, during the 1980s. We show that the key factor affecting the regional SAM-temperature relationship (STR) is the relative magnitude of two climatological low pressure centres to the west and east of the area, which determines the source region of air masses advected into the locality. The principal difference affecting the STR is shown to be a trend towards a significantly weaker climatological low (higher pressure) at similar to 20 degrees E during a positive phase of the SAM. Specifically, it is variations in the phase and magnitude of the wave number three patterns of atmospheric circulation, the non-annular component of the SAM, which are the principal factors governing the regional STR. A similar reversal is observed in the sign of the correlation between the SAM and oxygen-isotope values from an ice core located some 1,200 km east of Halley. This relationship is examined throughout the 20th Century, by comparing the isotope data to SAM reconstructions, and demonstrates marked decadal variability. Thus, these data suggest that switches in the STR are more likely to reflect natural variability in the long-wave patterns over the Southern Ocean rather than the influence of an anthropogenic forcing. This finding is important when considering the potential utility of Antarctic isotope data as a proxy for the SAM

The conflict between on-task and off-task actions in the classroom and its consequences for motivation and achievement

Kilian B, Hofer M, Fries S, Kuhnle C. The conflict between on-task and off-task actions in the classroom and its consequences for motivation and achievement. EUROPEAN JOURNAL OF PSYCHOLOGY OF EDUCATION. 2010;25(1):67-85.The relations between students' value orientations, decisions in conflicts between on-task and off-task actions in the classroom, and experiences of motivational interference following these conflicts were investigated. It was expected that well-being value orientation was positively linked and achievement value orientation was negatively linked to decision for off-task behavior in such conflicts and that the higher students' well-being value orientation, the higher their motivational impairment when deciding for the on-task behavior and the lower when deciding for the off-task behavior. For achievement orientation, the relationships were predicted to be reversed. The experience of motivational interference while performing on-task behavior was, in turn, expected to be related to worse grades. Data from 817 students (mean age 13.44) from 35 classrooms were collected using self-report questionnaires and analyzed in a series of hierarchical linear models. Analyses showed the relationships as predicted. All relationships found were comparable to the relationships found for a conflict between school and leisure actions after class. Results point out that even if students resist the off-task temptation in class, the mere possibility of off-task behavior can impair motivation and achievement