81 research outputs found

    On the possibility of the reaction (CuMoO4 + C), using the apparent activation energy method

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    This article discusses the calculation of the apparent activation energy (CuМоO4 + C) on the DTA (Differential Thermal Analysis) curve, to study and optimize the time-temperature synthesis mode, in particular, the activation energy. Activation energy allows us to investigate the elementary act of chemical interaction. Thus, we propose to use this method to calculate the interaction of Eact (CuМоO4 + C) in the solid phase of hardening occurring during synthesis. These results allow us to trace how much energy is expended to start the reaction

    On the possibility of the reaction (CuMoO4 + C), using the apparent activation energy method

    Get PDF
    This article discusses the calculation of the apparent activation energy (CuМоO4 + C) on the DTA (Differential Thermal Analysis) curve, to study and optimize the time-temperature synthesis mode, in particular, the activation energy. Activation energy allows us to investigate the elementary act of chemical interaction. Thus, we propose to use this method to calculate the interaction of Eact (CuМоO4 + C) in the solid phase of hardening occurring during synthesis. These results allow us to trace how much energy is expended to start the reaction

    The 6.7-GHz and 25-GHz methanol masers in OMC-1

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    The Australia Telescope Compact Array (ATCA) has been used to search for methanol maser emission at 6.7 GHz towards OMC-1. Two features peaking at 7.2 km/s and -1.1 km/s have been detected. The former has at least two components close in both velocity and position. It is located south-east of the Orion Kleinmann-Low (Orion-KL) nebula in the region of outflow traced by the 25-GHz methanol masers and the 95-GHz methanol emission. It is shown by modelling that in contrast to the widespread opinion that simultaneous masing of methanol transitions of different classes is impossible there are conditions for which simultaneous masing of the class II transition at 6.7-GHz and some class I transitions (e.g. the series at 25 GHz) is possible. A relevant example is provided, in which the pumping occurs via the first torsionally excited state and is driven by radiation of the dust intermixed with the gas in the cloud. In this regime the dust temperature is significantly lower (T is about 60 K) than in the case of bright 6.7-GHz masers (T>150 K). The narrow spectral feature at -1.1 km/s has a brightness temperature greater than about 1400 K, which suggests that it is probably a maser. It emanates from the Orion South region and is probably associated with the approaching part of outflow seen in CO. The 25-GHz maser associated with OMC-1 was observed quasi-simultaneously with the 6.7-GHz observations. No 25-GHz emission associated with the -1.1 km/s 6.7 GHz feature towards Orion South was detected.Comment: 11 pages, 5 figures, 4 tables, mn2e.cls included; accepted by MNRA

    Research of the Additional Losses Occurring in Optical Fiber at its Multiple Bends in the Range Waves 1310nm, 1550nm and 1625nm Long

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    Article is devoted to research of the additional losses occurring in the optical fiber at its multiple bends in the range waves of 1310 nanometers, 1550 nanometers and 1625 nanometers long. Article is directed on creation of the external factors methods which allow to estimate and eliminate negative influence. The automated way of calculation of losses at a bend is developed. Results of scientific researches are used by engineers of "Kazaktelekom" AS for practical definition of losses service conditions. For modeling the Wolfram|Alpha environment - the knowledge base and a set of computing algorithms was chosen. The greatest losses are noted on wavelength 1310nm and 1625nm. All dependences are nonlinear. Losses with each following excess are multiplicative

    Multi-transition study and new detections of class II methanol masers

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    We have used the ATNF Mopra antenna and the SEST antenna to search in the directions of several class II methanol maser sources for emission from six methanol transitions in the frequency range 85-115 GHz. The transitions were selected from excitation studies as potential maser candidates. Methanol emission at one or more frequencies was detected from five of the maser sources, as well as from Orion KL. Although the lines are weak, we find evidence of maser origin for three new lines in G345.01+1.79, and possibly one new line in G9.62+0.20. The observations, together with published maser observations at other frequencies, are compared with methanol maser modelling for G345.01+1.79 and NGC6334F. We find that the majority of observations in both sources are consistent with a warm dust (175 K) pumping model at hydrogen density ~10^6 cm^-3 and methanol column density ~5 x 10^17 cm^-2. The substantial differences between the maser spectra in the two sources can be attributed to the geometry of the maser region.Comment: 13 pages, 6 figures, Accepted for publication in MNRA

    Long - range foundry Al composite alloys

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    The technology of obtaining nanostructural composite aluminum alloys consists in the plasma injection of refractory nanometric particles with simultaneous two-plane magnetic dynamic mixing of the melt. Particularly important in obtaining composite aluminum matrix alloys is the provision of the introduced particles wettability with the matrix melt for forming stable adhesive bonds. Nanostructured powder components can be considered not only to be a starting product for producing nanostructural composite aluminum alloys but as an independent commerce product. Nanostructural composite metal matrix alloys make one of the most prospective structural materials of the future, and liquid-phase technologies of their obtaining are the most competitive in producing products of nanostructural composite aluminum alloys in the industrial scale

    The development and analysis of the machining attachments for the decrement of oscillations of a boring bar in the process of the refinement of high-accuracy apertures

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    Technological patterns in the formation of deflections in shape and positioning of apertures in the process of boring are established on the basis of theoretical and experimental analysis. The dominant factors that influence the formation of processing errors were brought to light, taking into account the specificity of the application of PNC machines (programmed numeral control) and specific automatic control systems that position the shape-forming point of a cutting tool by means of the decrement of its oscillations in the process of aperture boring. The need for and possibility of the control of the process of shape formation under boring have been shown, which fundamentally allows to increase the refinement accuracy and to decrease errors in positioning and roughness of the processed surfaces

    Power supply of autonomous systems using solar modules

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    The article shows the methods of constructing autonomous decentralized energy systems from solar modules. It shows the operation of up DC inverter. It demonstrates the effectiveness of DC inverters with varying structure. The system has high efficiency and low level of conductive impulse noise and at the same time the system is practically feasible. Electrical processes have been analyzed to determine the characteristics of operating modes of the main circuit elements. Recommendations on using the converters have been given

    Silicon production using long flaming coal and improvement of its quality indicators

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    The object of this study is to explore possibility of metallothermic producing of crystalline silicon using various types of carbon reducing agents as a reducing agent. The experience of existing enterprises shows that one of the best carbon reducing agents qualifying silicon electric melting technology is charcoal. On the other hand, charcoal has a number of disadvantages, such as its scarcity, high cost and low mechanical strength. Experimental melts has shown the principal possibility of producing the crystalline silicon that meets the requirements of quartz standard using low ash special coke and long-flame coal as reducing agents

    Development of technology of complex aluminum-silicon-chrome alloy with utilization of off grade raw materials

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    Experimental studies on obtaining a complex aluminum-silicon-chrome alloy (FASCh) from Karaganda high-ash coals and high-carbon ferrochromefines were carried out. A method for smelting low-carbon ferrochrome using aluminum-silicon-chrome alloy as a reductant is suggested
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