97 research outputs found
Simple models for dynamic hysteresis loops calculation: Application to hyperthermia optimization
To optimize the heating properties of magnetic nanoparticles (MNPs) in
magnetic hyperthermia applications, it is necessary to calculate the area of
their hysteresis loops in an alternating magnetic field. The three types of
theories suitable for describing the hysteresis loops of MNPs are presented and
compared to numerical simulations: equilibrium functions, Stoner-Wohlfarth
model based theories (SWMBTs) and linear response theory (LRT). Suitable
formulas to calculate the hysteresis area of major cycles are deduced from
SWMBTs and from numerical simulations; the domain of validity of the analytical
formula is explicitly studied. In the case of minor cycles, the hysteresis area
calculations are based on the LRT. A perfect agreement between LRT and
numerical simulations of hysteresis loops is obtained. The domain of validity
of the LRT is explicitly studied. Formulas to calculate the hysteresis area at
low field valid for any anisotropy of the MNP are proposed. Numerical
simulations of the magnetic field dependence of the area show it follows
power-laws with a large range of exponents. Then, analytical expressions
derived from LRT and SWMBTs are used for a theoretical study of magnetic
hyperthermia. It is shown that LRT is only pertinent for MNPs with strong
anisotropy and that SWMBTs should be used for weak anisotropy MNPs. The optimum
volume of MNPs for magnetic hyperthermia as function of material and
experimental parameters is derived. The maximum specific absorption rate (SAR)
achievable is calculated versus the MNP anisotropy. It is shown that an optimum
anisotropy increases the SAR and reduces the detrimental effects of size
distribution. The optimum anisotropy is simple to calculate and depends on the
magnetic field used in the hyperthermia experiments and on the MNP
magnetization only. The theoretical optimum parameters are compared to the one
of several magnetic materials.Comment: 35 pages, 1 table, 11 figure
Influence of a transverse static magnetic field on the magnetic hyperthermia properties and high-frequency hysteresis loops of ferromagnetic FeCo nanoparticles
The influence of a transverse static magnetic field on the magnetic
hyperthermia properties is studied on a system of large-losses ferromagnetic
FeCo nanoparticles. The simultaneous measurement of the high-frequency
hysteresis loops and of the temperature rise provides an interesting insight
into the losses and heating mechanisms. A static magnetic field of only 40 mT
is enough to cancel the heating properties of the nanoparticles, a result
reproduced using numerical simulations of hysteresis loops. These results cast
doubt on the possibility to perform someday magnetic hyperthermia inside a
magnetic resonance imaging setup.Comment: 6 pages, 3 figure
Magnetic anisotropy determination and magnetic hyperthermia properties of small Fe nanoparticles in the superparamagnetic regime
We report on the magnetic and hyperthermia properties of iron nanoparticles
synthesized by organometallic chemistry. They are 5.5 nm in diameter and
display a saturation magnetization close to the bulk one. Magnetic properties
are dominated by the contribution of aggregates of nanoparticles with respect
to individual isolated nanoparticles. Alternative susceptibility measurements
are been performed on a low interacting system obtained after eliminating the
aggregates by centrifugation. A quantitative analysis using the Gittleman s
model allow a determination of the effective anisotropy Keff = 1.3 * 10^5
J.m^{-3}, more than two times the magnetocristalline value of bulk iron.
Hyperthermia measurements are performed on agglomerates of nanoparticles at a
magnetic field up to 66 mT and at frequencies in the range 5-300 kHz. Maximum
measured SAR is 280 W/g at 300 kHz and 66 mT. Specific absorption rate (SAR)
displays a square dependence with the magnetic field below 30 mT but deviates
from this power law at higher value. SAR is linear with the applied frequency
for mu_0H=19 mT. The deviations from the linear response theory are discussed.
A refined estimation of the optimal size of iron nanoparticles for hyperthermia
applications is provided using the determined effective anisotropy value
Common fixed point theorems for compatible and weakly compatible mappings
Results on common fixed points for pairs of single and multivalued mappings on a complete metric space are examined. Our work establishes a common fixed point theorem for a pair of generalized contraction self-maps and a pair of set-valued mappings
Quantum Ignition of Intramolecular Rotation by Means of IR+UV Laser Pulses
Quantum ignition of intramolecular rotation may be achieved as follows: First, a few-cycle infrared (IR) laser pulse excites the torsional vibration in an oriented molecule. Subsequently, a well timed ultrashort ultraviolet (UV) laser pulse induces a Franck-Condon type transition from the electronic ground state to the excited state with approximate conservation of the intramolecular angular momentum. As a consequence, the torsional motion is converted into a unidirectional intramolecular rotation, with high angular momentum (â 100 h). The mechanism is demonstrated by means of representative laser driven wave packets which are propagated on ab initio potential energy curves of the model system (4-methyl-cyclohexylidene)fluoromethane
Large specific absorption rates in the magnetic hyperthermia properties of metallic iron nanocubes
We report on the magnetic hyperthermia properties of chemically synthesized
ferromagnetic 11 and 16 nm Fe(0) nanoparticles of cubic shape displaying the
saturation magnetization of bulk iron. The specific absorption rate measured on
16 nm nanocubes is 1690+-160 W/g at 300 kHz and 66 mT. This corresponds to
specific losses-per-cycle of 5.6 mJ/g, largely exceeding the ones reported in
other systems. A way to quantify the degree of optimization of any system with
respect to hyperthermia applications is proposed. Applied here, this method
shows that our nanoparticles are not fully optimized, probably due to the
strong influence of magnetic interactions on their magnetic response. Once
protected from oxidation and further optimized, such nano-objects could
constitute efficient magnetic cores for biomedical applications requiring very
large heating power
Impact of composts prepared from olive waste on the growth and production parameters of some fruit trees
In agriculture, the use of organic amendments allows a better sustainability and productivity of the crop by improving the quality and structure of the soil, due to their richness in organic matter and nutrients such as phosphorus, nitrogen, potassium, etc. This study aims to evaluate the effect of two composts of different compositions on the growth and yield of three types of trees: peach, pear and orange. The experimental design used is a randomized block with three replications. The treatment of trees was carried out by four types of amendments which were composts with olive waste (OW), olive mill wastewater (OMW), manure (M) and NPK fertilizer (F) of type 10-15-12. Their fertilizing power was evaluated by monitoring the morphological parameters of plant growth: height, trunk diameter, number of branches, and those of production including size, weight of fruit and yield. The obtained outcomes reveal that the two composts have a very highly significant effect on the investigated parameters. The production was recorded only in peach trees with a total yield of 31.5 t/ha; 25.5 t/ha; 22.5 t/ha; 18.5 t/ha, respectively for OW, OMW, F and M
Particle interactions in liquid magnetic colloids by zero field cooled measurements: effects on heating efficiency
The influence of magnetic interactions in assemblies formed by either aggregated or disaggregated uniform gamma-Fe_2O_3 particles are investigated as a function of particle size, concentration, and applied field. Hyperthermia and magnetization measurements are performed in the liquid phase of colloids consisting of 8 and 13 nm uniform gamma-Fe_2O_3 particles dispersed in water and hexane. Although hexane allows the disagglomerated obtaining particle system; aggregation is observed in the case of water colloids. The zero field cooled (ZFC) curves show a discontinuity in the magnetization values associated with the melting points of water and hexane. Additionally, for 13 nm gamma-Fe_2O_3 dispersed in hexane, a second magnetization jump is observed that depends on particle concentration and shifts toward lower temperature by increasing applied field. This second jump is related to the strength of the magnetic interactions as it is only present in disagglomerated particle systems with the largest size, i.e., is not observed for 8 nm superparamagnetic particles, and surface effects can be discarded. The specific absorption rate (SAR) decreases with increasing concentration only for the hexane colloid, whereas for aqueous colloids, the SAR is almost independent of particle concentration. Our results suggest that, as a consequence of the magnetic interactions, the dipolar field acting on large particles increases with concentration, leading to a decrease of the SAR
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