Three-dimensional Reconstruction of the Caspe Geological Structure (Spain) for Evaluation as a Potential CO2 Storage Site

The Caspe geological structure was formed by the convergence of the Iberian Range and the Catalonian Coastal Range, during the Tertiary compression. Traditionally, the Caspe structure has been interpreted from seismic profiles without considering surface structural data. The aim of this study is to build a 3D geological model taking into account the structural data from the geological map, stress fields and lineaments, and evaluate its possibility as potential CO2 storage site. Four surfaces have been modelled: Buntsandstein Top, Muschelkalk-I Top, Muschelkalk-II Top and Cenozoic Bottom. Considering the geometry and depth for storage the target reservoir was considered to be the Buntsandstein facies. The available seismic data indicate that the Buntsandstein facies top is at approximately 500 m depth and hosts a deep saline aquifer. The target reservoir series include the conglomerate and sandstone of the Hoz del Gallo and Cañizar Fms (Buntsandstein Facies) with an average thickness of 500 m and 21% porosity. The seal comprises the shales and silts of the Röt Fm with an average thickness of 100-150 m. The structure volume was calculated based on the -500 mbsl for the Buntsandstein top deepest closed contour lines. The estimated volume is 5, 800 Mm3 with most of CO2 in gaseous state

Field deployment of a man-portable stand-off laser-induced breakdown spectrometer: A preliminary report on the expedition to the Cumbre Vieja volcano (La Palma, Spain, 2021)

This paper reports on the expedition to the Cumbre Vieja volcano (Canary Islands, Spain) in November 2021 to assess stand-off laser-induced breakdown spectroscopy for real-time measurements of the lava streams from a safe point. The paper provides insight on the analytical approach to the problem, the rationale of the instrument design and construction carried out in three weeks, the experience with the new-born instrument at the volcano and the preliminary results. Despite the subtle spectral differences among the samples and the signal variability induced by the strong wind gusts at site, a statistical approach to data processing such as PCA, made possible to extract sufficient information and provide a robust classification tool.We express our sincere gratitude to the Spanish Unidad Militar de Emergencias (UME) for providing essential support, security, and expertise at the field. We would like to thank Carlos Malag ́on (Astro- shop, M ́alaga, Spain) for donating the telescope used in the stand-off LIBS instrument, to the personnel of the Chemical Analysis Area and the Machine Shop of the Central Facility for Research Support (SCAI-UMA) and to Profs. E.R. Losilla and A. Cabeza (Dept. Química Inorgánica, Cristalografía y Mineralogía, UMA) and D. Marrero (Dept. Física Aplicada I, UMA) for their valuable comments and advice with the surrogate samples. This work has been partially supported by the I Plan Propio de Investigaci ́on de la Universidad de M ́alaga, the Extraordinary Funding (RD 1078/2021, 7th December, Núm. 293 Sec. I. P ́ag. 150,995) and PID2020-113407RB-I00 granted by the Spanish Ministry of Science and Innovation (MICINN). Funding for open access charge: Universidad de Málaga / CBU

Three-dimensional Reconstruction of the Caspe Geological Structure (Spain) for Evaluation as a Potential CO2 Storage Site

The Caspe geological structure was formed by the convergence of the Iberian Range and the Catalonian Coastal Range, during the Tertiary compression. Traditionally, the Caspe structure has been interpreted from seismic profiles without considering surface structural data. The aim of this study is to build a 3D geological model taking into account the structural data from the geological map, stress fields and lineaments, and evaluate its possibility as potential CO2 storage site. Four surfaces have been modelled: Buntsandstein Top, Muschelkalk-I Top, Muschelkalk-II Top and Cenozoic Bottom. Considering the geometry and depth for storage the target reservoir was considered to be the Buntsandstein facies. The available seismic data indicate that the Buntsandstein facies top is at approximately 500 m depth and hosts a deep saline aquifer. The target reservoir series include the conglomerate and sandstone of the Hoz del Gallo and Cañizar Fms (Buntsandstein Facies) with an average thickness of 500 m and 21% porosity. The seal comprises the shales and silts of the Röt Fm with an average thickness of 100-150 m. The structure volume was calculated based on the -500 mbsl for the Buntsandstein top deepest closed contour lines. The estimated volume is 5,800 Mm3 with most of CO2 in gaseous state.Financial support for this study was received from the Spanish administration through the Instituto para la Reestructuración de la Minería del Carbón y el Desarrollo Alternativo de las Comarcas Mineras (IRMC).Peer reviewe