Submarine eruption-fed and resedimented pumice-rich facies: the Dogashima Formation (Izu Peninsula, Japan)

In the Izu Peninsula (Japan), the Pliocene pumice-rich Dogashima Formation (4.55?±?0.87 Ma) displays exceptional preservation of volcaniclastic facies that were erupted and deposited in a below wave-base marine setting. It includes high-concentration density current deposits that contain clasts that were emplaced hot, indicating an eruption-fed origin. The lower part of the Dogashima 2 unit consists of a very thick sequence (&lt;12 m) of massive grey andesite breccia restricted to the base of a submarine channel, gradationally overlain by pumice breccia, which is widespread but much thinner and finer in the overbank setting. These two breccias share similar mineralogy and crystal composition and are considered to be co-magmatic and derived from the destruction of a submarine dome by an explosive, pumice-forming eruption. The two breccias were deposited from a single, explosive eruption-fed, sustained, sea floor-hugging, water-supported, high-concentration density current in which the clasts were sorted according to their density. At the rim of the channel, localised good hydraulic sorting of clasts and stratification in the pumice breccia are interpreted to reflect local current expansion and unsteadiness rather than to be the result of hydraulic sorting of clasts during fall from a submarine eruption column and/or umbrella plume. A bimodal coarse (&gt;1 m) pumice- and ash-rich bed overlying the breccias may be derived from delayed settling of pyroclasts from suspension. In Dogashima 1 and 2, thick cross- and planar-bedded facies composed of sub-rounded pumice clasts are intercalated with eruption-fed facies, implying inter-eruptive mass-wasting on the flank of a submarine volcano, and reworking and resedimentation by high-energy tractional currents in a below wave-base environment.<br/

Grain-size distribution of volcaniclastic rocks 2: Characterizing grain size and hydraulic sorting

Quantification of the grain size distribution of sediments allows interpretation of processes of transport and deposition. Jutzeler et al. (2012) developed a technique to determine grain size distribution of consolidated clastic rocks using functional stereology, allowing direct comparison between unconsolidated sediments and rocks. Here, we develop this technique to characterize hydraulic sorting and infer transport and deposition processes. We compare computed grain size and sorting of volcaniclastic rocks with field-based characteristics of volcaniclastic facies for which transport and depositional mechanisms have been inferred. We studied pumice-rich, subaqueous facies of volcaniclastic rocks from the Oligocene Ohanapecosh Formation (Ancestral Cascades, Washington, USA), Pliocene Dogashima Formation (Izu Peninsula, Honshu, Japan), Miocene Manukau Subgroup (Northland, New Zealand) and the Quaternary Sierra La Primavera caldera (Jalisco State, Mexico). These sequences differ in bed thickness, grading and abundance of matrix. We propose to evaluate grain size and sorting of volcaniclastic deposits by values of their modes, matrix proportion (< 2 mm; F-1) and D16, instead of median diameter (D50) and standard deviation parameters. F-1 and D16 can be uniformly used to characterize and compare sieving and functional stereology data. Volcaniclastic deposits typically consist of mixtures of particles that vary greatly in density and porosity. Hydraulic sorting ratios can be used to test whether inferred density of mixed clast populations of pumice and dense clasts are hydraulically sorted with each other, considering various types of transport under water. Evaluation of this ratio for our samples shows that most studied volcaniclastic facies are deposited by settling from density currents, and that basal dense clast breccia are emplaced by shear rolling. These hydraulic sorting ratios can be applied to any type of clastic rocks, and indifferently on consolidated and unconsolidated samples

Sediment-matrix igneous breccias at the top contacts of felsic units in the IPB : implications for VHMS exploration

The Volcanic Sedimentary Complex of the Iberian Pyrite Belt is dominated by mudstone units and comprises felsic lavas/domes and pyroclastic units that define lava-cryptodome-pumice cone volcanoes. Sediment-matrix igneous breccias may outline the contacts of volcanic units, occur within them, or lie laterally to the volcanic centres. These breccias can form by several processes, each with its genetic implications, having nevertheless very similar final aspect. We have distinguished and characterized several sediment-matrix breccia types. The most abundant types are sediment-infill volcanic breccia and peperite; however other types of sediment-matrix breccia were also identified. The correct identification of these breccias is crucial to reconstruct the volcanic centres and to define the stratigraphy, which in mineralized volcanic provinces is a major issue both for metallogenic and mineral exploration models

Sulfur, Chlorine, and Flourine Degassing and Atmospheric Loading by the 1783 - 1784 AD Laki (Skaftar Fires) Eruption in Iceland

The 1783-1784 Laki tholeiitic basalt fissure eruption in Iceland was one of the greatest atmospheric pollution events of the past 250 years, with widespread effects in the northern hemisphere. The degassing history and volatile budget of this event are determined by measurements of pre-eruption and residual contents of sulfur, chlorine, and fluorine in the products of all phases of the eruption. In fissure eruptions such as Laki, degassing occurs in two stages: by explosive activity or lava fountaining at the vents, and from the lava as it flows away from the vents. Using the measured sulfur concentrations in glass inclusions in phenocrysts and in groundmass glasses of quenched eruption products, we calculate that the total accumulative atmospheric mass loading of sulfur dioxide was 122 Mt over a period of 8 months. This volatile release is sufficient to have generated approximately 250 Mt of H2SO4 aerosols, an amount which agrees with an independent estimate of the Laki aerosol yield based on atmospheric turbidity measurements. Most of this volatile mass (approximately 60 wt.%) was released during the first 1.5 months of activity. The measured chlorine and fluorine concentrations in the samples indicate that the atmospheric loading of hydrochloric acid and hydrofluoric acid was approximately 7.0 and 15.0 Mt, respectively. Furthermore, approximately 75% of the volatile mass dissolved by the Laki magma was released at the vents and carried by eruption columns to altitudes between 6 and 13 km. The high degree of degassing at the vents is attributed to development of a separated two-phase flow in the upper magma conduit, and implies that high-discharge basaltic eruptions such as Laki are able to loft huge quantities of gas to altitudes where the resulting aerosols can reside for months, or even 1-2 years. The atmospheric volatile contribution due to subsequent degassing of the Laki lava flow is only 18 wt.% of the total dissolved in the magma, and these emissions were confined to the lowest regions of the troposhere and therefore important only over Iceland. This study indicates that determination of the amount of sulfur degassed from the Laki magma batch by measurements of sulfur in the volcanic products (the petrologic method) yields a result which is sufficient to account for the mass of aerosols estimated by other methods

The Eruption of Submarine Rhyolite Lavas and Domes in the Deep Ocean – Havre 2012, Kermadec Arc

Silicic effusive eruptions in deep submarine environments have not yet been directly observed and very few modern submarine silicic lavas and domes have been described. The eruption of Havre caldera volcano in the Kermadec arc in 2012 provided an outstanding database for research on deep submarine silicic effusive eruptions because it produced 15 rhyolite (70–72 wt.% SiO2) lavas and domes with a total volume of ∼0.21 km3 from 14 separate seafloor vents. Moreover, in 2015, the seafloor products were observed, mapped and sampled in exceptional detail (1-m resolution) using AUV Sentry and ROV Jason2 deployed from R/V Roger Revelle. Vent positions are strongly aligned, defining NW-SE and E-W trends along the southwestern and southern Havre caldera margin, respectively. The alignment of the vents suggests magma ascent along dykes which probably occupy faults related to the caldera margin. Four vents part way up the steeply sloping southwestern caldera wall at 1,200–1,300 m below sea level (bsl) and one on the caldera rim (1,060 m bsl) produced elongate lavas. On the steep caldera wall, the lavas consist of narrow tongues that have triangular cross-section shapes. Two of the narrow-tongue segments are connected to wide lobes on the flat caldera floor at ∼1,500 m bsl. The lavas are characterized by arcuate surface ridges oriented perpendicular to the propagation direction. Eight domes were erupted onto relatively flat sea floor from vents at ∼1,000 m bsl along the southern and southwestern caldera rim. They are characterized by steep margins and gently convex-up upper surfaces. With one exception, the domes have narrow spines and deep clefts above the inferred vent positions. One dome has a relatively smooth upper surface. The lavas and domes all consist of combinations of coherent rhyolite and monomictic rhyolite breccia. Despite eruption from deep-water vents (most &gt;900 m bsl), the Havre 2012 rhyolite lavas and domes are very similar to subaerial rhyolite lavas and domes in terms of dimensions, volumes, aspect ratio, textures and morphology. They show that lava morphology was strongly controlled by the pre-existing seafloor topography: domes and wide lobes formed where the rhyolite was emplaced onto flat sea floor, whereas narrow tongues formed where the rhyolite was emplaced on the steep slopes of the caldera wall

Volcanic facies architecture, hydrothermal alteration and subsea-floor replacement at the Neves Corvo deposit, Iberian Pyrite Belt

Contribution to research project ARCHYMEDESII-POCTI/CTA/45873/2002.Three felsic volcanic sequences constitute the host succession to the Neves Corvo VHMS deposit. The lower volcanic sequence (late Famennian) consists of a rhyolitic fiamme-rich facies association that comprises polymictic and overall graded quartzphyric fiamme breccia units (up to 60 m thick). These units have pyroclastic origin and constitute the substrate to the rhyolite facies association (intermediate volcanic sequence). The rhyolite facies association (late Strunian) comprises intervals of coherent quartz-feldspar-phyric rhyolite (up to 10 m thick) that are enclosed by much thicker intervals (up to 250 m) of jigsaw-fit and clast-rotated monomictic rhyolite breccia. Laterally these breccias grade to beds of monomictic rhyolite breccia that alternate with crystal-rich sandstone. The units defined by the rhyolite facies association are rhyolitic lavas. The massive sulfide orebodies (late Strunian) directly overly the lavas or are interleaved with relatively thin (up to 50 m) intervals of mudstone. The upper volcanic sequence (early Visean) consists of a thin interval of monomictic dacite breccia. The host succession to the Neves Corvo orebodies thus comprises proximal to source vent deposits from submarine explosive and effusive eruptions. However, the ore-forming process relates both in time and space with the rhyolitic lavas, which are coeval with the mineralization. Neves Corvo is well known for its high-grade Cu ores and unique cassiterite mineralization. Ore-related hydrothermal activity overprints an early metasomatic stage and relates with a multi-sourced hydrothermal system, responsible for early stringer and massive cassiterite deposition and subsequent massive sulfide oregeneration. In the Corvo orebody, the early deposition of massive cassiterite ores was fed by an independent stockwork in a tectonically-bounded alignment. Textural and petrographic analyses, geochemistry and oxygen-isotope data indicate brusque flushing of the tin-bearing fluid into seawater after minimal fluid-rock interaction during up flow. Massive sulfide-related hydrothermal alteration is essentially stratabound and controlled by permeability contrasts. Alteration zonation is classical, consisting of an inner chlorite/donbassite-quartz-sulfides-(sericite) core that grades into sericitequartz- sulfides-(chlorite) and paragonite-quartz-sulfides-(chlorite) peripheral envelopes. The aluminous hydrothermal alteration mineralogy coupled with elemental and stable isotope geochemistry indicates very low pH, unusually high maximum interaction temperature and predominant low-sulfidation alteration/mineralization conditions. Textural and mass-balance analyses show extensive silicate-sulfide replacement in the coherent volcanic rocks of the footwall sequence, and disseminated replacement mineralization in the volcaniclatic/sedimentary units

The largest deep-ocean silicic volcanic eruption of the past century

© The Author(s), 2018. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Science Advances 4 (2018): e1701121, doi:10.1126/sciadv.1701121.The 2012 submarine eruption of Havre volcano in the Kermadec arc, New Zealand, is the largest deep-ocean eruption in history and one of very few recorded submarine eruptions involving rhyolite magma. It was recognized from a gigantic 400-km2 pumice raft seen in satellite imagery, but the complexity of this event was concealed beneath the sea surface. Mapping, observations, and sampling by submersibles have provided an exceptionally high fidelity record of the seafloor products, which included lava sourced from 14 vents at water depths of 900 to 1220 m, and fragmental deposits including giant pumice clasts up to 9 m in diameter. Most (>75%) of the total erupted volume was partitioned into the pumice raft and transported far from the volcano. The geological record on submarine volcanic edifices in volcanic arcs does not faithfully archive eruption size or magma production.This research was funded by Australian Research Council Postdoctoral fellowships (DP110102196 and DE150101190 to R. Carey), a short-term postdoctoral fellowship grant from the Japan Society for the Promotion of Science (to R. Carey), National Science Foundation grants (OCE1357443 to B.H., OCE1357216 to S.A.S., and EAR1447559 to J.D.L.W.), and a New Zealand Marsden grant (U001616 to J.D.L.W.). J.D.L.W. and A.M. were supported by a research grant and PhD scholarship from the University of Otago. R.W. was supported by NIWA grant COPR1802. J.D.L.W. and F.C.-T. were supported by GNS Science grants CSA-GHZ and CSA-EEZ. M.J. was supported by the U.S. Department of Defense (DoD) through the National Defense Science and Engineering Graduate Fellowship (NDSEG) Program